Search results for "Fondamenti"

Photocatalytic process intensification by coupling with pervaporation

2011

The integration of photocatalysis with a membrane separation process, in particular pervaporation, permits the recovery of valuable intermediate compounds (aromatic aldehydes) while they are produced avoiding their further degradation in the reactive ambient. In this way the yield and the conversion are enhanced. The coupling of the two processes is straightforward and the integration is complete even maintaining pervaporation and photocatalysis in two separate apparatuses provided that the process stream is continuously recycled at a sufficiently high flow rate. Additional advantages are: higher degree of purification of the aldehyde in the powder-free product stream, semicontinuous produc…

Facile preparation of CuBi2O4/TiO2 hetero-systems employed for simulated solar-light selective oxidation of 4-methoxybenzyl alcohol model compound

2023

The selective photocatalytic oxidation of organic substances is today considered one of the green techniques to synthesize important starting materials in different technological applications. This work reports an efficient, simple and cheap strategy for the synthesis of a new photocatalytic CuBi2O4-TiO2 (CBO/TiO2) heterosystem at room temperature. The prepared powders were characterized by X-ray diffraction (XRD), UV–Vis diffuse reflectance spectra (DRS), field-emission scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS), and electrochemical measurements. The photocatalytic activity was evaluated by performing a probe reaction, namely the partial oxidation of 4-me…

Nanomateriali a base di TiO2 come fotocatalizzatori per sintesi selettive di alcoli ad aldeidi in fase acquosa

2011

Ferulic Acid Oxidation Through Visible Light Induced TiO2 Photocatalysis

2012

Heterogeneous photocatalysis: a promising advanced oxidation process

2018

This chapter reports the fundamentals of heterogeneous PC. In particular, different kinetic models and the influence of some parameters (such as pH, temperature, light intensity) on the rate of PC are described, and the effects of some photocatalyst modifications are discussed. Methods for photoreactor modeling are analyzed and the coupling of PC with other AOPs using H2O2, O3, and peroxydisulfate are discussed.

Membranes for photocatalysis in wastewater treatment

2011

Selective photocatalytic oxidation of 4-substituted aromatic alcohols in water with rutile TiO2 prepared at room temperature

2009

WOS: 000264978500012

Determination of Photoadsorption Capacity of Polychrystalline TiO2 Catalyst in Irradiated Slurry

2009

WOS: 000322711800002

Photoelectrocatalytic reactors and light sources

2023

Photoelectrocatalysis (PEC) couples electrochemical methods with photocatalysis (PC) to enhance the separation of the photoproduced electron and hole pairs at semiconductor active surface, thus increasing the photocatalytic efficiency. PEC technology is considered one of the most promising method for processes as water treatment, fuel generation, and PEC sensing. This chapter try to link fundamental research and practical applications in photoelectrochemical engineering including reactors design strategies in different scales.

PMRs Utilizing Non–Pressure-Driven Membrane Techniques

2018

In the present chapter it is shown how photocatalytic membrane reactors utilizing membrane processes, which are not pressure driven, can exploit various mechanisms to obtain a substantial improvement of the process. The fundamentals of this particular type of membrane reactors are reviewed including the effects of the most important parameters and the methods and rules of coupling photocatalysis and membrane separation. The survey of the studies on photocatalytic membrane reactors (PMRs) utilizing pervaporation, dialysis, membrane contactors and membrane distillation offers the opportunity of discussing the advantages with respect to PMRs adopting pressure driven membrane processes. Indeed,…