Search results for "FrACT"
showing 10 items of 6229 documents
Lower Cretaceous tholeiitic dyke swarms from the Ponta Grossa Arch (southeast Brazil): Petrology, Sr-Nd isotopes and genetic relationships with the P…
1990
The Lower Cretaceous dykes of the Ponta Grossa Arch, the most important dyke swarms in Brazil, are associated with the flood basalts and rare acid flows of the northern Parana basin. The Ponta Grossa (PG) dykes are formed by two-pyroxene tholeiites and rare acid rocks. The basaltic dykes may be distinguished into two main groups: a dominant, high-TiO2 (> 2 wt.%; HTi) group and a subordinate, low-TiO2 (< 2 wt.%; LTi) group, characterized, for similar MgO content, by high and low incompatible-element contents, respectively. Most PG dykes do not show chemical and isotope evidence supporting important crustal contamination. PG dykes with (87Sr86Sr)0 < 0.7060 plot in the mantle array (ϵSr ≈ + 17…
Late proterozoic island arc volcanics from Gebeit, Red Sea Hills, north-east Sudan
1994
The area of Gebeit Mine in the northern Red Sea Hills, Sudan, is built up of voluminous volcanic rocks and minor volcaniclastic and clastic sequences. According to their chemical and modal compositions the Gebeit volcanics can be devided into four groups: (a) cpx-physic basalts with clinopyroxene and plagioclase as the dominant phenocrysts and minor opaques; (b) hbl-physic basalts with hornblende, clinopyroxene, plagioclase and subordinate magnetite including one rare dacite; (c) pl-phyric andesites with plagioclase phenocrysts in a matrix that is rich in magnetite; and (d) aphyric basalts. The compositional variation within the distinct volcanic groups can only partly be explained by fract…
First gas and thermal measurements at the frequently erupting Gamalama volcano (Indonesia) reveal a hydrothermally dominated magmatic system
2020
Abstract The first gas and thermal measurements at the summit of the Gamalama volcano indicate that the system is dominated by hydrothermal processes. This is highlighted by the prevalence of H2S over SO2 (H2S/SO2 = 2–8), a high CO2/SO2 ratio (76–201), and a low heat transfer (3.0 MW) to the surface. A relative variation in gas composition is observed along the degassing fracture zone, possibly due to partial S scrubbing. Despite this surface hydrothermal signature, the system exhibits high gas equilibrium temperatures (425–480 °C), indicating that fluids are not exclusively derived from a boiling hydrothermal aquifer, but also sourced by cooling and crystallizing basaltic magma at deep tha…
40Ar-39Ar ages and petrogenesis of middle Eocene post-collisional volcanic rocks along the Izmir-Ankara-Erzincan suture zone, NE Turkey
2019
Abstract The central and northeastern of Turkey were shaped by the transition from collisional to post-collisional tectonics and coeval magmatism during Early Cenozoic. However, the temporal and spatial evolution of the magmatism during the middle Eocene remains elusive. In this paper, we provide petrological, isotopic and radiometric data from two middle Eocene volcano-sedimentary successions, from the northern (Almus) and southern (Yildizeli) parts of the Izmir–Ankara–Erzincan Suture Zone, and discuss their generation in the post-collisional setting. Our results indicate that the volcanic units from these regions display similar stratigraphic and petrological evolution during the narrow w…
Geochemistry and early Palaeogene SHRIMP zircon ages for island arc granitoids of the Sierra Maestra, southeastern Cuba
2004
The Palaeogene volcanic arc successions of the Sierra Maestra, southeastern Cuba, were intruded by calc-alkaline, low- to medium-K tonalites and trondhjemites during the final stages of subduction and subsequent collision of the Caribbean oceanic plate with the North American continental plate. U‐Pb SHRIMP zircon dating of five granitoids yielded 206 Pb/ 238 U emplacement ages between 60.5F2.2 and 48.3F0.5 Ma. The granitoids are the result of subduction-related magmatism and have geochemical characteristics similar to those of magmas from intra-oceanic island-arcs such as the Izu Bonin‐Mariana arc and the New Britain island arc, Lesser Antilles. Major and trace element patterns suggest evol…
Transition from mildly-tholeiitic to calc-alkaline suite: the case of Chichontepec volcanic centre, El Salvador, Central America
1998
Abstract The Chichontepec volcano is a Plio-Pleistocene composite volcano that erupted lavas ranging from high-alumina basalts to dacites. It experienced a caldera-forming paroxysmal eruption during the early Pleistocene. Pre-caldera lavas are mildly tholeiitic and they evolved mainly by low pressure crystal fractionation, notwithstanding the fact that most mafic lavas (low-MgO high-alumina basalts) retain traces of polybaric evolution. Conversely, post-caldera lavas, which are mainly pyroxene andesites, are clearly calc-alkaline, having evolved by open-system crystal fractionation. Sr–Nd isotopic data and trace elements characteristics indicate that the same mantle source was involved in t…
Sources, degassing, and contamination of CO2, H2O, He, Ne, and Ar in basaltic glasses from Kolbeinsey Ridge, North Atlantic
2005
Abstract New volatile data (CO2, H2O, He, Ne, and Ar) are presented for 24 submarine basaltic glasses from the Kolbeinsey Ridge, Tjornes Fracture Zone and Mohns Ridge, North Atlantic. Low CO2 and He contents indicate that magmas were strongly outgassed with the extent of degassing increasing toward the south, as expected from shallower ridge depths. Ne and Ar are significantly more abundant in the southernmost glasses than predicted for degassed melt. The strong atmospheric isotopic signal associated with this excess Ne and Ar suggests syn- or posteruptive contamination by air. Degassing, by itself, cannot generate the large variations in δ13C values of dissolved CO2 or coupled CO2-Ar varia…
X-Ray crystallographic and computational study on uranyl-salophen complexes bearing nitro groups.
2017
In the solid state, salophen–UO2 complexes bearing one, two, or three NO2 groups lack the pronounced ligand curvature that represents a structural hallmark for this class of compounds. A detailed structural study based on single-crystal X-ray crystallography and computational methods, comprising molecular dynamics, gas-phase Hartree Fock, and DFT calculations, was carried out to investigate the coordination properties of the uranyl cation.
Fracture stratigraphy and oil first migration in Triassic shales, Favignana Island, western Sicily, Italy
2021
This study aims at evaluating the control exerted by fracture stratigraphy and diagenetic processes on oil first migration through an outcropping, mixed carbonate-siliciclastic succession. The present work included results of sedimentological, paleontological, mineralogical, petrographic, structural, and microstructural analyses carried out on organic-rich shales exposed at the Favignana Island of Sicily, Italy. The analyses focus on Upper Triassic yellowish siltstones and greyish laminated dolomitic limestones, which form a 10's of m-thick succession exposed along the westernmost portion of the Sicilian fold-and-thrust belt. The studied succession deposited in a coastal lagoon associated t…
Pimobendan B from powder diffraction data
2013
The title molecule, C19H18N4O2{systematic name: (RS)-6-[2-(4-methoxyphenyl)-1H-benzimidazol-5-yl]-5-methyl-4,5-dihydropyridazin-3(2H)-one}, adopts an extended conformation. The dihedral angles between the central benzimidazole ring sytem and the pendant methoxyphenyl and pyridazinone residues are 1.41 (18) and 9.7 (3)°, respectively. In the crystal, N—H...N hydrogen bonds link the imadazole groups into [001] chains, and pairs of N—H...O hydrogen bonds link the pyridazinone groups into dimers. Together, these generate a two-dimensional supramolecular structure parallel to (010). The layers are linked by C—H...π interactions.