Search results for "Frame"
showing 10 items of 1767 documents
CONCESSIONI DEMANIALI MARITTIME E DIRITTO EUROUNITARIO: LA FINE DEL TEMPO DELLE MORE
2023
Il contributo analizza il frammentario quadro normativo delle concessioni demaniali marittime, lacuali e fluviali con finalità turistico-ricreativa alla luce degli orientamenti della giurisprudenza domestica, con le significative pronunce del Consiglio di Stato e di quella della Corte di Giustizia dell’Unione europea, in particolare della recentissima sentenza 20 aprile 2023 (C-348/22).
Tutela e sicurezza del lavoro tra centro e periferia: la sicurezza sui luoghi di lavoro
2013
Il saggio prende in esame la complessa questione del riparto di competenze tra Stato e Regioni alla luce del Titolo V della Costituzione in materia di salute e sicurezza sui luoghi di lavoro. Il riparto di competenze tra centro e periferia è stato oggetto di una limitata analisi da parte della dottrina e della giurisprudenza, che si sono concentrate in particolare sulla disciplina del mercato del lavoro. L’Autore descrive un sistema multilivello, caratterizzato dalla compresenza di fonti nazionali e regionali, della contrattazione collettiva, nonché di codici di condotta. Sulla scorta di una ricostruzione del quadro normativo e dei percorsi della giurisprudenza, il saggio propone una lettur…
On the problem of visualizing point distributions in high dimensional spaces
1995
Abstract Exploring dynamical systems with the aid of computer graphics requires that the relevant structures can be seen and be noticed. This poses special problems if the system is multidimensional, and it has to be decided which kind of projection serves the purpose. I propose using the mathematical frame of categories and functors to describe the process of visualization. This allows detecting and analyzing possible sources of misinterpretation in a formal way. The distribution of distances of embedded electroencephalographic data from a fixed reference point is used as an example for discussing some aspects of the visualization process. The multidimensional p-norms are an example of a p…
Geometric and conceptual knowledge representation within a generative model of visual perception
1989
A representation scheme of knowledge at both the geometric and conceptual levels is offered which extends a generative theory of visual perception. According to this theory, the perception process proceeds through different scene representations at various levels of abstraction. The geometric domain is modeled following the CSG (constructive solid geometry) approach, taking advantage of the geometric modelling scheme proposed by A. Pentland, based on superquadrics as representation primitives. Recursive Boolean combinations and deformations are considered in order to enlarge the scope of the representation scheme and to allow for the construction of real-world scenes. In the conceptual doma…
Electronic properties of graphene: A learning path for undergraduate students
2016
The purpose of this work is to present a learning path aimed at deepening student understanding of the fundamental concepts underlying the electronic properties of new materials, graphene in particular. To achieve this task, we propose a five-week long workshop where students may be introduced to fundamental concepts of advanced physics, rarely used in learning paths, such as the symmetry properties of the crystal lattice, the group theory , the features of the free electron wave functions and energy levels, the relativistic Dirac equation. Particular emphasis is given to the manner of introducing these concepts, since an essential knowledge of solid state physics, quantum physics and relat…
Constructivismo, psicoterapias cognitivas de reestructuración y enfoques contextuales
2020
En este trabajo se establecen las diferencias y convergencias principales entre los modelos cognitivos de reestructuración, los constructivistas y los contextuales. Partiendo de una breve revisión histórica se podrá enmarcar el surgimiento de cada uno de estos enfoques e, igualmente, las diferencias epistemológicas y ontológicas entre ellos. Estos modelos se analizan, principalmente, haciendo hincapié en sus conceptos principales y en las técnicas desarrolladas que, en principio, serían coherentes con su marco teórico. Igualmente, la coherencia entre teoría y práctica se hace evidente mediante el desarrollo de un tipo concreto, y diferente, de relación terapéutica en cada modelo. La conclus…
Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes
2011
A highly porous member of isoreticular MFU-4-type frameworks, [Zn(5)Cl(4)(BTDD)(3)] (MFU-4l(arge)) (H(2)-BTDD=bis(1H-1,2,3-triazolo[4,5-b],[4',5'-i])dibenzo[1,4]dioxin), has been synthesized using ZnCl(2) and H(2)-BTDD in N,N-dimethylformamide as a solvent. MFU-4l represents the first example of MFU-4-type frameworks featuring large pore apertures of 9.1 Å. Here, MFU-4l serves as a reference compound to evaluate the origin of unique and specific gas-sorption properties of MFU-4, reported previously. The latter framework features narrow-sized pores of 2.5 Å that allow passage of sufficiently small molecules only (such as hydrogen or water), whereas molecules with larger kinetic diameters (e.…
A tris-oxovanadium pyrogallate complex: synthesis, structure, and magnetic and electronic properties
2021
International audience; With the aim of identifying new cation-phenolate complexes, we herein investigated the reactivity of pyrogallol (H(3)pgal) with vanadium salts. A trimetallic anionic complex was identified, and found to be formed under a broad set of reaction conditions. This complex, with the formula V3O3(pgal)(3)(3-), consists of three oxovanadium(iv) units connected together by three pyrogallate ligands to afford a bowl-shaped species presenting a pseudo 3-fold symmetry axis. Its crystal structure is reported, as well as its characterisation by a broad set of techniques, including powder X-ray diffraction, thermogravimetric analysis, infrared and Raman spectroscopy, and solid stat…
Coordination Driven Capture of Nicotine Inside a Mesoporous MOF.
2017
Metal organic frameworks (MOFs) are a wide class of crystalline porous polymers studied in many fields, ranging from catalysis to gas storage. In the past few years, MOFs have been studied for the encapsulation of organic or organometallic molecules and for the development of potential drug carriers. Here, we report on the study of two structurally-related mesoporous Cu-MOFs, namely PCN-6 and PCN-6′ (PCN stands for Porous Coordination Network), for nicotine trapping. Nicotine is a well-known alkaloid liquid molecule at room temperature, whose crystalline structure is still unknown. In this work, the loading process was monitored by electron ionization mass spectrometry by using a direct ins…
2004
In rats, two peroxisomal 3-ketoacyl-CoA thiolase genes (A and B) have been cloned, whereas only one thiolase gene is found in humans. The aim of this study was thus to clone the different mouse thiolase genes in order to study both their tissue expression and their associated enzymatic activity. In this study, we cloned and characterized two mouse peroxisomal 3-ketoacyl-CoA thiolase genes (termed thiolase A and B). Both thiolase A and B genes contain 12 exons and 11 introns. Using RNA extracted from mouse liver, we cloned the two corresponding cDNAs. Thiolase A and B cDNAs possess an open reading frame of 1272 nucleotides encoding a protein of 424 amino acids. In the coding sequence, the tw…