Search results for "Frequency generation"
showing 10 items of 30 documents
Optimized blue light generation in optically contacted walk-off compensated RbTiOAsO4 and KTiOP1−yAsyO4
1999
Abstract We study type II 1.32 μm second harmonic generation (SHG) in a RbTiOAsO 4 optically contacted walk-off compensated device. The reduction of the effective walk-off angle by a factor of 3.7 with respect to KTiOPO 4 for the same interaction leads to an enhancement by a factor of 10 of the conversion efficiency. A model is proposed for both type I and type II SHG in such a structure. The angular tuning curve is a multi-peaked one, as predicted by the model. The enhancement of the SHG conversion efficiency allows us to optimize the generation of blue laser light at 440 nm: a specially designed KTiOP 0.98 As 0.02 O 4 solid solution crystal achieves angular non-critical phase matching at …
Lipid carbonyl groups terminate the hydrogen bond network of membrane-bound water.
2015
We present a combined experimental sum-frequency generation (SFG) spectroscopy and ab initio molecular dynamics simulations study to clarify the structure and orientation of water at zwitterionic phosphatidylcholine (PC) lipid and amine N-oxide (AO) surfactant monolayers. Simulated O-H stretch SFG spectra of water show good agreement with the experimental data. The SFG response at the PC interface exhibits positive peaks, whereas both negative and positive bands are present for the similar zwitterionic AO interface. The positive peaks at the water/PC interface are attributed to water interacting with the lipid carbonyl groups, which act as efficient hydrogen bond acceptors. This allows the …
The Fluorite/Water Interfaces: Structure and Spectroscopy from First Principles Simulations
2014
Despite its relevance to industrial, environmental and medical application, the fluorite/water interface still lacks a microscopic/atomistic characterization. In this contribution we provide the first atomistic description of such interface using first principles molecular dynamics simulations. Our models, which explore a wide range of pH, are able to provide a rational of the recent vibrational spectroscopy experiments. In particular we find that at neutral pH the water at the interface is disordered, in agreement with the experimental data, and explaining why no Vibrational Sum Frequency Generation (VSFG) signal is recorded. At high pH, OH groups which localize at the interface are respon…
Experimental and theoretical evidence for bilayer-by-bilayer surface melting of crystalline ice
2017
On the surface of water ice, a quasi-liquid layer (QLL) has been extensively reported at temperatures below its bulk melting point at 273 K. Approaching the bulk melting temperature from below, the thickness of the QLL is known to increase. To elucidate the precise temperature variation of the QLL, and its nature, we investigate the surface melting of hexagonal ice by combining noncontact, surface-specific vibrational sum frequency generation (SFG) spectroscopy and spectra calculated from molecular dynamics simulations. Using SFG, we probe the outermost water layers of distinct single crystalline ice faces at different temperatures. For the basal face, a stepwise, sudden weakening of the hy…
Sum Frequency Generation Spectra from Velocity-Velocity Correlation Functions: New Developments and Applications
2018
At the interface, the properties of water can be rather different from those observed in the bulk. In this chapter we present an overview of our computational approach to understand water structure and dynamics at the interface including atomistic and electronic structure details. In particular we show how Density Functional Theory-based molecular dynamics simulations (DFT-MD) of water interfaces can provide a microscopic interpretation of recent experimental results from surface sensitive vibrational Sum Frequency Generation spectroscopy (SFG). In our recent work we developed an expression for the calculation of the SFG spectra of water interfaces which is based on the projection of the at…
Counter-propagating difference-frequency generation in diamond with terahertz fields
2013
The nonlinear interaction of terahertz (THz) pulses with optical fields in Kerr, gaseous media is a key ingredient for broadband THz detection schemes [1]. Terahertz field-induced second harmonic generation in solid-state media has also been considered for THz detection and as a tool e.g. for liquid dynamics investigations [2,3], while four-wave mixing has been addressed as a possible mechanism for THz generation [4,5]. © 2013 IEEE.
Experimental observation of incoherent modulation instability in standard optical fibers
2005
In this work, we demonstrate theoretically and experimentally that a partially temporally incoherent light can exhibit modulational instability when propagating in an optical fiber with instantaneous nonlinear Kerr response.
Broadband Second-Harmonic Generation via Random Quasi-Phase-Matching in PPLT
2010
We demonstrated broadband second-harmonic generation via random Quasi-Phase-Matching in periodically poled Lithium Tantalate.
Sum Frequency Generation Spectra from Velocity–Velocity Correlation Functions
2017
We developed an expression for the calculation of the sum frequency generation spectra (SFG) of water interfaces that is based on the projection of the atomic velocities on the local normal modes. Our approach permits one to obtain the SFG signal from suitable velocity-velocity correlation functions, reducing the computational cost to that of the accumulation of a molecular dynamics trajectory, and therefore cutting the overhead costs associated with the explicit calculation of the dipole moment and polarizability tensor. Our method permits to interpret the peaks in the spectrum in terms of local modes, also including the bending region. The results for the water-air interface, obtained usi…
Parametric solitons in nonlinear photonic crystals
2007
We present theoretical and experimental investigations on the soliton dynamics associated to multiple second harmonic generation resonances in two-dimensional nonlinear photonic crystals, highlighting a wealth of new possibilities for soliton management in such structures.