Search results for "Fuel Cell"
showing 10 items of 260 documents
Covalent-ionically cross-linked polyetheretherketone proton exchange membrane for direct methanol fuel cell
2010
Abstract In this paper, the proton exchange membrane prepared by covalent-ionically cross-linking water soluble sulfonated–sulfinated poly(oxa- p -phenylene-3,3-phthalido- p -phenylene-oxa- p -phenylene-oxy-phenylene) (SsPEEK-WC) is reported. Compared with covalent cross-linked PEEK-WC membrane, this covalent-ionically cross-linked PEEK-WC membrane exhibits extremely reduced water uptake and methanol permeability, but just slightly sacrificed proton conductivity. The proton conductivity of the covalent-ionically cross-linked PEEK-WC membrane reaches to 2.1 × 10 −2 S cm −1 at room temperature and 4.1 × 10 −2 S cm −1 at 80 °C. The methanol permeability is 1.3 × 10 −7 cm 2 s −1 , 10 times …
Electronic modifications in (Ba,La)(Fe,Zn,Y)O3−δ unveiled by oxygen K-edge X-ray Raman scattering
2022
Oxides with mixed protonic-electronic conductivity are relevant as oxygen electrodes for protonic ceramic fuel cells and electrolyzers. We investigate the modification of the electronic structure of (Ba,La)(Fe,Zn,Y)O3−δ when iron is partially replaced by Zn2+ or Y3+ and when it changes between 3+ and 4+ formal oxidation states. With a combination of X-ray Raman scattering (O K-edge) and X-ray absorption near edge structure (Fe, Zn, and Y K-edges) and the corresponding simulations reproducing the spectroscopic data, we quantitatively analyze the degree of covalency of the Fe-O bonds in reduced (Fe mainly 3+) and oxidized (Fe mainly 4+) materials. The simulations employ two semi-empirical par…
Grid interaction and environmental impact of a net zero energy building
2020
Abstract The concept of Net Zero Energy Building (NZEB), as a grid-connected building that generates as much energy as it uses over a given period, has been developing through policies and research agendas during the last decade as a contribution towards the decarbonization of the building sector. However, since the most applicable and widely used renewable energy supply options are non-programmable, the large-scale NZEBs diffusion into the existing power grids can seriously affect their stability having a relapse on operation costs and environmental impacts. In this context, the study aims at performing the design of the energy systems to be used in the case-study through a wide numbers of…
Fuel cell modelling and test: Experimental validation of model accuracy
2013
In the last few years, renewable energies have been encouraged by worldwide governments to meet energy saving policies. Among renewable energy sources, fuel cells have attracted much interest for a wide variety of research areas. Fuel cell-based residential-scaled power supply systems take advantage of simultaneous generation of power and heat, reducing the overall fossil fuel consumption and utilities cost. Modeling is one of the most important topics concerning fuel cell use. In this paper, a measurement-based steady-state and dynamic fuel cell model is presented. The proposed modelling approach is implemented on a 5kW Proton Exchange Membrane Fuel Cell. The parameters identification proc…
MATLAB-based simulator of a 5 kW fuel cell for power electronics design
2013
Abstract In the last few years, renewable energies have been encouraged by worldwide governments to meet energy saving policies. Among renewable energy sources, fuel cells have attracted much interest for a wide variety of research areas. Since combined heat-power generation is allowed, household appliances are still the most promising applications. Fuel cell-based residential-scaled power supply systems take advantage by simultaneous generation of power and heat, reducing the overall fossil fuel consumption and utilities cost. Modelling is one of the most important topic concerning fuel cell use. In this paper, a measurement-based steady-state and dynamic fuel cell model is presented. The …
Development of electrodes materials for SOFC fed by natural gas / biogas. Applications to "pre-reforming" and "single-chamber" concepts
2010
Solid Oxide Fuel Cell is a device for “clean” electricity production from chemical energy. The new configuration called “single-chamber” seems to be very attractive with several advantages over bi-chamber conventional configuration: easier manufacturing, lowering of working temperature, possible use of hydrocarbons as fuel… Such configuration involves the development of new electrode materials satisfying new requirements. The evaluation of 7 potential cathode materials through several characterizations has shown that a compromise has to be found since one material does not exhibit all the requested features. A library of 15 supported catalysts (3 metals and 5 supports) was developed. These …
Surface Self-Diffusion and Mean Displacement of Hydrogen on Graphite and a PEM Fuel Cell Catalyst Support
2009
International audience; Quasielastic neutron scattering (QENS) measurements together with equilibrium molecular dynamic (EMD) simulations have been performed to investigate the surface interaction between hydrogen molecules and a carbon material commonly used in polymer electrolyte membrane fuel cells (PEMFC), called XC-72. Half a monolayer of molecular hydrogen was adsorbed on to the carbon material at 2 K. QENS spectra were recorded at the time-of-flight spectrometer IN5 at 40, 45, 50, 60, 70, 80, and 90 K. Simultaneously the pressure was measured as a function of time to monitor the equilibrium surface coverage at each temperature. By using the Chudley and Elliott model for jump diffusio…
Life cycle assessment of solid oxide fuel cells and polymer electrolyte membrane fuel cells: A review
2017
Fuel cells (FCs) are among the key technologies that Europe will have to rely on in order to comply with the most recent environmental targets inspired by decarbonization and circular economy. The assessment of the real advantages of using FCs for producing energy must include a reliable analysis of the energy and environmental impacts during the life cycle of these systems, including the raw materials supply, production, use, and disposal. In this context, the life cycle assessment (LCA) is a well-established methodology for assessing the eco-profile of products and services and for identifying the components and the life cycle steps having the largest contribution to energy and environmen…
Analysis of Load Match in Nearly Zero Energy Buildings
2018
The concept of load matching refers to the degree of agreement or disagreement of the on-site generation with the building load profiles: it can be increased and optimised with modifications on both the energy demand and generation. In this context, the paper presents the load match analysis of a case study: a modular housing construction (it has an area of 45 m 2 and S/V ratio equal to 2.75 m −1 ) built in Messina (Italy). Moreover, in order to optimize the design of the next test module to be built, a parametric analysis was performed considering different scenarios on the generation side, to explore the effectiveness of the solutions sets used in current design and plan different solutio…
Heteropolyacids - Chitosan Membranes for H2/O2 Low Temperature Fuel Cells
2016
Proton exchange membrane fuel cells (PEMFCs) have received much attention in recent years because of their high power density, efficiency and zero-environmental pollution. As one of the key components in fuel cells, the proton exchange membrane is expected to have high proton conductivity and good electrochemical stability. In the attempt to promote PEMCFs commercialization, high cost of fuel cell systems and short lifecycle are the two main issues that need to be addressed, thus large research effort has been devoted in developing new polymer electrolytes that can replace the usually employed proton conductors, e.g. Nafion®, with other membranes of comparable performances but lower cost.A…