Search results for "Fuel Cell"
showing 10 items of 260 documents
Proton Conducting Membrane Prepared by Cross-Linking Highly Sulfonated Peek for PEMFC Application
2009
The proton conducting membrane was prepared by cross-linking highly sulfonated and sulfinated poly(etheretherketone) (SsPEEK). The cross-linked membrane is low cost due to its use of non-expensive chemical and simple production procedure. The membrane exhibited high proton conductivity (0.04 S/cm at 60 °C), extremely reduced water uptake, enhanced strength and stability compared with that of non-cross-linked membrane. These results suggested that the cross-linked PEEK membrane is a suitable candidate of proton conducting membranes for polymer electrolyte membrane fuel cell (PEMFC) applications, particularly promising to be used in direct methanol fuel cell (DMFC) due to its lower methanol c…
Insights into the Dynamics of Grotthuss Mechanism in a Proton-Conducting Chiral bioMOF
2016
Proton conduction in solids attracts great interest, not only because of possible applications in fuel cell technologies, but also because of the main role of this process in many biological mechanisms. Metal–organic frameworks (MOFs) can exhibit exceptional proton-conduction performances, because of the large number of hydrogen-bonded water molecules embedded in their pores. However, further work remains to be done to elucidate the real conducting mechanism. Among the different MOF subfamilies, bioMOFs, which have been constructed using biomolecule derivatives as building blocks and often affording water-stable materials, emerge as valuable systems to study the transport mechanisms involve…
PBI-based composite membranes for polymer fuel cells
2010
Abstract In the present study poly(2,2-(2,6-pyridin)-5,5-bibenzimidazole) was used for the preparation of novel MEAs for high-temperature polymer fuel cells (HT-PEMFCs). We prepared hybrid materials with two types of silica fillers in order to increase the MEA performances using this polymer. The membranes were characterized in terms of their microstructure and thermal stability. Cell operation tests and Electrochemical Impedance Spectroscopy were used for the characterization of the MEAs. A maximum power density of about 80 mW cm−2 was obtained at 300 mA cm−2 by using an imidazole-modified silica filler. The EIS technique showed that the fillers chiefly help to reduce the charge transfer r…
Synthesis and characterization of bisulfonated poly(vinyl alcohol)/graphene oxide composite membranes with improved proton exchange capabilities
2020
Abstract Composite membranes based on poly(vinyl alcohol) (PVA) and graphene oxide (GO) were prepared by solution-casting method to be used as proton exchange membranes (PEMs) in fuel cell (FC) applications. Bisulfonation was employed as a strategy to enhance the proton conductivity of these membranes. First, a direct sulfonation of the polymer matrix was accomplished by intra-sulfonation of the polymer matrix with propane sultone, followed by the inter-sulfonation of the polymer chains using sulfosuccinic acid (SSA) as a crosslinking agent. Furthermore, the addition of graphene oxide (GO) as inorganic filler was also evaluated to enhance the proton-conducting of the composite membranes. Th…
A Covalently Cross-linked Polyetheretherketone Proton Exchange Membrane for DMFC
2009
The proton exchange membrane was prepared by covalent cross-linking sulfonated-sulfinated polyetheretherketone. The cross-linked membrane showed high proton conductivity (0.04 S/cm) with suitable water uptake, low methanol permeability (2.21 × 10-7 cm2/s) and good electrochemical stability. The results suggested that cross-linked polyetheretherketone membrane is particularly promising to be used as proton exchange membrane for the direct methanol fuel cell application.
Elektroutlenianie odpadowego syntetycznego oleju silnikowego w wodnym roztworze H2SO4
2017
W pracy przedstawiono badania nad możliwością wykorzystania odpadowego syntetycznego oleju silnikowego do bezpośredniego wytwarzania energii elektrycznej. Pomiary przeprowadzono w zakresie temperatur 293–333 K. Obejmowały one elektroutlenianie emulsji odpadowego (zużytego) syntetycznego oleju silnikowego na elektrodzie platynowej w wodnym roztworze H2SO4. Do wytworzenia emulsji wykorzystano niejonowy środek powierzchniowo czynny Syntanol DS-10. Maksymalna uzyskana gęstość prądu wyniosła 22 mA/cm2 (dla temp. 333 K). Wykazano więc, że istnieje możliwość bezpośredniego wytwarzania prądu elektrycznego z odpadowego syntetycznego oleju silnikowego, a więc zasilania nim ogniw paliwowych.
A multi-input, single-inductor power system for multisource energy harvesting
2013
Today, energy harvesting is drawing a great deal of attention due to modern trends in energy saving and sustainable development purposes. Among renewable energy sources fuel cells and photovoltaic arrays are the most promising for a wide variety of applications, ranging from few mWatts of wireless sensor networks to kWatts for household appliances. Coupling several harvesters and renewable sources is the winning strategy to ensure a proper supply overcoming the uncertainty and limited availability of common harvesters and renewable sources. Multisource energy harvesting is actually an open research topic involving several pressing and often conflicting requirements. System cost, complexity,…
Microbial fuel cell with Ni-Co cathode
2016
The possibility of trwastewater treatment using the Ni-Co alloys as catalysts for cathode of mickrobial fuel cells is presented in this paper. Using the Ni-Co catalyst allows to increase the power of prototype microbal fuel sell. Use of Ni-Co catalyst will increase the efficiency of the production of electricity. Thid solution will allow to contribute to the development of high efficiency green energy sources.
Feasibility of Waste Engine Oil Electrooxidation with Ni-Co and Cu-B Catalysts
2022
To implement a circular economy policy, methods of using waste products as a starting point for other technologies are constantly researched. One of the waste products that should be disposed of after use is waste engine oil (WEO). Despite the permanent introduction of the electrification of cars, the number of combustion vehicles (and, thus, the production of WEO) is constantly increasing. For these reasons, the reuse of WEOs is extremely important; e.g., to use these oils for energy purposes. One of the potential uses of this type of oil is as fuel for fuel cells (for direct electricity production). To lower the production costs of electrodes for fuel cells, catalysts that do not contain …
Preparation and Analysis of Ni–Co Catalyst Use for Electricity Production and COD Reduction in Microbial Fuel Cells
2019
Microbial fuel cells (MFCs) are devices than can contribute to the development of new technologies using renewable energy sources or waste products for energy production. Moreover, MFCs can realize wastewater pre-treatment, e.g., reduction of the chemical oxygen demand (COD). This research covered preparation and analysis of a catalyst and measurements of changes in the concentration of COD in the MFC with a Ni&ndash