Search results for "Function"

The Single-Scattering Albedo of Atmospheric Aerosol Particles as a Function of Relative Humidity

1976

Relationship between the effective cloud optical depth and different atmospheric transmission factors

2015

This study examines the sensitivity of cloud optical depth (COD) for overcast conditions to radiation transmission using data collected in Valencia, Spain. These relationships are provided as simple empirical functions, therefore avoiding the need to apply complex model minimisation schemes to obtain COD. Comparisons are presented between COD obtained by a minimization method and several radiation transmission factors comprising a clearness index (kt), a modified version (kt'), a cloud modification factor (CMF) and its modified version (CMF'). Additionally, a statistical model of COD proposed by J.C. Barnard and C.N. Long (2004) is tested with our data. Statistical relationships between COD…

Spatial and temporal temperature trends on the Yunnan Plateau (Southwest China) during 1961-2004

2010

Monthly mean (TEM), maximum (Tmax) and minimum (Tmin) surface air temperatures at 119 meteorological stations on the Yunnan Plateau (YP, Southwest China) were analysed for temporal trends and spatial variation patterns during the period 1961–2004. Linear trend analyses revealed that annual temperature over the YP increased at a rate of 0.3 °C/decade during the period 1961–2004, while warming trend of 0.33 °C/decade and 0.26 °C/decade was observed for winter and summer temperatures, respectively. Warming trends of nighttime minimum temperature are more pronounced than those of daytime maximum temperature, especially during winter season. Consequently, a decreasing trend of diurnal temperatur…

Surface tension and density of binary mixtures of monoalcohols, water and acetonitrile: equation of correlation of the surface tension

2009

Measurements of the surface tension (σ) and density (ρ) of binary mixtures of monoalcohols, water and acetonitrile at 298.15 K and at atmospheric pressure, as a function of mole fraction (x) have been made. The experimental values of the deviation of surface tension and the excess of molar volume (Δσ, V E) have been correlated by the Redlich–Kister equation. An empirical correlation equation is presented for the study of the surface tension of these mixtures, and comparisons are made of the experimental values of surface tension versus those obtained with the correlation equation and with other models of correlation. Finally, with the purpose of corroborating the validity of the correlation…

Nano photoelectron ioniser chip using LaB6 for ambient pressure trace gas detection

2012

A detector including a nanoscaled ioniser chip that surmounts the limitation of conventional photo ionisation detectors is presented. Here, ionisable gaseous substances can be detected by photoelectrons accelerated to the ionisation potential of the incoming gaseous molecules. Thin lanthanum hexaboride (LaB"6) films deposited by pulsed laser technique (PLD) serve as the air stable photocathode material representing the basis of the ioniser chip of the detector. Besides the analysis of the emission behaviour of the photocathode in vacuum and at atmospheric pressure, the detection of different volatile alcohols using the detector with a low-energy UV LED instead of a PID (VUV photon source) w…

Analysis of broadband surface BRDFs derived from TOA SW CERES measurements for surfaces classified by the IGBP land cover

2012

Most studies on the reflectance properties of the Earth's surface are addressed estimating the bidirectional reflectance distribution function (BRDF) of high spatial resolution and high spectral resolution satellite measurements. This article assesses the development of broadband (BB) BRDFs from radiances corresponding to large footprints classified according to the International Geosphere-Biosphere Programme (IGBP) land-cover classification. Top-of-atmosphere (TOA) shortwave (SW) CERES (Clouds and the Earth's Radiant Energy System) measurements are employed to invert the bidirectional reflectance factor (BRF) Rahman–Pinty–Verstraete (RPV) model for regions identified with the same IGBP typ…

Quantum localization and bound state formation in Bose-Einstein condensates

2010

We discuss the possibility of exponential quantum localization in systems of ultracold bosonic atoms with repulsive interactions in open optical lattices without disorder. We show that exponential localization occurs in the maximally excited state of the lowest energy band. We establish the conditions under which the presence of the upper energy bands can be neglected, determine the successive stages and the quantum phase boundaries at which localization occurs, and discuss schemes to detect it experimentally by visibility measurements. The discussed mechanism is a particular type of quantum localization that is intuitively understood in terms of the interplay between nonlinearity and a bou…

First-principles nonequilibrium Green's-function approach to transient photoabsorption: Application to atoms

2015

We put forward a first-principle NonEquilibrium Green's Function (NEGF) approach to calculate the transient photoabsorption spectrum of optically thin samples. The method can deal with pump fields of arbitrary strength, frequency and duration as well as for overlapping and nonoverlapping pump and probe pulses. The electron-electron repulsion is accounted for by the correlation self-energy, and the resulting numerical scheme deals with matrices that scale quadratically with the system size. Two recent experiments, the first on helium and the second on krypton, are addressed. For the first experiment we explain the bending of the Autler-Townes absorption peaks with increasing the pump-probe d…

Compact two-electron wave function for bond dissociation and Van der Waals interactions: A natural amplitude assessment

2014

Electron correlations in molecules can be divided in short range dynamical correlations, long range Van der Waals type interactions and near degeneracy static correlations. In this work we analyze for a one-dimensional model of a two-electron system how these three types of correlations can be incorporated in a simple wave function of restricted functional form consisting of an orbital product multiplied by a single correlation function $f(r_{12})$ depending on the interelectronic distance $r_{12}$. Since the three types of correlations mentioned lead to different signatures in terms of the natural orbital (NO) amplitudes in two-electron systems we make an analysis of the wave function in t…

Long-range interactions and the sign of natural amplitudes in two-electron systems

2013

In singlet two-electron systems the natural occupation numbers of the one-particle reduced density matrix are given as squares of the natural amplitudes which are defined as the expansion coefficients of the two-electron wave function in a natural orbital basis. In this work we relate the sign of the natural amplitudes to the nature of the two-body interaction. We show that long-range Coulomb-type interactions are responsible for the appearance of positive amplitudes and give both analytical and numerical examples that illustrate how the long-distance structure of the wave function affects these amplitudes. We further demonstrate that the amplitudes show an avoided crossing behavior as func…