Search results for "GAS-MIXTURES"
showing 3 items of 3 documents
Femtosecond time resolved coherent anti-Stokes Raman spectroscopy: Experiment and modelization of speed memory effects on H2-N2 mixtures in the colli…
2005
194317; With the aim of temperature diagnostic, femtosecond time-resolved CARS (coherent anti-Stokes Raman spectroscopy) is applied to probe H2 in H2-N2 mixtures. In a first part, a Lorentzian profile is used to model the femtosecond CARS response. A difference between the experimental broadening and the expected one is observed in the collision regime. The observed broadening increases strongly in an inhomogeneous way with respect to the perturber concentration. This is of considerable importance for temperature measurements. In a second part, we show that in the collision regime, this inhomogeneous broadening is due to the speed dependence of the collisional parameters and the memory effe…
Control of rotational wave packets using phase-modulated ultrashort laser pulses
2004
8th Colloquium on Lasers and Quantum Optics SEP 03-05, 2003 Toulouse, FRANCE INSA Toulouse, Univ Paul Sabatier, CNRS, CNES, DGA, ONERA, Minist Rech & Nouvelles Technologies, Soc Francaise Opt, Soc Francaise Phys
Controlling ground-state rotational dynamics of molecules by shaped femtosecond laser pulses
2004
We report controlled excitation of ground-state rotational wave packet by pulse-shaping technique. The experiment is conducted in nitrogen $({\mathrm{N}}_{2})$ at room temperature and atmospheric pressure. A femtosecond laser pulse produces rotational coherences in the vibronic ground state of ${\mathrm{N}}_{2}$ through an impulsive Raman process. The laser pulse is tailored using a spatial light modulator producing spectral phase modulation. Periodic phase steps are applied in order to control the excitation of specific rotational Raman transitions. The outcome is the modification of the relative excitation between odd and even rotational states which allows the control of the symmetry and…