Search results for "GEOM"
showing 10 items of 6506 documents
Modulating the DNA cleavage ability of copper(II) Schiff bases through ternary complex formation
2018
Copper(II) complexes with the potentially tridentate Schiff bases N-[(3-ethoxy-2-hydroxyphenyl)methylidene]-N′-tosylbenzene-1,2-diamine (H2L1) and N-[(2-hydroxynaphthanyl)methylidene]-N′-tosylbenzene-1,2-diamine (H2L2) have been synthesized by electrochemical oxidation of the metal in an electrochemical cell containing a solution of the corresponding ligand in acetonitrile. Adducts of these compounds with 2,2′-bipyridine (2,2′-bpy), 4,4′-bipyridine (4,4′-bpy) or 1,10-phenanthroline (phen) were also obtained. The complexes have been characterized by microanalysis, mass spectrometry, EPR, IR and UV-Vis spectroscopies, as well as DFT calculations. The ligand H2L1 and the compounds [CuL1(H2O)]·…
Magneto-structural correlations in asymmetric oxalato-bridged dicopper(II) complexes with polymethyl-substituted pyrazole ligands
2018
Two oxalato-bridged dinuclear copper(II) complexes, [{Cu(Hdmpz)3}2(μ-ox)](ClO4)2·2H2O (1) and [{Cu(Htmpz)3}2(μ-ox)](ClO4)2·2H2O (2) (Hdmpz = 3,5-dimethyl-1H-pyrazole and Htmpz = 3,4,5-trimethyl-1H-pyrazole), have been synthesized and structurally and magnetically characterized. The crystal structures of 1 and 2 consist of asymmetric bis-bidentate μ-oxalatodicopper(II) complex cations with two short [Cu–O = 1.976(2) (1) and 1.973(2) Å (2)] and two long copper–oxygen bonds [Cu–O = 2.122(2) (1) and 2.110(2) Å (2)]. The environment at each CuII ion in 1 and 2 is closer to the trigonal bipyramidal geometry than to the square pyramidal [τ = 0.633 (1) and 0.711 (2)]. The magnetic properties of 1 a…
Synthesis, crystal structure and magnetic properties of the cyclic tetranuclear compound [Cu4(pz)4(hppa)2(H2O)4] [pz = pyrazolate; hppa = R,S-2-hydro…
2019
Abstract The synthesis, X-ray structure and magnetic properties of the neutral tetranuclear copper(II) complex of formula [Cu4(pz)4(hppa)2(H2O)4] (1) [Hpz = pyrazole and hppa = R,S-2-hydroxo-2-phenyl-2-(1-pyrazolyl)acetate] are reported. Remarkably, the structure of 1 reveals the presence of the S- and R-forms of the new hppa ligand which is formed in situ in the complex reaction between copper(II), pyrazole and phenylmalonate in water:methanol solvent mixture under ambient conditions. The two crystallographically independent copper(II) ions [Cu(1)/Cu(2)] are five-coordinate in square pyramidal surroundings. Three nitrogen atoms, from two pz groups and one hppa ligand and one oxygen atom of…
Surface sediment dynamics along the shore of Hammamet Gulf (Tunisia, southern Mediterranean)
2016
International audience; In the summer of 2015 the authors analysed grain size and surface sediment composition through high spatial resolution from samples taken at 53 stations along the Hammamet coast (southern Mediterranean Sea). The Acoustic Doppler Current Profiler deployed in this study showed that the surface current flows toward the north-east, parallel to the coast at a maximum speed along the main axis of about 5.9 cm s−1. Near the bottom the current flows toward the north-west at a maximum speed of 2.2 cm s−1. The tide plays a relatively small role in water circulation in Hammamet Gulf. Spatial distribution of particle size, along with speed and current direction analysis, furnish…
Measuring rill erosion using structure from motion: A plot experiment
2017
Abstract In this paper the results of a plot experiment on rill erosion are reported. The rill network, manually incised on the soil and further shaped by a clear inflow discharge, was surveyed using the three-dimensional photo-reconstruction (3D-PR) technique which allows to obtain a digital terrain model (DTM) by a large series of oblique images of the channel from consumer un-calibrated and non-metric cameras. The three-dimensional (3D) DTM and the quasi-tridimensional (2.5D) model were generated by Agisoft Photoscan software. For a single rill channel, the reliability of the 3D image-based ground measurements of morphological and hydraulic variables was positively tested by the correspo…
Bathymetric estimation using MERIS images in coastal sea waters.
2007
Bathymetric estimation using remote sensing images has previously been applied to high spatial resolution imagery such as CASI, Ikonos, or SPOT but not on medium spatial resolution images (i.e., MERIS). This choice can be justified when there is a need to map the bathymetry on large areas. In this letter, we present the results of the bathymetry estimation over a large known area, the Gulf of Lion (France), expanding over 270times180 km
Intercomparison of Soil Moisture Retrieved from GNSS-R and from Passive L-Band Radiometry at the Valencia Anchor Station
2019
In this paper, the SOMOSTA (Soil Moisture Monitoring Station) experiment on the intercomparison of soil moisture monitoring from Global Navigation Satellite System Reflectometry (GNSS-R) signals and passive L-band microwave radiometer observations at the Valencia Anchor Station is introduced. The GNSS-R instrument has an up-looking antenna for receiving direct signals from satellites, and a dual-pol down-looking antenna for receiving LHCP (left-hand circular polarization) and RHCP (right-hand circular polarization) reflected signals from the soil surface. Data were collected from the three different antennas through the two channels of Oceanpal GNSS-R receiver and, in addition, calibration …
Assessment of the Potential Evapotranspiration MODIS Product Using Ground Measurements in the Pampas
2018
Evapotranspiration is the hydrological variable of greatest relevance in the Argentina Pampas Region (APR). The estimation of potential evapotranspiration (PET) in this area becomes essential since primary productivity is directly linked to water availability. In order to evaluate the MOD16_A2 product of evapotranspiration (ET), a comparison with in situ measurements was conducted. We used ET data provided by the Oficina de Riesgo Agropecuario, corresponding to 24 stations placed in the region covering all seasons for the years 2012 to 2014. Results show an overestimation of 86% and 52% in Autumn-Winter and Spring-Summer, respectively. Mean Absolut Error (MAE) range between ±0.9 and ±2.1 mm…
Global trends in NDVI-derived parameters obtained from GIMMS data
2011
The Normalized Difference Vegetation Index (NDVI) has been proven to be useful to assess vegetation changes around the world, in spite of limitations such as sensitivity to cloud or snow contamination. In order to map vegetation changes at global scale, this study uses NDVI time series provided by the GIMMS (Global Inventory Modeling and Mapping Studies) group, which were fitted annually to a double logistic function. This fitting procedure allowed for retrieval of NDVI-derived parameters which were tested for trends using Mann-Kendall statistics. These trends were validated by comparison at 73 ground control points documented as change hotspots. The obtained trends for NDVI-derived paramet…
Beyond APAR and NPQ: Factors Coupling and Decoupling SIF and GPP Across Scales
2021
The connection between solar-induced fluorescence (SIF) and vegetation gross primary productivity is being widely investigated across spatial, temporal, and biological scales, including: a) studies at the leaf [1], [2], plant canopy [2]–[4] or satellite pixel scale [5], [6], b) temporally with studies spanning from diurnal [7] to seasonal scales [1], [3], [5], and b) biologically with studies covering various plant functional types (PFTs), e.g., crops [4], [7], deciduous [8] or evergreen forests [1], [3], in response to different sources of stress.