Search results for "GLASS"

Investigation on the influence of the surface resin rich layer on the thermoelastic signal from different composite laminate lay-ups

2006

This work presents a set of experimental results based on the measured thermoelastic signal from GRP composite coupons adopting different lay-ups. A comparison is made with the thermoelastic signal predicted by two different analytical models: one based on the classical law of the thermoelastic effect for orthotropic materials, and the other based on a novel theory accounting for the presence of a resin layer on the external surface of the composite structure. The composite coupons were designed such to determine a significant difference in the predictions made by the two theoretical models. Experimental results have shown a far better match with the predictions based on the novel theory ac…

The dielectric α -relaxation in polymer films: A comparison between experiments and atomistic simulations

2013

The question of whether the glass transition temperature in thin polymer films depends on the film thickness or not has given rise to heated debate for almost two decades now. One of the most puzzling findings is the seemingly universal thickness independence of the dielectric α-relaxation observed for supported films. It is puzzling not only in view of the fact that other techniques or other geometries sometimes showed a significant shift of as a function of film thickness, but more so, because computer simulations for all types of polymer film models revealed changes in the structure and dynamics close to a hard surface or a free surface. Our results suggest to explain this apparent contr…

Direct evidence for glass transition taking place in the surface layers of solution grown crystals of polybutene-1

1969

Proof of the existence of a glass transition in the surface layers of polyethylene single crystals

1970

A Certain Mathematical Model of the Glass Fibre Material Production

1997

There is considered the full mathematical model of chemical reactions on the surface of glass fibre material that was imbedded in the flow of acid solution and was pulled longitudionally. Self-similar forms of this model are obtained and their approximations by monotone schemes of differences are proposed. Some special cases which make possible to get the analytic solutions are underlined. The self-similar forms of the differential equations of the substances transport allow to calculate the emission of the alkaline oxide from the glass fibre material under the influence of the acid solution flow. Some conclusions with practical significance for the technological process is made up accordin…

2D dynamical arrest transition in a mixed nanoparticle-phospholipid layer studied in real and momentum spaces

2015

AbstractWe investigate the interfacial dynamics of a 2D self-organized mixed layer made of silica nanoparticles interacting with phospholipid (DPPC) monolayers at the air/water interface. This system has biological relevance, allowing investigation of toxicological effects of nanoparticles on model membranes and lung surfactants. It might also provide bio-inspired technological solutions, exploiting the self-organization of DPPC to produce a non-trivial 2D structuration of nanoparticles. The characterization of interfacial dynamics yields information on the effects of NPs on the mechanical properties, important to improve performances of systems such as colloidosomes, foams, creams. For thi…

Diphenylsulfone-based hosts for electroluminescent devices: Effect of donor substituents

2020

DG acknowledges to the ERDF PostDoc project No. 1.1.1.2/VIAA/1/16/177. This work was supported by the project of scientific co-operation program between Latvia, Lithuania and Taiwan ?Polymeric Emitters with Controllable Thermally Activated Delayed Fluorescence for Solution-processable OLEDs? (grant No. S-LLT-19-4). Support of the Lithuanian Academy of Sciences is gratefully acknowledged; Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART²

The Schroeder paradox or how the state of water affects the moisture transfer through edible films

2012

The objective of this work was to better understand the water permeation through edible films when water is either in its vapour or in its liquid state related to their physico-chemical properties. Film based on iota-carrageenans or sodium alginate, containing or not fat, and encapsulating or not an aroma compound (n-hexanal) have been prepared. Films were conditioned at three different relative humidities, 0%, 43% and 84%. The incorporation of the n-hexanal in both types of biopolymer modifies the mechanical properties of film matrix and has a synergistic effect when associated to fat. Increasing the moisture content induces film plasticization by decreasing the glass transition of the gly…

A model of oil burnout from glass fabric

1997

A mathematical model is proposed for the process of the removal (by burning) of oil contained in a glass fibre insulation fabric manufactured in Latvia. The small aspect ratio of the fabric allows simplifications to the modelling which reduce the problem to a single nonlinear ordinary differential equation. When the effects of reflected radiation are also included, the differential equation is supplemented by two integral equations. Predictions of the position of the ‘burning zone’ accord well with observations made at the factory. The effect of the inclusion of extra heating chambers is also examined, and it is found that the temperature gradient in the fabric may be greatly decreased in t…

Calorimetric study of myoglobin embedded in trehalose-water matrixes

2009

It has been suggested that in ‘dry’ protein–trehalose–water systems, water–mediated hydrogen bond network, whose strength increases by drying, anchors the protein to its surroundings. To further characterize this effect, we performed a DSC study on low-water myoglobin–trehalose systems. The denaturation temperature resulted to increase by decreasing hydration, and linearly correlated to the glass transition temperature of both the ternary protein–water–trehalose and the binary water–trehalose systems. Further measurements are being performed to investigate eventual differences among different saccharides.