Search results for "GRAPHENE OXIDE"

Graphene oxide and Fumed silica graphene oxide nanocomposites modification by thermal treatments

2014

In the present study we investigate post synthesis thermal treatments up to 400 °C of graphene oxide (GrO) prepared from commercial graphite and of GrO–silica nanocomposites prepared by a solution of commercial Fumed silica nanoparticles (average diameter 7 nm or 40 nm) and the GrO. The thermal treatments were carried out in air, vacuum or He atmosphere to highlight tunable changes. Two GrO batches with small differences in the D (~1350 cm–1) and G (~1580 cm–1) Raman bands have been employed to evaluate effects depending on preparation. Thermal effects have been monitored through the Raman spectroscopy focusing on D, G and 2D (2500–3500 cm–1) bands spectral ranges. The experiments evidenced…

IMPROVED STABILITY OF GRAPHENE OXIDE-SILICA NANOHYBRIDS AND RELATED POLYMER-BASED NANOCOMPOSITES

2014

Although its promising properties make the graphene oxide (GO) very interesting as filler for polymer matrices, some problems related to its thermal stability in the region which ranges from 80 to 200 °C, are crucial for the possibility to melt process GO together with practically all the polymers [1,2]. Moreover, above 100 °C GO lamellae were found to become stacked. In this work, two different ways to preserve the GO structure and ensure its dispersion within different polymer matrices have been investigated and schematized in Fig. 1. Exfoliation plays a key-role in the achievement of good mechanical properties since it preserves the GO from both stacking phenomena. The capability of sili…

Polyamide 6/Graphene Oxide Nanohybrids

2013

Facile and novel synthesis of Graphene oxide/Silica nanohybrids with tunable properties

2013

An Overview of Functionalized Graphene Nanomaterials for Advanced Applications

2021

Interest in the development of graphene-based materials for advanced applications is growing, because of the unique features of such nanomaterials and, above all, of their outstanding versatility, which enables several functionalization pathways that lead to materials with extremely tunable properties and architectures. This review is focused on the careful examination of relationships between synthetic approaches currently used to derivatize graphene, main properties achieved, and target applications proposed. Use of functionalized graphene nanomaterials in six engineering areas (materials with enhanced mechanical and thermal performance, energy, sensors, biomedical, water treatment, and c…

Revealing lattice disorder, oxygen incorporation and pore formation in laser induced two-photon oxidized graphene

2019

Abstract Laser induced two-photon oxidation has proven to be a reliable method to pattern and control the level of oxidation of single layer graphene, which in turn allows the development of graphene-based electronic and optoelectronic devices with an all-optical method. Here we provide a full structural and chemical description of modifications of air-suspended graphene during the oxidation process. By using different laser irradiation doses, we were able to show via transmission electron microscopy, electron energy loss spectroscopy, electron diffraction and Raman spectroscopy how graphene develops from its pristine form up to a completely oxidized, porous and amorphous carbon layer. Furt…

Optimized Deposition of Graphene Oxide Langmuir-Blodgett Thin Films

2014

Abstract Single sheet graphene (SG) is an innovative transparent material with high electrical and thermal conduction the use of which in transparent electrodes instead of traditional materials improves the performance of optoelectronic devices. In this study, graphene oxide (GO) has been obtained by a modified Hummer`s method followed by an advanced technique of water removal (lyophilisation). The Langmuir-Blodgett (LB) method was applied to transfer GO from suspension to substrate. To optimize the deposition process, as suspending and spreading solvents the benzene and benzene/methanol mixtures were chosen instead of previously studied water suspensions. The number of GO layers in suspens…

PREPARATION OF MULTIFUNCTIONAL NANO-STRUCTURED POLYMER NANOHYBRIDS CONTAINING CARBON COMPOUNDS

Photocatalytic H2 evolution from aqueous solutions of oxygenated organic compounds in the presence of C3N4/reduced graphene oxide based photocatalysts

2022

Composites of C3N4/reduced graphene oxide have been used as a cheap and promising photocatalysts for triethanolamine and ethanol photo-reforming with H2 generation in aqueous solution. The rate of H2 production over the best performing photocatalysts reached 1,415 μmol·h-1·g-1 which increases up to 57,306 in the presence of 1% of Pt. The apparent quantum efficiency of the optimal material was 7 % by using both LED and natural sunlight irradiation

Silica as a green exfoliant agent for graphene oxidepolymer nanocomposites prepared in the melt

2017

For the first time, solid-state exfoliant agents were used to hinder the re-aggregation of graphene oxide (GO) during melt processing with polyamide 6 (PA6). This technique drastically reduces the time and difficulty related to solvent (removal, disposal, etc.), and avoids water consumption, since in this case 150 mL of water under mild operative conditions are enough to prepare the amount of GOS necessary for the realization of almost 100 grams of PA6- GOS nanocomposites with outstanding ultimate properties.