Search results for "Galvanization"
showing 10 items of 15 documents
Reliability of numerical models for simulating galvanic corrosion processes
2012
International audience; Maturity of numerical simulation represents an important issue in the development of predictive models of galvanic corrosion. As widely used in electrochemical engineering, a coupled electrochemical-transport-reaction (CETR) model is recommended to simulate the current distribution above a galvanic corrosion cell made of the cut-edge of a galvanized steel sheet. Nevertheless, simulating current density distributions obtained experimentally by scanning vibrating electrode technique (SVET) above such a galvanic cell appears to be more accurate using an electrostatic model considering a homogeneous conductivity. In this case, the absence of concentration gradients next …
Corrosion behaviour of galvanized steel studied by electrochemical microprobes applied on low-angle cross sections
2018
Abstract The combined use of the microcapillary cell (MEC) and scanning vibrating electrode technique (SVET) and low-angle cross sections was employed to elucidate the role of each coating region on the protection of the cut-edge corrosion of galvanized steels. Different compounds are involved in the blocking action of the corrosion products: Zincite (ZnO) on the steel substrate, hydrozincite (Zn5(OH)6(CO3)2) at the coating/steel interface, and Simonkolleite (Zn5(OH)8Cl2) and ZnO on the different coating regions in different proportions. The coating surface is also active at the initial stage and during long-term protection and thus, must be considered in experimental simulation of the cut-…
Heterogeneous crystallization of zinc hydroxystannate on galvanized steel for enhancing the bond strength at the rebar/concrete interface
2021
Abstract Zinc hydroxystannate (ZnSn(OH)6) coatings were deposited on galvanized carbon steel samples by an electroless heterogeneous crystallization process. Structural and morphological features of the coatings as a function of the immersion time were determined by X-ray diffraction, Raman Spectroscopy and Scanning Electron Microscopy revealing the presence of truncated octahedrons of crystalline ZnSn(OH)6. Electrochemical characterization in a simulated concrete pore solution without and with addition of chloride ions proved that the cathodic protection is preserved and that ZnSn(OH)6 improved the corrosion resistance of the rebars. Pull-out tests demonstrated an enhanced bond strength at…
Modeling bimetallic corrosion under thin electrolyte films
2011
A finite element model (FEM) was developed to calculate the potential distribution in the electrolyte in the case of bimetallic corrosion between iron and zinc electrodes, taking into account mass transport of oxygen in the solution. This model was first compared with experimental results obtained by scanning vibrating electrode technique (SVET) on a galvanized steel cut-edge in immersion conditions in a 0.03 M NaCl electrolyte. A good agreement was obtained between the calculated and experimental current densities. The model predicted the evolution of the galvanic coupling as function of the electrolyte thickness and for various iron–zinc surface area ratios. Different coupling regimes wer…
Protective mechanisms occurring on zinc coated steel cut-edges in immersion conditions
2011
Abstract Electrochemical processes occurring on the cut-edge of a galvanized steel immersed in NaCl solutions were studied using numerical simulations, and in situ current and pH profiles measured over the cut-edge. These results clearly demonstrate that only the steel surface remote from the zinc coating is cathodically active, oxygen reduction being strongly inhibited in the vicinity of zinc. This trend was confirmed by local polarization curves recorded on these distinct areas. Ex-situ AES and SEM analysis and cathodic polarization curves in solutions containing Zn 2+ ions led to conclude that this cathodic inhibition was related to the fast nucleation of a dense Zn(OH) 2 film on the ste…
Investigation of self-healing mechanism on galvanized steels cut edges by coupling SVET and numerical modeling
2008
Local cathodic inhibition has been observed on the cut-edge of galvanized steel immersed in 0.03 M NaCl solution using the scanning vibrating electrode technique. The current distribution results indicate that cathodic inhibition occurs in a limited spatial zone located between the cathodic sites on the steel and the anodic sites on the exposed zinc surface. The experimental current distributions are compared with the results of numerical simulations that show the specific diagnostic features for the detection of cathodic inhibition from scanning vibrating electrode technique (SVET) data so as to distinguish the zero current regions from experimental artifacts due to the lateral resolution …
Numerical support for laser welding of zinc-coated sheets process development
2002
Abstract A lap welding process for zinc-coated sheets has been developed with the help of numerical simulations. This process has been improved and is now compatible with industrial requirements. The zinc boiling point (1180 K) is lower than the steel melting point (1800 K). Consequently, a violent boiling of zinc in melted steel produces serious defects in the seam. To get round this difficulty, we choose to consider a two-spots process: the first spot vaporizes the zinc coating at the interface; the second one welds the sheets. Previously, we develop a numerical model that permits a process parameters choice and limits the plan of experimentations. The zinc ablation spotlight shape is cho…
Scheduling in a continuous galvanizing line
2009
In this paper we address a sequencing problem in a Continuous Galvanizing Line of a Spanish Steel Company. Production scheduling in this context is an extremely complex task which needs to take into account many constraints. We present a conceptually simple model and a Tabu Search (TS) algorithm that efficiently solves it. The TS moves are defined in order to repair non-satisfied constraints, leading to smaller and more efficient neighbourhoods. The TS co-ordinates several intensification and diversification procedures guided by an evaluation function based on a shifting penalty strategy. This function reinforces the anticycling mechanism and makes the algorithm avoid already visited soluti…
An integrated approach for the HCl and metals recovery from waste pickling solutions: pilot plant and design operations
2021
Abstract Continuous regeneration of industrial pickling solutions and recovery of valuable materials are implemented in a pilot-scale plant including diffusion dialysis (DD), where HCl is recovered, membrane distillation (MD), where HCl is concentrated, and reactive precipitation (CSTR), where metal ions are recovered in different forms. The integration of the three processes allows to minimize waste streams generation and to accomplish a closed-loop process, thus increasing the environmental sustainability and economic impact of the galvanizing industry. Process reliability was proved through the operation of a demonstrator in the real industrial environment of the Tecnozinco SrL hot-dip g…
Design of a novel membrane-integrated waste acid recovery process from pickling solution
2019
Abstract Hydrochloric acid pickling is a common practice in steel manufacturing industry. During the process, acid is consumed to dissolve surface oxides and metals ions are accumulated in the solution, which becomes less effective with time. In addition, the costly and risky waste acid disposal is another issue affecting the hot-dip galvanizing industry. In this work, a novel sustainable waste acid recovery process from pickling solutions based on circular approach is proposed to tackle these issues. The innovative system allows (i) the continuous regeneration of pickling solutions to enhance process rate and performance and (ii) minimise the highly expensive and environmentally risky wast…