Search results for "Gand"

showing 10 items of 4024 documents

Linear Approximation Property, Minkowski Dimension, and Quasiconformal Spheres

1990

010101 applied mathematicsProperty (philosophy)General Mathematics010102 general mathematicsMathematical analysisMinkowski–Bouligand dimensionSPHERESLinear approximation0101 mathematics01 natural sciencesMathematicsJournal of the London Mathematical Society
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Computational volumetric reconstruction of integral imaging with improved depth resolution considering continuously non-uniform shifting pixels

2018

Abstract In this paper, we propose a new computational volumetric reconstruction technique of three-dimensional (3D) integral imaging for depth resolution enhancement by using non-uniform and integer-valued shifting pixels. In a typical integral imaging system, 3D images can be recorded and visualized using a lenslet array. In previous studies, many computational reconstruction techniques such as computational volumetric reconstruction and pixel of elemental images rearrangement technique (PERT) have been reported. However, a computational volumetric reconstruction technique has low visual quality and depth resolution because low-resolution elemental images and uniformly distributed shiftin…

010302 applied physicsIntegral imagingPixelLenslet arrayComputer sciencebusiness.industryMechanical EngineeringResolution (electron density)ComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONÒptica01 natural sciencesAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsVolumetric reconstruction010309 opticsQuality (physics)0103 physical sciencesComputer visionArtificial intelligenceElectrical and Electronic EngineeringbusinessImatges Processament Tècniques digitalsComputingMethodologies_COMPUTERGRAPHICS
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Integral-Imaging display from stereo-Kinect capture

2017

In this paper, we propose a new approach in order to improve the quality of microimages and display them onto an integral imaging monitor. Our main proposal is based on the stereo-hybrid 3D camera system. Originally, hybrid camera system has dissimilarity itself. We interpret our method in order to equalize the hybrid sensor's characteristics and 3D data modification strategy. We generate integral image by using synthetic back-projection mapping method. Finally, we project the integral image onto our proposed display system. We illustrate this procedure with some imaging experiments in order to prove an advantage of our approach.

010302 applied physicsIntegral imagingbusiness.industryComputer scienceComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONPoint cloudStereo display01 natural sciencesÒptica Aparells i instrumentsImage (mathematics)010309 opticsComputer graphics (images)0103 physical sciences3d cameraComputer visionArtificial intelligencebusinessThree-Dimensional Imaging, Visualization, and Display 2017
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New fine structures resolved at the ELNES Ti-L2,3 edge spectra of anatase and rutile: comparison between experiment and calculation.

2010

Abstract Anatase and rutile Ti- L 2,3 edge spectra were measured in electron energy loss spectroscopy (EELS) using a transmission electron microscope (TEM) coupled to a CEOS Cs-probe corrector, an omega-type monochromator and an in-column omega-type energy filter fully corrected for 2nd order aberrations. Thanks to the high energy resolution, high electron probe current and high stability achieved under this instrumental configuration, new fine structures, never reported before, were resolved at the L 3 band of both rutile and anatase. The data suggest that new peaks also exist in the L 2 e g band. The experimental spectra are compared with multichannel multiple scattering (MMS) calculation…

010302 applied physicsLigand field theoryAnataseMaterials scienceScatteringElectron energy loss spectroscopyAnalytical chemistry02 engineering and technology[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnology01 natural sciencesMolecular physicsAtomic and Molecular Physics and OpticsSpectral lineElectronic Optical and Magnetic Materialslaw.inventionG bandlaw[ CHIM.MATE ] Chemical Sciences/Material chemistry0103 physical sciences0210 nano-technologyElectronic band structureInstrumentationComputingMilieux_MISCELLANEOUSMonochromator
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Exploring the transport properties of equatorially low coordinated erbium single ion magnets

2019

Single-molecule spin transport represents the lower limit of miniaturization of spintronic devices. These experiments, although extremely challenging, are key to understand the magneto-electronic properties of a molecule in a junction. In this context, theoretical screening of new magnetic molecules provides invaluable knowledge before carrying out sophisticated experiments. Herein, we investigate the transport properties of three equatorially low-coordinated erbium single ion magnets with C3v symmetry: Er[N(SiMe3⁠)2⁠]3⁠ (1), Er(btmsm)3⁠ (2) and Er(dbpc)3⁠ (3), where btmsm=bis(trimethylsilyl)methyl and dbpc=2,6-di-tert-butyl-p-cresolate. Our ligand field analysis, based on previous spectros…

010302 applied physicsLigand field theoryMaterials scienceCondensed Matter - Mesoscale and Nanoscale PhysicsSpintronicschemistry.chemical_elementFOS: Physical sciences02 engineering and technology021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesElectronic Optical and Magnetic MaterialsMagnetic fieldErbiumchemistryChemical physicsMagnet0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)MiniaturizationMolecule0210 nano-technologyGround state
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Integral imaging with Fourier-plane recording

2017

Integral Imaging is well known for its capability of recording both the spatial and the angular information of threedimensional (3D) scenes. Based on such an idea, the plenoptic concept has been developed in the past two decades, and therefore a new camera has been designed with the capacity of capturing the spatial-angular information with a single sensor and after a single shot. However, the classical plenoptic design presents two drawbacks, one is the oblique recording made by external microlenses. Other is loss of information due to diffraction effects. In this contribution report a change in the paradigm and propose the combination of telecentric architecture and Fourier-plane recordin…

010302 applied physicsMicrolensDiffractionIntegral imagingPlane (geometry)Computer sciencebusiness.industryComputationComputingMethodologies_IMAGEPROCESSINGANDCOMPUTERVISIONOblique case01 natural sciencesÒptica Aparells i instruments010309 opticssymbols.namesakeFourier transformOptics0103 physical sciencessymbolsComputer visionDepth of fieldArtificial intelligenceFourier Anàlisi debusinessThree-Dimensional Imaging, Visualization, and Display 2017
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MD Simulation Investigation on the Binding Process of Smoke-Derived Germination Stimulants to Its Receptor

2019

Karrikins (KARs) are a class of smoke-derived seed germination stimulants with great significance in both agriculture and plant biology. By means of direct binding to the receptor protein KAI2, the compounds can initiate the KAR signal transduction pathway, hence triggering germination of the dormant seeds in the soil. In the research, several molecular dynamics (MD) simulation techniques were properly integrated to investigate the binding process of KAR1 to KAI2 and reveal the details of the whole binding event. The calculated binding free energy, -7.00 kcal/mol, is in good agreement with the experimental measurement, -6.83 kcal/mol. The obtained PMF profile indicates the existence of thre…

010304 chemical physicsProtein ConformationChemistryGeneral Chemical EngineeringGerminationGeneral ChemistryPlasma protein bindingMolecular Dynamics SimulationLibrary and Information SciencesLigand (biochemistry)01 natural sciences0104 chemical sciencesComputer Science Applications010404 medicinal & biomolecular chemistryMolecular dynamicsProtein structure0103 physical sciencesMoleBiophysicsThermodynamicsMoleculeSignal transductionReceptorPlant ProteinsProtein BindingJournal of Chemical Information and Modeling
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Catalytic epoxidation using dioxidomolybdenum(VI) complexes with tridentate aminoalcohol phenol ligands

2019

Reaction of the tridentate aminoalcohol phenol ligands 2,4-di-tert-butyl-6-(((2 hydroxyethyl)(methyl)amino)methyl)phenol (H2L1) and 2,4-di-tert-butyl-6-(((1-hydroxybutan-2-yl)amino)methyl)phenol (H2L2) with [MoO2(acac)2] in methanol solutions resulted in the formation of [MoO2(L1)(MeOH)] (1) and [MoO2(L2)(MeOH)] (3), respectively. In contrast, the analogous reactions in acetonitrile afforded the dinuclear complexes [Mo2O2(μ-O)2(L1)2] (2) and [Mo2O2(μ-O)2(L2)2] (4). The corresponding reactions with the potentially tetradentate ligand 3-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)propane-1,2-diol (H3L3) led to the formation of the mononuclear complex [MoO2(L3)(MeOH)] (5) in methanol whi…

010402 general chemistry01 natural sciencesMedicinal chemistryCatalysisInorganic Chemistrychemistry.chemical_compoundkatalyytitepoxidationMaterials ChemistryPhenolMoietyPhysical and Theoretical ChemistryHydrogen peroxideAcetonitrileta116010405 organic chemistryLigandmolybdenum complexSubstrate (chemistry)kompleksiyhdisteettrinuclear structure0104 chemical scienceschemistrytridentate ligandMethanolmolybdeeniInorganica Chimica Acta
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The Taming of Redox‐Labile Phosphidotitanocene Cations

2019

International audience; Tame d0 phosphidotitanocene cations stabilized with a pendant tertiary phosphane arm are reported. These compounds were obtained by one-electron oxidation of d1 precursors with [Cp2Fe][BPh4]. The electronic structure of these compounds was studied experimentally (EPR, UV/Vis, and NMR spectroscopy, X-ray diffraction analysis) and through DFT calculations. The theoretical analysis of the bonding situation by using the electron localization function (ELF) shows the presence of π-interactions between the phosphido ligand and Ti in the d0 complexes, whereas dπ–pπ repulsion prevents such interactions in the d1 complexes. In addition, CH–π interactions were observed in seve…

010402 general chemistry01 natural sciencesRedoxTransition metal phosphidesCatalysisFrustrated Lewis pairlaw.inventionchemistry.chemical_compoundFrustrated Lewis Pair (FLP)[CHIM.ANAL]Chemical Sciences/Analytical chemistrylaw[CHIM.COOR]Chemical Sciences/Coordination chemistryPhosphorus LigandsElectron paramagnetic resonanceDiphenylacetyleneComputingMilieux_MISCELLANEOUSTitanium[CHIM.ORGA]Chemical Sciences/Organic chemistry010405 organic chemistryLigandOrganic Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryGeneral ChemistryNuclear magnetic resonance spectroscopyElectron localization function0104 chemical sciencesHomolysis[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryDensity Functional Theory (DFT)Crystallographychemistry[CHIM.CHEM]Chemical Sciences/CheminformaticsChemistry – A European Journal
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Oxidovanadium(V) amine bisphenolates as epoxidation, sulfoxidation and catechol oxidation catalysts

2017

Air-stable oxidovanadium(V) complexes with tetradentate amine bisphenolate ligands were made by the reaction of VOSO4·xH2O and ligand precursors in MeOH solutions. Isolated compounds were studied as catechol oxidase models as well as catalysts for epoxidation and sulfoxidation reactions. All compounds can catalyse such oxidation reactions without notable structure-activity correlations. The 51V NMR studies indicate that the complexes turn to the number of different species during the catalytic experiments. peerReviewed

010402 general chemistry01 natural sciencesRedoxvanadiiniCatalysisInorganic ChemistryTurn (biochemistry)chemistry.chemical_compoundMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryCatechol oxidaseta216ta116Catecholbiologycatalysis010405 organic chemistryLigandoxo transferbiomimetic0104 chemical scienceschemistrykatalyysibiology.proteinvanadiumAmine gas treatingInorganic Chemistry Communications
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