Search results for "Gas composition"
showing 10 items of 32 documents
First determination of magma-derived gas emissions from Bromo volcano, eastern Java (Indonesia)
2015
The composition and fluxes of volcanic gases released by persistent open-vent degassing at Bromo Volcano, east Java (Indonesia), were characterised in September 2014 from both in-situ Multi-GAS analysis and remote spectroscopic (dual UV camera) measurements of volcanic plume emissions. Our results demonstrate that Bromo volcanic gas is water-rich (H2O/SO2 ratios of 56-160) and has CO2/SO2 (4.1 +/- 0.7) and CO2/S-tot (3.2 +/- 0.7) ratios within the compositional range of other high-temperature magma-derived gases in Indonesia. H-2/H2O and H2S/SO2 ratios constrain a magmatic gas source with minimal temperature of 700 degrees C and oxygen fugacity of 10(-17)-10(-18) bars. UV camera sensing on …
Magmatic gas percolation through the old lava dome of El Misti volcano
2017
International audience; The proximity of the major city of Arequipa to El Misti has focused attention on the hazards posed by the active volcano. Since its last major eruption in the fifteenth century, El Misti has experienced a series of modest phreatic eruptions and fluctuating fumarolic activity. Here, we present the first measurements of the compositions of gas emitted from the lava dome in the summit crater. The gas composition is found to be fairly dry with a H2O/SO2 molar ratio of 32 ± 3, a CO2/SO2 molar ratio of 2.7 ± 0.2, a H2S/SO2 molar ratio of 0.23 ± 0.02 and a H2/SO2 molar ratio of 0.012 ± 0.002. This magmatic gas signature with minimal evidence of hydrothermal or wall rock int…
Gas emissions and crustal deformation from the Krýsuvík high temperature geothermal system, Iceland
2020
Abstract The Krýsuvik volcanic system is located on the oblique spreading Reykjanes Peninsula, SW Iceland. Since early 2009 the region has been undergoing episodes of localized ground uplift and subsidence. From April–November 2013, we operated near-real time monitoring of gas emissions in Krýsuvik, using a Multi-component Gas Analyzer System (Multi-GAS), collecting data on gas composition from a fumarole (H2O, CO2, SO2, H2S). The dataset in this study, comprises a near-continuous gas composition time series, the quantification of diffuse CO2 gas flux, analytical results for direct samples of dry gas, seismic records, and GPS data. Gas emissions from the Krýsuvik geothermal system were exam…
Total volatile flux from Mount Etna
2008
[1] The Total Volatile (TV) flux from Mount Etna volcano has been characterised for the first time, by summing the simultaneously-evaluated fluxes of the three main volcanogenic volatiles: H2O, CO2 and SO2. SO2 flux was determined by routine DOAS traverse measurements, while H2O and CO2 were evaluated by scaling MultiGAS-sensed H2O/SO2 and CO2/SO2 plume ratios to the UV-sensed SO2 flux. The time-averaged TV flux from Etna is evaluated at ∼21,000 t·day−1, with a large fraction accounted for by H2O (∼13,000 t·day−1). H2O dominates (≥70%) the volatile budget during syn-eruptive degassing, while CO2 and H2O contribute equally to the TV flux during passive degassing. The CO2 flux was observed to…
First multi-GAS based characterisation of the Boiling Lake volcanic gas (Dominica, Lesser Antilles)
2013
We used a Multi-component Gas Analyser System (Multi-GAS) to measure, for the very first time, the composition (H2O, CO2, H2S, SO2) of the volcanic gas plume issuing from the Boiling Lake, a vigorously degassing, hot (T ~ 80-90°C) volcanic lake in Dominica, West Indies. The Multi-GAS captured in-plume concentrations of H2O, CO2 and H2S were well above those typical of ambient atmosphere, while no volcanic SO2 was detected (<0.05 ppm). These were used to derive the Boiling Lake plume characteristic ratios of CO2/H2S (5.2±0.4) and H2O/CO2 (31.4±6). Assuming that other volcanic gas species (e.g., HCl, CO, H2, N2, etc.) are absent in the plume, we recalculated a (air-free) composition fo…
Magmatic Gas Composition Reveals the Source Depth of Slug-Driven Strombolian Explosive Activity
2007
Strombolian-type eruptive activity, common at many volcanoes, consists of regular explosions driven by the bursting of gas slugs that rise faster than surrounding magma. Explosion quakes associated with this activity are usually localized at shallow depth; however, where and how slugs actually form remain poorly constrained. We used spectroscopic measurements performed during both quiescent degassing and explosions on Stromboli volcano (Italy) to demonstrate that gas slugs originate from as deep as the volcano-crust interface (approximately 3 kilometers), where both structural discontinuities and differential bubble-rise speed can promote slug coalescence. The observed decoupling between de…
Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo
2017
Between 2007 and 2011 four measurement campaigns (June 2007, July 2010, June 2011, and December 2011) were carried out at the crater rim of Nyiragongo volcano, DR Congo. Nyiragongo is one of the most active volcanoes in Africa. The ground-based remote sensing technique Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which uses scattered sunlight, the in-situ Multi-Component Gas Analyzer System (Multi-GAS) and alkaline impregnated filter were simultaneously applied during all field trips. The bromine monoxide to sulfur dioxide (BrO/SO2) and carbon dioxide to sulfur dioxide (CO2/SO2) molar ratios were determined, among other ratios. During the different field trips variati…
Plume composition and volatile flux of Nyamulagira volcano, Democratic Republic of Congo, during birth and evolution of the lava lake, 2014-2015
2017
Very little is known about the volatile element makeup of the gaseous emissions of Nyamulagira volcano. This paper tries to fill this gap by reporting the first gas composition measurements of Nyamulagira’s volcanic plume since the onset of its lava lake activity at the end of 2014. Two field surveys were carried out on 1 November 2014, and 13–15 October 2015. We applied a broad toolbox of volcanic gas composition measurement techniques in order to geochemically characterize Nyamulagira’s plume. Nyamulagira is a significant emitter of SO2, and our measurements confirm this, as we recorded SO2 emissions of up to ~ 14 kt/d during the studied period. In contrast to neighbouring Nyiragongo volc…
Multicopter measurements of volcanic gas emissions at Masaya (Nicaragua), Turrialba (Costa Rica) and Stromboli (Italy) volcanoes: Applications for vo…
2017
Abstract. Volcanoes are a natural source of several reactive gases (e.g. sulfur and halogen containing species), as well as non-reactive gases (e.g. carbon dioxide). Besides that, halogen chemistry in volcanic plumes might have important impacts on atmospheric chemistry, carbon to sulfur ratios and sulfur dioxide fluxes are important established parameters to gain information on subsurface processes. In this study we demonstrate the successful deployment of a multirotor UAV (quadcopter) system with custom-made lightweight payloads on board for the compositional analysis and gas flux estimation of volcanic plumes. The various applications and their potential with such new measurement strateg…
Genesis and evolution of the fumaroles of vulcano (Aeolian Islands, Italy): a geochemical model
1981
A geochemical model explaining the presence of fumaroles having different gas composition and temperature at the top of the crater and along the northeastern coast of Vulcano island is proposed. A pressurized biphase (liquid-vapor) reservoir at the depth of about 2 km is hypothesized. Energy and mass balance sheets controlP-T conditions in the system.P-T must vary along a boiling curve of brine as liquid is present. The CO2 content in the steam is governed by the thermodynamic properties of the fluids in the H2-NaCl-CO2 system. On the assumption that oxygen fugacity in the system is between the HM-FMQ oxygen buffers, observed SO2/H2S, CO2/CO, CO/CH4 ratios in the fumarolic gases at the Foss…