Search results for "Gasification"
showing 10 items of 32 documents
Corrosion Resistance of Alloys in IGCC Environment
2001
IGCC recovery boiler materials are subject to severe corrosion in environments composed of a gas mixture (CO-H 2 -H 2 O-CO 2 -H 2 S) and vanadium-containing fly-ash resulting from the combustion of oil residues. This paper presents a study of the corrosion behaviour of two Fe-Ni-Cr austenitic alloys in a typical IGCC environment at 400°C. The alloy composition influences the vanadium incorporated in the corrosion scales during the test, which affects the scale growth process. The valence state (determined by micro-XANES) and the amount of the incorporated vanadium is modified by a subsequent air flow at 400°C.
ENERGY RECOVERY FROM REGASIFICATION OF LNG
2012
The international forecasts on energy consumption in the next future show an increasing trend due also to growing markets, and among this the leading emerging economies connected to BRICS countries (Brazil, Russia, India, China and South Africa). We need more and more energy. On the other side the environmental problem is arising and the climate change is a more and more pressing emergency. The latest environmental disasters, as the oil spill in the Gulf of Mexico in 2010 and the earthquake with the following tsunami in Japan in 2011, struck the public opinion and so, as in many European countries, the nuclear program is under a deep revision or even stopped. So it is necessary to utilize a…
Experimental and fluid dynamic study of continuous supercritical water gasification of glucose
2016
Abstract The supercritical water gasification (SCWG) of glucose as a model compound for H 2 production is studied in term of process development at 25 MPa and 650 °C. Gasification has been investigated using a laboratory scale continuous plant comprising a continuous down flow reactor with a volume of 200 cm 3 , a heat recovery section and pre-heat of the biomass to simulate more closely an industrial design. Feed streams (pure water and glucose solution) are introduced at the top of the vessel and products are extracted from the bottom. The reactor is equipped with various inlet points that allow to modify the inlet position of reacting streams in order to study the effect of stream mixing…
Numerical and Experimental Investigation of Equivalence Ratio (ER) and Feedstock Particle Size on Birchwood Gasification
2017
This paper discusses the characteristics of Birchwood gasification using the simulated results of a Computational Fluid Dynamics (CFD) model. The CFD model is developed and validated with the experimental results obtained with the fixed bed downdraft gasifier available at the University of Agder (UIA), Norway. In this work, several parameters are examined and given importance, such as producer gas yield, syngas composition, lower heating value (LHV), and cold gas efficiency (CGE) of the syngas. The behavior of the parameters mentioned above is examined by varying the biomass particle size. The diameters of the two biomass particles are 11.5 mm and 9.18 mm. All the parameters investigate wit…
Exergy Recovery during LNG Regasification: Electric Energy Production - Part Two
2009
In liquefied natural gas (LNG) regasification facilities, for exergy recovery during regasification, an option could be the production of electric energy recovering the energy available as cold. In a previous paper, the authors propose an innovative process which uses a cryogenic stream of LNG during regasification as a cold source in an improved combined heat and power (CHP) plant. Considering the LNG regasification projects in progress all over the World, an appropriate design option could be based on a modular unit having a mean regasification capacity of 2 × 109 standard cubic meters/year. This paper deals with the results of feasibility studies, developed by the authors at DREAM in the…
Exergy recovery in regasification facilities – Cold utilization: A modular unit
2009
Abstract The paper deals with the problem of cold recovery for direct utilization both in the site of regasification facility and far from it. A modular LNG regasification unit is proposed having the regasification capacity of 2 billion standard cubic meters/year of gas. The modular plant is based on use of a power cycle working with ethane or ethylene which allows operation of cold energy transfer, contained in LNG to be regasified, in a range of temperatures suitable for multipurpose use of cold, reducing regasification process irreversibility. Some electric energy is produced by the power cycle, but the own mission of modular unit proposed is addressed to deliver cold suitable for indust…
Demethanization of aqueous anaerobic effluents using a polydimethylsiloxane membrane module: Mass transfer, fouling and feasibility
2017
Abstract The performance, fouling and feasibility of a polydimethylsiloxane hollow fibre membrane module for in situ methane degasification from the effluent of an Expanded Granular Sludge Bed anaerobic reactor has been investigated. Experiments at different operational conditions were carried out (liquid flow, sweep gas flow and vacuum pressure) with maximum removal efficiency (77%) at lowest flow-rate (0.4 L h−1), highest vacuum gauge pressure (−800 mbar) and liquid flowing in lumen side. Mass transport analysis denoted a considerably higher methane transfer than that predicted (attributed to liquid oversaturation). An enhancement factor for liquid phase has been proposed to correlate the…
Catalytic effect of Ca and K on CO2 gasification of spruce wood char
2015
Abstract Gasification is one route to produce chemicals and liquid fuels from biomass. The gasification of the char is catalyzed by alkali and alkaline earth metals in the biomass. In this work the catalytic effect of calcium (Ca) and potassium (K) on CO2 gasification of spruce wood was studied using a thermo gravimetric analyzer (TGA). The ash-forming elements were first removed from the wood using an acid leaching method. Then, various concentrations of K and Ca were absorbed to the wood by ion-exchange to carboxylic and phenolic groups, impregnation of K2CO3 or physically mixing of CaC2O4. The prepared spruce samples were placed in a mesh holder and gasified in the TGA at 850 °C in 100% …
Safety study of an LNG regasification plant using an FMECA and HAZOP integrated methodology
2015
Abstract A safety analysis was performed to determine possible accidental events in the storage system used in the liquefied natural gas regasification plant using the integrated application of failure modes, effects and criticality analysis (FMECA) and hazard and operability analysis (HAZOP) methodologies. The goal of the FMECA technique is the estimation of component failure modes and their major effects, whereas HAZOP is a structured and systematic technique that provides an identification of the hazards and the operability problems using logical sequences of cause-deviation-consequence of process parameters. The proposed FMECA and HAZOP integrated analysis (FHIA) has been designed as a …
Supercritical water gasification of microalgae and their constituents in a continuous reactor
2016
The supercritical water gasification of Nannochloropsis gaditana microalgae has been studied in term of process development at 24 MPa and 663 °C. Gasification has been investigated using a 200 cm3 down flow reactor working continuously. The effect of microalgae slurry concentration, with or without alkali catalysts, was studied. Moreover, the role played by different constituents of microalgae on gasification was investigated. Particularly, gasification of amino acids, carbohydrates and model mixtures among them was studied. Nannochloropsis gaditana was successfully gasified up to 97.4 wt% as gasification efficiency and 86.0 wt% as carbon efficiency. The product gas is mainly composed of hy…