Search results for "Geochemistry"
showing 10 items of 2967 documents
Abiotic and biotic controls on methane formation down to 2.5 km depth within the Precambrian Fennoscandian Shield
2017
Abstract Despite a geological history characterised by high temperature and pressure processes and organic carbon deprived crystalline bedrock, large amounts of hydrocarbons are found in deep groundwaters within Precambrian continental shields. In many sites, methane comprises more that 80% of the dissolved gas phase reaching concentrations of tens of mmol l −1 . In this study, we used isotopic methods to study the carbon isotope systematics and sources of crustal methane within the Fennoscandian Shield. The main study sites were the Outokumpu Deep Drill Hole and the Pyhasalmi mine in Finland, both of which allow groundwater sampling down to 2.5 km depth and have been previously studied for…
Long-term stability of alpha particle damage in natural zircon
2005
Abstract We report the first discovery of radiation damage haloes generated by alpha particles in zircon. Proterozoic zircon crystals from a potassium-rich leucogranite from the Adirondack Mountains, New York State, have interior regions that are generally low in actinide elements (UO 2 + ThO 2 ≤ 0.02 wt.%) but show a remarkable pattern of heterogeneous metamictisation. The degree of radiation damage in these regions is not uniformly low, as would be expected if it corresponded to the observed actinide distribution patterns and age of the crystals. Rather, radiation damage is significantly increased in the outermost micro-areas of the low-actinide regions. The additional radiation damage …
The geology of Cuba: A brief overview and synthesis
2016
Cuba is the largest island in the Greater Antilles, and its geology records three important episodes: (1) the Jurassic breakup of North and South America (Pangea) and associated passive margin and oceanic sedimentary and magmatic evolution; (2) the sedimentary, magmatic, and metamorphic evolution of an intra-oceanic Cretaceous-Paleogene ophiolite-arc complex; and (3) the Paleogene 'soft collision' and transfer of the NW Caribbean plate (and Cuba) to the North American plate. Thick sequences of Jurassic-Cretaceous strata (conglomerates, sandstones, limestones, dolostones, shales) and interlayered basaltic rocks characterize passive margin sequences preserved in the Guaniguanico terrane (wes…
Towards Understanding the Interconnection between Celestial Pole Motion and Earth’s Magnetic Field Using Space Geodetic Techniques
2021
The understanding of forced temporal variations in celestial pole motion (CPM) could bring us significantly closer to meeting the accuracy goals pursued by the Global Geodetic Observing System (GGOS) of the International Association of Geodesy (IAG), i.e., 1 mm accuracy and 0.1 mm/year stability on global scales in terms of the Earth orientation parameters. Besides astronomical forcing, CPM excitation depends on the processes in the fluid core and the core–mantle boundary. The same processes are responsible for the variations in the geomagnetic field (GMF). Several investigations were conducted during the last decade to find a possible interconnection of GMF changes with the length of day (…
Numerical evidence for thermohaline circulation reversals during the Maastrichtian
2005
[1] The sensitivity of the Maastrichtian thermohaline circulation to the opening/closing of marine communications between the Arctic and North Pacific oceans is investigated through a set of numerical experiments using the model CLIMBER-2 (Earth Model of Intermediate Complexity). We show here that the opening or closing of an Arctic-Pacific marine gateway induces transitions between different equilibrium states of the thermohaline circulation. Sensitivity tests of the inferred modes of thermohaline circulation to atmospheric CO2 level changes have also been explored. An abrupt switch in deep convection from high northern to high southern latitudes, a change consistent with isotopic evidence…
Water vapor increase in the northern lower stratosphere by the Asian monsoon anticyclone observed during TACTS/ESMVal campaigns
2017
Abstract. The impact of air masses from Asia influenced by the Asian monsoon anticyclone on the northern hemispheric stratosphere is investigated based on in-situ measurements. An statistical significant increase in water vapor of about 0.5 ppmv (11 %) and methane up to 20 ppbv (1.2 %) in the extra-tropical stratosphere above a potential temperature of 380 K was detected between August and September 2012 by in-situ instrumentation in the northern hemisphere during the HALO aircraft mission TACTS and ESMVal. We investigate the origin of this water vapor and methane increase with the help of the three-dimensional Lagrangian chemistry transport model CLaMS. We assign the source of the moist ai…
Coralline alga reveals first marine record of subarctic North Pacific climate change
2007
[1] While recent changes in subarctic North Pacific climate had dramatic effects on ecosystems and fishery yields, past climate dynamics and teleconnection patterns are poorly understood due to the absence of century-long high-resolution marine records. We present the first 117-year long annually resolved marine climate history from the western Bering Sea/Aleutian Island region using information contained in the calcitic skeleton of the long-lived crustose coralline red alga Clathromorphum nereostratum, a previously unused climate archive. The skeletal δ18O-time series indicates significant warming and/or freshening of surface waters after the middle of the 20th century. Furthermore, the ti…
Sr/Ca and Mg/Ca ratios of ontogenetically old, long-lived bivalve shells (Arctica islandica) and their function as paleotemperature proxies
2011
International audience; The Sr/Ca and Mg/Ca ratios of many biogenic skeletons provide useful paleotemperature estimates. As yet however, it has remained largely impossible to obtain such information from bivalve shells. In the present study, metal-to-calcium values in the hinge plate (aragonite, outer shell layer) of four ontogenetically old (85 to 374 year-old) specimens of the long-lived bivalve, Arctica islandica, were measured on a LA-ICP-MS. The shells were collected alive in 1868, 1986 and 2003 from three different localities around Iceland. With increasing ontogenetic age and decreasing growth rate, a distinct trend toward increasing Sr/Ca (max. 5.17 mmol/mol) and Mg/Ca values (max. …
Determination of water speciation in hydrous haplogranitic glasses with partial Raman spectra
2020
Abstract We use a mathematical approach to decompose the Raman water band at 3000 cm−1 to 3750 cm−1 into two partial Raman spectra corresponding to the individual Raman activity of the two water species, i.e., molecular water (H2Om) and OH-groups, present in hydrous rhyolitic glasses. The approach is based on a least-squares optimization algorithm and the assumption that the water band can be expressed as a linear combination of two partial Raman spectra. Our model makes no assumptions regarding the shape of the partial Raman spectra. The model input consists of about 700 Raman spectra from hydrous haplogranitic (HPG8) compositions with total water contents from 0.6 to 3.1 wt% and with know…
Zipper junctions: A new approach to the intersections of conjugate strike-slip faults
2016
Intersecting pairs of simultaneously active faults with opposing slip sense present geometrical and kinematic problems. Such faults rarely offset each other but usually merge into a single fault, even when they have displacements of many kilometers. The space problems involved are solved by lengthening the merged fault (zippering up the conjugate faults) or splitting it (unzippering). This process can operate in thrust, normal, and strike-slip fault settings. Examples of conjugate pairs of large-scale strike-slip faults that may have zippered up include the Garlock and San Andreas faults in California (USA), the North and East Anatolian faults (Turkey), the Karakoram and Altyn Tagh faults (…