Search results for "Geochemistry"
showing 10 items of 2967 documents
A facies distribution model controlled by a tectonically inherited sea bottom topography in the carbonate rimmed shelf of the Upper Tithonian–Valangi…
2016
The Upper Tithonian–Valanginian shallow-water carbonates outcropping in the Palermo Mts (NW Sicily) consist of several facies associations reflecting different depositional environments of a carbonate rimmed shelf, pertaining to the Southern Tethyan continental margin. The reconstructed depositional model, based on the sedimentological features, cyclic facies arrangement and biota distribution, shows that a wide protected lagoon, dominated by algae, molluscs and scattered patch reefs, was bordered landward by a tidal flat, where stromatolitic algal mats were cyclically subaerial exposed, and seaward by a marine sand belt and reef complex. Oolitic packstone-grainstone lithofacies, cyclically…
Redox estimates through trace elements partitioning: application on two Italian volcanoes, model comparison and overview on different geodynamic envi…
2021
Oxygen fugacity of Earth’s mantle is one of the most debated issues of petrology. While is evident that the arc-related magmas are more oxidized than MORB and intraplate magmas, however, is not yet possible to produce a model that can uniquely determine this thermodynamic parameter for the depth of the Earth. Furthermore, there is not a clear cause that create this difference of redox conditions between volcanic products. Recently, several experimental models based on the V partitioning between olivine and mafic melt were published and proposed as tools for investigating the redox state of mantle melts for different geodynamic environments. During this PhD we have applied different oxybarom…
Short-period volcanic gas precursors to phreatic eruptions: Insights from Poás Volcano, Costa Rica
2016
Texto completo del documento Volcanic eruptions involving interaction with water are amongst the most violent and unpredictable geologic phenomena on Earth. Phreatic eruptions are exceptionally difficult to forecast by traditional geophysical techniques. Here we report on short-term precursory variations in gas emissions related to phreatic blasts at Poás volcano, Costa Rica, as measured with an in situ multiple gas analyzer that was deployed at the edge of the erupting lake. Gas emitted from this hyper-acid crater lake approaches magmatic values of SO2/CO21–6 days prior to eruption. The SO2flux derived from magmatic degassing through the lake is measureable by differential optical absorpti…
Absolute acidity of clay edge sites from ab-initio simulations
2012
International audience; We provide a microscopic understanding of the solvation structure and reactivity of the edges of neutral clays. In particular we address the tendency to deprotonation of the different reactive groups on the (0 1 0) face of pyrophyllite. Such information cannot be inferred directly from titration experiments, which do not discriminate between different sites and whose interpretation resorts to macroscopic models. The determination of the corresponding pKa then usually relies on bond valence models, sometimes improved by incorporating some structural information from ab-initio simulations. Here we use density functional theory based molecular dynamics simulations, comb…
A methodological system for hydraulic heritage assessment: a management tool
2016
Traditional irrigation systems are spatial units with a remarkable cultural and heritage value, which in turn generate water landscapes. They are part of hydraulic heritage, which includes material, ideational and symbolic assets. However, the assets related to historical irrigation systems and their landscape units have been poorly studied and evaluated. This paper develops a methodological system for the assessment of hydraulic heritage which combines basic and multi-criteria quantitative techniques. The authors conducted an evaluation of water heritage assets and their associated systems for the purpose of establishing a hierarchy for devising appropriate heritage management actions.
Natural and anthropogenic influences on the geochemistry of Quaternary lake sediments from Holzmaar, Germany
1997
The accumulation of heavy metals and trace elements has been investigated in a well laminated sequence of Holocene and late Pleistocene lake sediments composed of diatomaceous gyttja, tuff and silt and clay sediments. Varve chronology of the annually deposited gyttja yielded a continuous high-resolution time sequence and allowed the absolute age dating of the sediment. Fluxes of elements remained largely uniform from the late Pleistocene into the Holocene. Higher trace element and heavy metal fluxes occur from 2322 to 862 VT years ago (VT: varve time, years before 1950) and reached their maxima in the uppermost sediments (<845 VT years ago). These increasing element fluxes correlate with in…
The role of pedogenic overprinting in the obliteration of parent material in some polygenetic landscapes of Sicily (Italy)
2016
Abstract Many soils older than the Holocene have experienced several changes, and possess properties that may be due to the complex effect of several stages of soil development; these soils are called polygenetic. It is still rather unclear, however, if, as time elapses, pedogenic processes tend to diverge generating different soils, or converge towards increasingly similar soils. We studied five pedons (37°60′N, 13°90′E) exposed to present weathering simultaneously since the Holocene but located on Upper Miocene or Holocene parent material. Their XRD and FTIR clay mineralogy reveal an overall homogeneity; smectites, calcite and gypsum reach the thermodynamic equilibrium, a slight undersatu…
A new FESEM procedure for assessment of XRD microstructural data of kaolinites
2007
Abstract A sample preparation method for FESEM microstructural analysis of sheet silicates using oriented aggregates on metallic strips parallel to the electronic beam is described. The method allows the easy measurement of thickness of kaolinite crystallites. The results have been compared to the apparent crystallite size measured by XRD The performed measurements for a set of selected kaolinites are in the range 15–60 nm and show a good correlation with XRD crystallite thickness (in the range 11–48 nm) obtained by the Voigt function method.
Generation of CO2-rich melts during basalt magma ascent and degassing
2013
International audience; To test mechanisms of basaltic ma gma degassing, continuous decompressions of volatile-bearing (2.7-3.8 wt% H2O, 600-1300 ppm CO2) Stromboli melts were performed from 250-200 to 50-25 MPa at 1180-1140°C. Ascent rates were varied from 0.25 to ~ 1.5 m/s. Glasses after decompression show a wide range of textures, from totally bubble-free to bubble-rich, the latter with bubble number densities from 104 to 106/cm3, similar to Stromboli pumices. Vesicularities range from 0 to ~ 20 vol%. Final melt H2O concentrations are homogeneous and always close to solubilities. In contrast, the rate of vesiculation controls the final melt CO2 concentration. High vesicularity charges ha…
A golden era for volcanic gas geochemistry?
2022
The exsolution, rise, expansion, and separation of volatiles from magma provide the driving force behind both effusive and explosive volcanic eruptions. The field of volcanic gas geochemistry therefore plays a key role in understanding volcanism. In this article, we summarize the most important findings of the past few decades and how these shape today’s understanding of volcanic degassing. We argue that the recent advent of automated, continuous geochemical monitoring at volcanoes now allows us to track activity from unrest to eruption, thus providing valuable insights into the behavior of volatiles throughout the entire sequence. In the next 10 years, the volcanological community stands t…