Search results for "Geochemistry"

Higher-order Hamilton–Jacobi perturbation theory for anisotropic heterogeneous media: dynamic ray tracing in Cartesian coordinates

2018

With a Hamilton–Jacobi equation in Cartesian coordinates as a starting point, it is common to use a system of ordinary differential equations describing the continuation of first-order derivatives of phase-space perturbations along a reference ray. Such derivatives can be exploited for calculating geometrical spreading on the reference ray and for establishing a framework for second-order extrapolation of traveltime to points outside the reference ray. The continuation of first-order derivatives of phase-space perturbations has historically been referred to as dynamic ray tracing. The reason for this is its importance in the process of calculating amplitudes along the reference ray. We exte…

Spectroscopic methods applied to zircon

2003

Natural and synthetic (pure and doped) zircon (ZrSiO4) have been studied with a variety of spectroscopic techniques. These techniques are based on different physical phenomena, for instance transitions between spin states of nuclei and electrons, energetic transitions of valence electrons, intra-molecular vibrations, or vibrations of atoms and molecular units in the lattice. All of the diverse spectroscopic techniques, however, have in common that they probe energy differences between a ground and excited states, mostly upon interaction of the mineral with incident radiation. Such interactions are not only determined by the excited elementary particles or molecules themselves but depend gre…

Seasonal and Inter-annual Variation of Evapotranspiration in Amazonia Based on Precipitation, River Discharge and Gravity Anomaly Data

2019

We analyzed seasonal and spatial variations of evapotranspiration (ET) for five Amazon sub-basins and their response to the 2015/16 El Nino episode using a recently developed water-budget approach. ET varied typically between similar to 7 and 10 cm/month with exception of the Xingu basin for which it varied between 10 and 15 cm/month. Outstanding features of ET seasonality are (i) generally weak seasonality, (ii) two ET peaks for the two very wet catchments Solimoes and Negro, with one occurring during the wet season and one during the drier season, and (iii) a steady increase of ET during the second half of the dry season for the three drier catchments (Madeira, Tapajos, Xingu). Peak ET oc…

Spring to summer changes in the West African monsoon through NCEP/NCAR reanalyses (1968–1998)

2002

[1] This article focuses on the spring to summer evolutions of the West African monsoon from an energetic point of view; it uses NCEP/NCAR reanalyses along with observed and simulated rainfall data over the period 1968–1998. The results show that the West African monsoon can be viewed as a coupled ocean-atmosphere-land system phased with the zenithal evolution of solar radiation which maintains its thermally direct circulation by pumping, from the surface, enthalpy mainly in spring and latent energy in summer. In this context the horizontal energy gradients in the boundary layer play a key role during the spring to summer transition. At the beginning of spring, the moist static energy (MSE)…

Monitoring of Cueva Larga, Puerto Rico—A First Step to Decode Speleothem Climate Records

2017

This study presents results of an ongoing cave monitoring program at Cueva Larga, Puerto Rico. The monitoring includes monthly analyses of stable isotope ratios of rain and drip water, and trace element ratios of drip water and cave air parameters. Drip sites are above growing speleothems offering the unique chance to calibrate geochemical variations in speleothems in order to reconstruct past climate conditions. Seasonal rainfall patterns above Cueva Larga show characteristic stable isotope values. The wet season is characterized by more negative δ18O and δD values and a maritime deuterium excess (+10‰). The dry season has more positive δ18O and δD values and elevated deuterium excess (>15…

Climate Adjustments over Africa Accompanying the Indian Monsoon Onset

2010

Abstract Rainfall and circulation changes accompanying the Indian monsoon onset are examined, focusing on the African continent and neighboring areas. The Indian Meteorological Department official monsoon onset dates over Kerala (MOK; on average on 1 June) are used. Composites are formed at a pentad (5 days) time scale to compare pre- and postonset conditions. Climate Prediction Center (CPC) Merged Analysis of Precipitation (CMAP) data for 1979–2007 indicate that a substantial rainfall decrease over several parts of Africa is associated with MOK. Significant rainfall anomalies, after removal of the mean seasonal cycle, are found in eastern Africa and the nearby western Indian Ocean. Indian …

2016

AbstractDetermining the manganese concentration in shells of freshwater bivalves provides a unique way to obtain information about climate and environmental changes during time-intervals that pre-date instrumental data records. This approach, however, relies on a thorough understanding of how manganese is incorporated into the shell material –a point that remained controversial so far. Here we clarify this issue, using state-of-the-art X-ray absorption and X-ray emission spectroscopy in combination with band structure calculations. We verify that in the shells of all studied species manganese is incorporated as high-spin Mn2+, i.e. manganese always has the same valence as calcium. More impo…

New evidence of mantle heterogeneity beneath the Hyblean Plateau (southeast Sicily, Italy) as inferred from noble gases and geochemistry of ultramafi…

2012

Abstract We analyzed major and trace elements, Sr and Nd isotopes in ultramafic xenoliths in Miocenic age Hyblean diatremes, along with noble gases of CO2-rich fluid inclusions hosted in the same products. The xenoliths consist of peridotites and pyroxenites, which are considered to be derived from the upper mantle. Although the mineral assemblage of peridotites and their whole-rock abundance of major elements (e.g., Al2O3 = 0.8–1.5 wt.%, TiO2 = 0.03–0.08 wt.%) suggest a residual character of the mantle, a moderate enrichment in some incompatible elements (e.g., LaN/YbN = 9–14) highlights the presence of cryptic metasomatic events. In this context a deep silicate liquid is considered the me…

A structural comparison of halloysite nanotubes of different origin by Small-Angle Neutron Scattering (SANS) and Electric Birefringence

2018

The structure of halloysite nanotubes (Hal) from different mines was investigated by Small-Angle Neutron Scattering (SANS) and Electric Birefringence (EBR) experiments. The analysis of the SANS curves allowed us to correlate the sizes and polydispersity and the specific surfaces (obtained by a Porod analysis of the SANS data) of the nanotubes with their specific geological setting. Contrast matching measurements were performed on patch Hal (from Western Australia) in order to determine their experimental scattering length density for a more precise analysis. Further characterization of the mesoscopic structure of Hal was carried out by Electric Birefringence (EBR), which allowed to study th…

Element variability in the coralline alga Lithophyllum yemenense as archive of past climate in the Gulf of Aden (NW Indian Ocean)

2017

This study presents the first algal thallus (skeleton) archive of Asian monsoon strength and Red Sea influence in the Gulf of Aden. Mg/Ca, Li/Ca, and Ba/Ca were measured in Lithophyllum yemenense from Balhaf (Gulf of Aden) using laser ablation inductively coupled plasma mass spectrometry, and Mg/Ca ratio oscillation was used to reconstruct the chronology (34 y). Oscillations of element rates corresponding to the algal growth between 1974 and 2008 were compared with recorded climate and oceanographic variability. During this period, sea surface temperatures (SST) in Balhaf recorded a warming trend of 0.55 degrees C, corresponding to an increase in Mg and Li content in the algal thallus of 2.…