Search results for "Geochemistry"
showing 10 items of 2967 documents
Environmental control on granular clinoforms of ancient carbonate shelves
2006
The purpose of this paper is to document the influence of depositional environments on shallow-water, low-relief clinoforms from the description of five ancient carbonate platforms: the Neoproterozoic (Namibia), Middle Jurassic (France), Lower Cretaceous (France), Upper Cretaceous (Oman) and Miocene (Turkey). These examples have been investigated on the basis of field observations. The clinoforms are described with reference to geometric and compositional attributes: declivity, shape, height, sedimentary structures, sediment fabric and components. The results show great variability in stratal geometry, declivity and facies distribution: (1) depositional profiles vary from exponential, to si…
Garnet as a monitor for melt–rock interaction: Textural, mineralogical, and compositional evidence of partial melting and melt‐driven metasomatism
2021
International audience; In this study, we focus on a partially melted garnet-bearing granulite from the Salvador–Esplanade Belt (Salvador da Bahia, Brazil), and examine the behaviour of major and trace elements during partial melting and melt-driven metasomatism. Phase equilibria modelling and U–Th– Pb geochronology show that the sample underwent partial melting during the heating segment of the decompression path from ~1.2 GPa and 675–700° C to ~0.8 GPa and 790°C at c. 2.06 Ga. During the final stage of decompression, from 0.8 to ~0.5 GPa, physical segregation of melt resulted in the establishment of chemical potential gradients and mass transfer between the host granulite and the leucosom…
U-Pb zircon geochronology and phase equilibria modelling of a mafi c eclogite from the Sumdo complex of south-east Tibet: insights into prograde zirc…
2017
Abstract The Sumdo complex is a Permian–Triassic eclogitic metamorphic belt in south-east Tibet, which marks the location of a suture zone that separates the northern and southern Lhasa terranes. An integrated geochronological and petrological study of a mafic eclogite from the complex has constrained its tectonometamorphic history and provides a case study of zircon growth in eclogite as a product of prograde dissolution–precipitation. In situ U–Pb geochronology indicates that the eclogite contains a single population of zircon with a crystallisation age of 273.6 ± 2.8 Ma. The morphology and chemistry of the zircon grains are consistent with growth by dissolution–precipitation of protolith…
Ba/Ca ratios in shells of Arctica islandica —Potential environmental proxy and crossdating tool
2017
Abstract Ba/Ca shell time-series of marine bivalves typically show flat background levels which are interrupted by erratic sharp peaks. Evidence from the literature indicates that background Ba/Ca shell ratios broadly reflect salinity conditions. However, the causes for the Ba/Ca shell peaks are still controversial and widely debated although many researchers link these changes to primary productivity, freshwater input or spawning events. The most striking feature is that the Ba/Ca shell peaks are highly synchronous in contemporaneous specimens from the same population. For the first time, we studied Ba/Ca shell in mature and ontogenetically old (up to 251 year-old) specimens of the long-li…
Coastal New Particle Formation: A Review of the Current State-Of-The-Art
2005
Environmental Context.Atmospheric aerosols play an important role in determining the earth’s radiative budget, climate change and air quality levels. Much effort has been spent on quantifying the impact of aerosols on climate change; however, the largest gap in our knowledge relates to quantifying natural aerosol systems and the new particle formation process associated with these systems. The marine aerosol system is of particular interest due to the 70% ocean coverage of the earth’s surface. Coastal new particle formation events are though to be more frequent and of stronger intensity compared with open ocean events and thus have been studied in detail to identify possible processes lead…
Quantification of Coastal New Ultra-Fine Particles Formation from In situ and Chamber Measurements during the BIOFLUX Campaign
2005
Environmental Context. Secondary processes leading to the production of ultra-fine particles by nucle- ation are still poorly understood. A fraction of new particles formed can grow into radiatively active sizes, where they can directly scatter incoming solar radiation and, if partly water soluble, contribute to the cloud condensation nuclei population. New particle formation events have been frequently observed at the Mace Head Atmospheric Research Station (western Ireland), under low tide and sunny conditions, leading to the hypothesis that new particles are formed from iodo-species emitted from macroalgae. Abstract. New particle formation processes were studied during the BIOFLUX campaig…
Age, lithology and structural evolution of the c. 3.53 Ga Theespruit Formation in the Tjakastad area, southwestern Barberton Greenstone Belt, South A…
2009
Abstract A field and petrographic re-assessment of rocks from the Theespruit Formation near Tjakastad, southwestern Barberton Greenstone Belt, is combined with new zircon U–Pb ages and whole-rock Sm–Nd isotopic results to reveal several important inconsistencies with a previous thrust-accretion model for this area. It was found that faults previously interpreted as ‘thrusts’ are extensional, ‘thrust slices of basement orthogneiss’ are little deformed quartz-feldspar porphyries or sheared felsic volcaniclastic sedimentary rocks, and ‘sedimentary diamictites’ are felsic agglomerates. These observations, combined with consistent facing directions of bedding, the recognition of distinct stratig…
Ancient xenocrystic zircon in young volcanic rocks of the southern Lesser Antilles island arc
2017
Abstract The Lesser Antilles arc is one of the best global examples in which to examine the effects of the involvement of subducted sediment and crustal assimilation in the generation of arc crust. Most of the zircon recovered in our study of igneous and volcaniclastic rocks from Grenada and Carriacou (part of the Grenadines chain) is younger than 2 Ma. Within some late Paleogene to Neogene (~ 34–0.2 Ma) lavas and volcaniclastic sediments however, there are Paleozoic to Paleoarchean (~ 250–3469 Ma) xenocrysts, and Late Jurassic to Precambrian zircon (~ 158–2667 Ma) are found in beach and river sands. The trace element characteristics of zircon clearly differentiate between different types o…
The use of shallow dripwater as an isotopic marker of seepage in karst areas: A comparison between Western Sicily (Italy) and the Harz Mountains (Ger…
2013
Abstract The isotopic signature of slow-flowing dripwater collected in caves located in Western Sicily (Italy) was determined for evaluating its possible use as an isotopic tracer of the local groundwater recharge. These spot measures were compared with a longer series of local rain and spring compositions and with other samples taken, under different hydrogeological conditions, in caves of the Harz Mountains (Northern Germany). The slow flowing dripwater from Sicily showed δ 18 O/δD ratios similar to those of local rain and groundwater, demonstrating that these three are all parent waters. A parallel similarity was found in the vertical isotopic gradient (Δδ 18 O) of the three groups of wa…
Benchmark study of undrained triaxial testing of Opalinus Clay shale: Results and implications for robust testing
2021
Triaxial testing of argillaceous rocks and shales is significantly more challenging than conventional rock mechanical testing. The challenges are mainly related to the very low permeability of these geomaterials, and their sensitivity to exposure of atmosphere and brines, which induces variations of water content, suction and effective stress. There are currently no international standards to guide service laboratories for robust testing procedures for shales. A benchmark study of undrained triaxial testing was therefore initiated with three leading service laboratories in shale testing, performing 13 tests and using two different methods of establishing sample saturation prior to deformati…