Search results for "Geochemistry"
showing 10 items of 2967 documents
Using calculated chemical potential relationships to account for coronas around kyanite: an example from the Bohemian Massif
2010
Corona textures around kyanite, involving for example zoned plagioclase separating kyanite from the matrix, reflect the instability of kyanite with the matrix on changing P-T conditions, commonly related to decompression. The chemical potential gradients set up between the kyanite and the matrix as a consequence of slow Al diffusion drive corona development, with the zoning of the plagioclase reflecting the gradients. Calculated mineral equilibria are used to account for corona textures involving plagioclase ± garnet around kyanite, and replacement of kyanite by plagioclase + spinel symplectite, in quartz + plagioclase + K-feldspar + garnet + kyanite granulite facies gneiss from the Blanský…
Trace metal modeling of groundwater–gas–rock interactions in a volcanic aquifer: Mount Vesuvius, Southern Italy
2005
We report a detailed study of trace metals in groundwaters from the Somma-Vesuvius volcanic complex and present a model of the chemical processes that control the fate of these components during gas–water–rock interactions. Trace metal concentrations in Vesuvian groundwaters range from 0.01 to 0.1 Ag/l for ultra-trace elements (Sb, Cs, Co, Cd, and Pb) up to 0.1–10 mg/l for minor elements (Fe and Sr), leading to water–rock ratios from ~0.5 to 10 � 9 when normalized to trace element concentrations in the host rocks. Our results indicate non-isochemical dissolution of local volcanic rocks by groundwaters, during which mobile trace elements (As, Se, Mo, V, Li) are enriched and elements such as …
Chemical and isotopic characterization of the gases of Mount Etna (Italy)
1997
Abstract In the period 1990–1995, 43 samples of dissolved gases in groundwaters (wells, springs and drainage galleries) and 64 samples of free gases (fumaroles, bubbling and soil gases) from the Mount Etna area were collected and analysed. Isotopic analyses were also carried out of both the carbon of the CO 2 in free gases and dissolved inorganic carbon (DIC) in the waters. The chemical composition of the gases depends on the relative abundances of three interacting components. These are gases of (1) atmospheric origin enriched in O 2 and N 2 , present almost exclusively in dissolved gases, (2) deep origin enriched in CO 2 , prevalent in the majority of cases, and (3) more superficial origi…
Rapid oxidation of mercury (Hg) at volcanic vents: Insights from high temperature thermodynamic models of Mt Etna's emissions
2011
A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna's magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna's vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. Thes…
Volcanic SiO2-cristobalite: A natural product of chemical vapor deposition
2020
Abstract Cristobalite is a low-pressure, high-temperature SiO2 polymorph that occurs as a metastable phase in many geologic settings, including as crystals deposited from vapor within the pores of volcanic rocks. Such vapor-phase cristobalite (VPC) has been inferred to result from silica redistribution by acidic volcanic gases but a precise mechanism for its formation has not been established. We address this by investigating the composition and structure of VPC deposited on plagioclase substrates within a rhyolite lava flow, at the micrometer to nanometer scale. The VPC contains impurities of the form [AlO4/Na+]0—coupled substitution of Al3+ charge-balanced by interstitial Na+—which are ty…
Minor and trace elements in olivines as probes into early igneous and mantle melting processes
2013
Abstract The trace element composition of olivine is a rapidly growing research area that has several applications of great potential. Mantle olivines can be distinguished from volcanic olivines by lower concentrations of Ca (
Variation of olivine composition in the volcanic rocks in the Songliao basin, NE China: lithosphere control on the origin of the K-rich intraplate ma…
2016
Abstract Lithospheric thickness and the heterogeneity of the mantle lithosphere are two major parameters that play a role in determining the final composition of the mafic melts and their minerals. The Songliao basin in northeast China represents an ideal natural laboratory to study the effect of these two parameters on early Pliocene to Holocene K-rich mafic lavas (K2O > 4 wt.%; K2O/Na2O > 1). A series of Cenozoic volcanic edifices (Erkeshan, Wudalianchi, Keluo and Xiaogulihe) are tentatively divided into three groups (Group 1 — thin, Group 2 — middle, and Group 3 — thick) according to the lithosphere thickness. They are located in the northern region of the Songliao basin extending in a n…
Does second phase content control the evolution of olivine CPO type and deformation mechanisms? A case study of paired harzburgite and dunite bands i…
2021
Abstract We have examined the microstructures and crystallographic preferred orientations (CPOs) of six “paired” harzburgite and dunite samples from a small (~ 1 km2) area in the Ellis Stream Complex, Red Hills Massif, Dun Mountain ophiolite belt in New Zealand. Here, banded peridotites with isoclinal folds, E-W striking vertical foliations and vertical lineations are inferred to result from shear on vertical planes that overprint previous mantle structures. The samples contain five different olivine CPOs: typically known as A, C, D, E and AG-types. The co-located harzburgite and dunite of each pair show different CPOs (e.g., A vs E type). In each pair, dunite generally has larger grain siz…
Lamproites as indicators of accretion and/or shallow subduction in the assembly of south-western Anatolia, Turkey
2010
IntroductionThe Western Anatolian region of Tur-key is tectonically one of the mostcomplex parts of the Alpine–Himala-yan orogenic belt (Fig. 1) because ofits long accretional palaeotectonicevolution. One of the major tectonicfeatures shaping the structure ofwestern Anatolia is the Menderesmetamorphic massif, which consistsof several assembled and imbricatedterranes exhumed during the exten-sion that affected the entire Aegeanprovince during the Late Miocene(Yilmaz et al., 2000; Okay, 2002).The Menderes Massif is usually inter-preted as a core complex delineated bylow-angle detachment faults (Bozkurtand Park, 1994; Hetzel et al., 1995;Ring et al., 2003). An alternativeexplanation associates …
The olivine macrocryst problem: New insights from minor and trace element compositions of olivine from Lac de Gras kimberlites, Canada
2015
This study presents detailed petrographical and geochemical investigations on remarkably fresh olivines in kimberlites from the EKATI Diamond Mine™ located in the Tertiary/Cretaceous Lac de Gras kimberlite field within the Slave craton of Canada. Olivine, constituting about 42 vol.% of the analyzed samples, can be divided into two textural groups: (i) macrocrystic olivines, > 100 μm sub-rounded crystals and (ii) groundmass olivines, < 100 μm subhedral crystals. Olivines from both populations define two distinct chemical trends; a “mantle trend” with angular cores, showing low Ca (< 0.1 wt.% CaO) and high Ni (0.3–0.4 wt.% NiO) at varying Mg# (0.86–0.93), contrasts with a “melt trend” typifie…