Search results for "Geochimica"

Analysis of the relationship between chemistry composition and stable isotope signals in coastal sediments: a biogeochemistry study to assess the env…

2008

First gas flux measurements of conduit permeability decrease prior to Strombolian eruption at Stromboli volcano (Italy)

2016

Strombolian eruptions can be described in terms of growth, coalescence, and rise of a gas pocket (aka slug) bursting at the surface of a vent. This model overlooks that the transition to explosive regimes is mostly controlled by the permeability in the upper part of a volcanic conduit. We report here on the first gas flux measurements of Strombolian explosions from a vent that exhibited a significant decrease of passive degassing tens of second prior to the onset of the explosion. This particular explosive activity took place during the July 2014 lava overflows, when the magma level inside the conduit rose up to the crater terrace. The amount of gas that accumulated before the eruption is i…

Multiple origins of methane in fluids circulating in the Othrys ophiolite, central Greece

2018

The complex geology of Greece includes two important parallel running ophiolitic belts. The Othrys Massif in central Greece belongs to westernmost of them. In and around this wide ophiolite outcrop, some cold hyperalkaline and some hypothermal (T < 40°C) alkaline springs are present. Thirty water samples were collected at 17 different sites and both bubbling and dissolved gases were analysed for their chemical (He, Ne, H2, O2, N2, CH4, C2H6, CO2 and H2S) and isotope (He, δ13C-CO2, δ 13C-CH4, δ 2H-CH4) composition. All samples except one have H2S contents below detection limit (10 μmol/mol), whilst H2 (from <2 to 2500 μmol/mol), CO2 (up to 26,000 but generally below 1000 μmol/mol) and …

Il risarcimento del danno ambientale da inquinamento: modelli di analisi geochimica valutazione monetaria di un eco-socio-sistema fluviale in Sicilia.

2014

The use of shallow dripwater as an isotopic marker of seepage in karst areas: A comparison between Western Sicily (Italy) and the Harz Mountains (Ger…

2013

Abstract The isotopic signature of slow-flowing dripwater collected in caves located in Western Sicily (Italy) was determined for evaluating its possible use as an isotopic tracer of the local groundwater recharge. These spot measures were compared with a longer series of local rain and spring compositions and with other samples taken, under different hydrogeological conditions, in caves of the Harz Mountains (Northern Germany). The slow flowing dripwater from Sicily showed δ 18 O/δD ratios similar to those of local rain and groundwater, demonstrating that these three are all parent waters. A parallel similarity was found in the vertical isotopic gradient (Δδ 18 O) of the three groups of wa…

Exploring the explosive‐effusive transition using permanent ultra‐violet cameras

2017

Understanding the mechanisms that cause effusive eruptions is the key to mitigating their associated hazard. Here we combine results from permanent ultraviolet (UV) cameras, and from other geophysical observations (seismic very long period, thermal, and infrasonic activity), to characterize volcanic SO2 flux regime in the period prior, during, and after Stromboli's August–November 2014 effusive eruption. We show that, in the 2 months prior to effusion onset, the SO2 flux levels are 2 times average level. We explain this anomalously high SO2 regime as primarily determined by venting of rapidly rising, pressurized SO2-rich gas pockets produced by strombolian explosions being more frequent and…

Degassing of halogens from basaltic volcanism: Insights from volcanic gas observations

2009

Abstract The currently available data set of S–Cl–F abundances in volcanic gas plumes and high-temperature fumarolic gas samples from basaltic volcanism is reviewed here in the attempt to derive constraints on the modes of halogen degassing from mafic silicate melts. Apart from large volcano-to-volcano variations, reflecting remarkable differences in volatile abundances in the source magmas, each of the explored volcanoes displays large changes of SO2/HCl and SO2/HF ratios with the style of volcanic activity, with HCl/HF staying fairly constant. Halogen abundances are low and SO2/HCl and SO2/HF are high when fresh (volatile-rich) magmas sustain degassing, as during explosive eruptions, at t…

Total volatile flux from Mount Etna

2008

[1] The Total Volatile (TV) flux from Mount Etna volcano has been characterised for the first time, by summing the simultaneously-evaluated fluxes of the three main volcanogenic volatiles: H2O, CO2 and SO2. SO2 flux was determined by routine DOAS traverse measurements, while H2O and CO2 were evaluated by scaling MultiGAS-sensed H2O/SO2 and CO2/SO2 plume ratios to the UV-sensed SO2 flux. The time-averaged TV flux from Etna is evaluated at ∼21,000 t·day−1, with a large fraction accounted for by H2O (∼13,000 t·day−1). H2O dominates (≥70%) the volatile budget during syn-eruptive degassing, while CO2 and H2O contribute equally to the TV flux during passive degassing. The CO2 flux was observed to…

The fumarolic CO2 output from Pico do Fogo volcano (Cape Verde)

2020

The Pico do Fogo volcano, in the Cape Verde Archipelago off the western coasts of Africa, has been the most active volcano in the Macaronesia region in the Central Atlantic, with at least 27 eruptions during the last 500 years. Between eruptions fumarolic activity has been persisting in its summit crater, but limited information exists for the chemistry and output of these gas emissions. Here, we use the results acquired during a field survey in February 2019 to quantify the quiescent summit fumaroles' volatile output for the first time. By combining measurements of the fumarole compositions (using both a portable Multi-GAS and direct sampling of the hottest fumarole) and of the SO2 flux (u…

Halogens in volcanic systems

2009

The transport, degassing and atmospheric release of halogens from active volcanism on Earth have been the 12 focus of increasing interest over the last few decades, and have recently been the subject of the 1st workshop 13 on “Halogens in volcanic systems and their environmental impacts” that was held in December of 2007 at 14 Yosemite Lodge in Yosemite National Park, California. As an introduction to this Chemical Geology special 15 issue, collecting contributions from many of the participants at the workshop, we review here recent 16 advances in this field, including experimental and theoretical investigations of halogen behaviour in volcanic 17 and related magmatic systems. We discuss pr…