Search results for "Geochimica"

Unmanned aerial vehicle measurements of volcanic carbon dioxide fluxes

2008

[i] We report the first measurements of volcanic gases with an unmanned aerial vehicle (UAV). The data were collected at La Fossa crater, Vulcano, Italy, during April 2007, with a helicopter UAV of 3 kg payload, carrying an ultraviolet spectrometer for remotely sensing the SO 2 flux (8.5 Mg d- 1 ), and an infrared spectrometer, and electrochemical sensor assembly for measuring the plume CO 2 /SO 2 ratio; by multiplying these data we compute a CO 2 flux of 170 Mg d -1 . Given the deeper exsolution of carbon dioxide from magma, and its lower solubility in hydro-thermal systems, relative to SO 2 , the ability to remotely measure CO 2 fluxes is significant, with promise to provide more profound…

Gas hazard assessment at the Monticchio crater lakes of Mt. Vulture, a volcano in Southern Italy

2009

Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140 000 years ago during Mt. Vulture volcanos last eruptive activity. Isotopic analyses suggest that CO2 and helium are of magmatic origin; the latter displays 3 He ⁄ 4 He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even though they are loca…

The Monticchio crater lakes: fluid geochemistry and circulation dynamics

2011

The structure of a hydrothermal system from an integrated geochemical, geophysical and geological approach: the Ischia Island case study

2011

The complexity of volcano-hosted hydrothermal systems is such that thorough characterisation requires extensive and interdisciplinary work. We use here an integrated multidisciplinary approach, combining geological investigations with hydrogeochemical and soil degassing prospecting, and resistivity surveys, to provide a comprehensive characterisation of the shallow structure of the south-western Ischia’s hydrothermal system. We show that the investigated area is characterised by a structural setting that, although very complex, can be schematised in three sectors, namely the extra caldera sector (ECS), caldera floor sector (CFS), and resurgent caldera sector (RCS). This contrasted structura…

Hydrothermal circulation on Ischia Island (Southern Italy), revealed by an integrated geochemical, geophysical and geological approach

2011

Volcano-hosted hydrothermal systems are complex geological objects, whose thorough characterisation requires extensive and interdisciplinary work. Indeed, even thought geological, geochemical and geophysical observations offer highly significant but independent information, only an integrated multidisciplinary approach can yield a comprehensive characterisation of the chemical/physical structure of hydrothermal systems. Notwithstanding the extensive application of geological, geochemical and geophysical techniques in geothermal research, there are only a few examples in the literature of concurrent use of the three techniques [Finizola et al., 2002; Zlotnicki et al., 2009]; these studies ov…

Constraints on mantle source and interactions from He-Sr isotope variation in Italian Plio-Quaternary volcanism.

2008

[1] Helium isotope ratios of olivine and pyroxene phenocrysts from Plio-Quaternary volcanic rocks from southern Italy (seven Aeolian Islands, Mt. Vulture, Etna, Ustica, and Pantelleria) range from 2.3 to 7.1 Ra. Importantly, the phenocryst 3He/4He correlate well with whole rock Sr isotopic composition (0.70309– 0.70711), reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near-linear He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr (and …

Preliminary geochemical characterization of gas manifestations in North Macedonia

2020

<p>Like most of the Balkan Peninsula, North Macedonia is a geodynamically active area. As such it has many hydrothermal features and gas manifestations. Until now, no systematic study about the geochemical characterization of the geogenic gases was made before in this country. In August 2019, 24 gas samples were collected in the study area. All, except one collected at Duvalo (soil gas), are gases bubbling or dissolved in thermomineral waters (temperatures from 12 to 66 °C). They were analysed in the laboratory for their chemical (He, Ne, Ar, O<sub>2</sub> , N<sub>2</sub> , H<sub>2</sub&…

Mineralogy of the soils altered by fumarolic activity at Nisyros volcano, Greece

2017

Nisyros is the easternmost island of the South Aegean Active Volcanic arc in Greece. It is an active stratovolcano known for its intense hydrothermal activity. In this study we present the results of the mineralogical analyses of 20 soil samples collected in the caldera area. Samples were analysed through X-ray diffraction and the results allow us to divide them in two groups: Lakki Plain and Stefanos Crater. In their majority the soils of Lakki Plain have a main mineralogical assemblage that consists of quartz, feldspar and gismondine (Ca2Al4Si4O16·9H2O). Gismondine as well as stellerite (CaAl2Si7O18·7H2O), which is appearing in some samples, derive from hydrothermal alteration, whilst wol…

Active real-time analyzers vs. passive/diffusive samplers for hydrogen sulfide (H2S) in air: a critical comparison

2015

Hydrogen sulfide (H2S) is a gas pollutant discharged in air from a large number of natural and anthropogenic sources. Its peculiar rotten-egg smell, causing odor nuisance to neighboring communities, is detectable at concentrations between 0.7 and 42 μg/m3 (Schiffman & Williams, 2005). High H2S concentrations could cause eye irritation, damage to the upper respiratory apparatus and loss of smell. The effects of long-term low level (< 2,800 μg/m3) exposures to H2S are still matter of debate (Bates et al., 2013). Hence, the development of techniques for accurate measurements of H2S in air at a wide range of concentrations is a primary issue in environmental monitoring. Two different app…

Hazard connected to endogenous gas emissions in Greece

2016

Like other geodynamically active areas, Greece is also affected by a large number of geogenic gas manifestations that occur either in form of point sources (fumaroles, mofettes, bubbling gases) or as diffuse soil gas emanations. Geogenic sources could have strong impact on human health. CO2 and H2S are the main gases responsible for acute mortality due to their asphyxiating and/or toxic properties. Gas hazard is often disregarded because in fatal episodes the death cause is often not correctly attributed. Geodynamic active areas can release geogenic gases for million years over wide areas and it is therefore important not to underestimate potential risks. A preliminary estimation of the gas…