Search results for "Geometry"

Large-eddy simulations of turbulent flow with heat transfer in simple and complex geometries using Harwell-FLOW3D

1996

Abstract Large-eddy simulation (LES) results are presented and discussed for the turbulent flow with heat transfer in different geometrical configurations, including a plane channel, a channel bearing transverse square ribs on one of the walls, and a crossed-corrugated air heater. They were obtained using the computational fluid dynamics (CFD) code Harwell-FLOW3D (Release 2), finite-volume grids having up to 423 nodes, and the Smagorinsky subgrid model with several variants regarding near-wall damping and wall boundary conditions. The first problem (plane turbulent Poiseuille flow with heat transfer) was mainly used as a benchmark to investigate the influence of numerical methods (pressure-…

Diffuse ultraviolet erythemal irradiance on inclined planes: a comparison of experimental and modeled data.

2009

Values of measured and modeled diffuse UV erythemal irradiance (UVER) for all sky conditions are compared on planes inclined at 40 degrees and oriented north, south, east and west. The models used for simulating diffuse UVER are of the geometric-type, mainly the Isotropic, Klucher, Hay, Muneer, Reindl and Schauberger models. To analyze the precision of the models, some statistical estimators were used such as root mean square deviation, mean absolute deviation and mean bias deviation. It was seen that all the analyzed models reproduce adequately the diffuse UVER on the south-facing plane, with greater discrepancies for the other inclined planes. When the models are applied to cloud-free con…

The Geometry of a Domed Architecture: A Stately Example of Kārbandi at Bagh-e Dolat Abad in Yazd

2016

This paper analyses the kārbandi of the Hashti pavilion at Bagh-e-Dolat Abad in Yazd. Kārbandi is a spatial system obtained through the projection of a star-shaped drawing onto a curved surface. It is characterised by a complex use of geometry and repetitive symmetry. The analysis of its geometrical aspects contributes to an understanding of the traditional rules underlying the original design. The kārbandi of the octagonal vestibule of the Hashti pavilion consists of a complex roof system that completes the octagonal volume of the room below; its intrados presents a pattern of interlocking ribbed arches. The paper also looks at the drawings, module and proportions of the Hashti pavilion, w…

Courbe d'une fraction rationnelle et courbes de Bézier à points massiques

2019

Modelling polynomial curves or arcs with Bezier curves can be seen as a basis conversion not so easy for the rational curves. The classical representation of Rational curves based on controlled points with non negative weights as in NURBS does not cover all rational curves. This can be fixed by using the rational Bezier representation by mass points that are weighted points with negative or null weights. The curve of any rational function includes arcs denoted as connex components. These curves and their asymptotic lines are here modelled by the use of mass control points. The asymptotic lines are described by a point that are one weighted point or a vector. An algorithm proposes to represe…

Cover Feature: The Missing Link in the Magnetism of Hybrid Cobalt Layered Hydroxides: The Odd–Even Effect of the Organic Spacer (Chem. Eur. J. 3/2021)

2020

Cleavage of Ge–Ge and Sn–Sn Triple Bonds in Heavy Group 14 Element Alkyne Analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2) by Rea…

2016

The reactions of heavier group 14 element alkyne analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with the group 6 transition-metal carbonyls M(CO)6 (M = Cr, Mo, W) under UV irradiation resulted in the cleavage of the E–E triple bond and the formation of the complexes {AriPr4EM(CO)4}2 (1–6), which were characterized by single crystal X-ray diffraction as well as by IR and multinuclear NMR spectroscopy. Single-crystal X-ray structural analyses of 1–6 showed that the complexes have a nearly planar rhomboid M2E2 core with three-coordinate group 14 atoms. The coordination geometry at the group 6 metals is distorted octahedral formed by four carbonyl groups as well as two br…

Coordination Chemistry of Cu2+ Complexes of Small N-Alkylated Tetra-azacyclophanes with SOD Activity

2018

A new tetraaza-pyridinophane macrocycle (L1) N-alkylated with two isopropyl and one methyl groups symmetrically disposed has been prepared and its behavior compared with those of the unsubstituted pyridinophane (L3) and the related compound with three methyl groups (L2). The protonation studies show that, first, a proton binds to the central methylated amine group of L1, while, second protonation leads to a reorganization of the protons that are at this stage attached to the lateral isopropylated amines. The X-ray structure of [HL1]+ agrees with the UV–vis and NMR studies as well as with the results of DFT calculations. The stability of the Cu2+ complexes decreases on increasing the bulkine…

Polymerizable and polymeric zwitterionic surfactants: 1. Synthesis and bulk properties

1991

Abstract The synthesis of a series of permanently zwitterionic surfactant monomers based on sulphobetaines and the preparation of their polymers is described. Solubilities, thermal properties and bulk structures of the zwitterionic polymers are studied with respect to their molecular architecture, and compared with cationic analogues. The various solubilities of the polymers can be correlated with their molecular geometry, enabling differentiation into distinct classes. This behaviour is paralleled by the observed bulk structures of the polymers where distinct classes of superstructures are present. However, independently of the molecular geometry, no thermal transition could be detected fo…

Oxygen atom transfer catalysis by dioxidomolybdenum(VI) complexes of pyridyl aminophenolate ligands

2021

Abstract A series of new cationic dioxidomolybdenum(VI) complexes [MoO2(Ln)]PF6 (2–5) with the tripodal tetradentate pyridyl aminophenolate ligands HL2-HL5 have been synthesized and characterized. Ligands HL2-HL4 carry substituents in the 4-position of the phenolate ring, viz. Cl, Br and NO2, respectively, whereas the ligand HL5, N-(2-hydroxy-3,5-di-tert-butylbenzyl)-N,N-bis(2-pyridylmethyl)amine, is a derivative of 3,5-di-tert-butylsalicylaldehyde. X-ray crystal structures of complexes 2, 3 and 5 reveal that they have a distorted octahedral geometry with the bonding parameters around the metal centres being practically similar. Stoichiometric oxygen atom transfer (OAT) properties of 5 with…

Speciation of tin(II) in aqueous solution: thermodynamic and spectroscopic study of simple and mixed hydroxocarboxylate complexes

2013

This contribution reports the results of potentiometric and Mossbauer investigations on the formation, stability, and structure of binary and ternary mono- and binuclear complexes of Sn2+ with three hydroxocarboxylic ligands (namely L = tartrate, malate, and citrate) and chloride at T = 298.15 K in different ionic media and ionic strengths (0.15 and 1.00 mol dm−3 in NaCl(aq) and 1.00 mol dm−3 in NaNO3(aq)). The stability constants of various simple Sn i H j L (2+−) and mixed Sn i H j L k Cl (2+−−) species obtained in the different experimental conditions are reported, and various speciation diagrams of the simple and mixed systems are shown in different conditions. The sequestering ability …