Search results for "Geophysics"
showing 10 items of 2645 documents
Fast offline data reduction of laser ablation MC-ICP-MS Sr isotope measurements: Via an interactive Excel-based spreadsheet 'SrDR'
2020
Strontium isotopes are applied to a wide range of scientific fields and to different types of sample materials, providing valuable information foremost about provenance and age, but also on diagenetic processes and mixing relationships between different Sr reservoirs. The development of in-situ analytical techniques, such as laser ablation ICP-MS, has improved our understanding of Sr isotope variability in several field of application, because of the possibility to discriminate small-scale changes and their spatial distribution. However, large outputs of Sr isotope data are produced by laser ablation MC-ICP-MS systems, which necessitate of multiple offline steps to correct and assess the da…
Strontium and argon isotopic homogenization of pelitic sediments during low-grade regional metamorphism: The pan-African upper Damara sequence of Nor…
1979
Abstract The fine mineral fractions extracted from pelitic sediments of the Eocambrian upper Damaran Mulden Group were subjected to a detailed isotopic study by the Rb-Sr and K-Ar methods in combination with a mineralogical analysis by X-ray diffractometry. The sediments contain two major parageneses of metamorphic origin which can be related to two separate low-grade regional metamorphic events of anchizonal intensity with temperatures between 250 and 300°C and pressures up to 2 kbar. These events are dated at about 535 m.y. and 455 m.y. respectively (with λ( 87 Rb) = 1.42 × 10 −11 yr −1 ). Anomalously high K-Ar ages on samples from specific stratigraphic horizons can be related to open sy…
Reproducibility of trace element time-series (Na/Ca, Mg/Ca, Mn/Ca, Sr/Ca, and Ba/Ca) within and between specimens of the bivalve Arctica islandica – …
2017
Abstract Trace element time-series in bivalve mollusk shells and other (biogenic) materials can potentially serve as environmental proxies. Yet, the applicability of element-to-calcium ratios is often challenging, because non-environmental factors such as vital effects distort or mask environmental signals. If a trace element time-series is driven by an environmental factor, it should be reproducible within and between coeval specimens of the same species. In the present study, we tested whether time-series of trace element-to-calcium ratios can be reproduced within and between coeval specimens of the bivalve Arctica islandica and thus whether an external signal is encoded in the temporal v…
Controls on strontium and barium incorporation into freshwater bivalve shells ( Corbicula fluminea )
2017
Abstract Trace elements of bivalve shells can potentially serve as proxies of environmental change. However, to reconstruct past environments using the geochemical properties of the shells and determine the degree to which the element levels are biologically influenced, it is essential to experimentally determine the relationship between environmental variables and the element composition of the shells. To disentangle possible controls on the incorporation of strontium and barium into freshwater bivalve shells, we conducted controlled laboratory experiments using the extremely salinity and temperature tolerant Asian clam, Corbicula fluminea as a model species. Bivalves were reared for five …
Recent advances in space-time statistics with applications to environmental data: An overview
2003
[1] This paper introduces a special section based on general environmental scientific problems, with a particular focus on using atmospheric data. All the papers and authors provide the methodology to study, analyze, predict, and evaluate the spatial-temporal behavior and the complicated spatial-temporal structure of the data. The overall aim is to present up-to-date developments in spatial and spatiotemporal statistics in the field of the atmosphere, to present on-going research, and to discuss important problems to be addressed in the near future.
Rapid chemical evolution of tropospheric volcanic emissions from Redoubt Volcano, Alaska, based on observations of ozone and halogen-containing gases
2013
Abstract We report results from an observational and modeling study of reactive chemistry in the tropospheric plume emitted by Redoubt Volcano, Alaska. Our measurements include the first observations of Br and I degassing from an Alaskan volcano, the first study of O 3 evolution in a volcanic plume, as well as the first detection of BrO in the plume of a passively degassing Alaskan volcano. This study also represents the first detailed spatially-resolved comparison of measured and modeled O 3 depletion in a volcanic plume. The composition of the plume was measured on June 20, 2010 using base-treated filter packs (for F, Cl, Br, I, and S) at the crater rim and by an instrumented fixed-wing a…
Early Silurian tholeiitic-boninitic Mailisu ophiolite, South Tianshan, Kyrgyzstan: a geochemical record of subduction initiation
2019
ABSTRACTOphiolite assemblages of the South Tianshan fold-and-thrust-belt (STS) track the sea floor dynamics of the late Cambrian to Carboniferous Turkestan Ocean in the western Central Asian Orogen...
Age and origin of the Böllsteiner Odenwald
2001
The granitoid protoliths of the gneisses of the Bollsteiner Odenwald, a part of the Mid German Crystalline Rise, intruded at 405 ± 3 Ma. This age was obtained by single zircon 207Pb/206Pb evaporation measurements. It is supported by an upper discordia intercept age of 410 ± 11 Ma from single zircon U/Pb data. These granitoids were derived from hybrid magmas according to their geochemical characteristics. Inherited zircon grains with apparent ages of 882 and 1138 Ma further constrain the source heterogeneity. The isotope data with Nd model ages for the granitoid gneisses between 1.3 and 1.7 Ga also underline the involvement of Proterozoic material into the magma sources. Since the geochemica…
Growth patterns of the topshell Phorcus lineatus (da Costa, 1778) in northern Iberia deduced from shell sclerochronology
2019
Combined shell growth pattern and oxygen isotope analysis has become a powerful approach in palaeoclimate and archaeological studies for reconstructing palaeoclimate conditions and littoral exploitation patterns, respectively. Recent investigations have shown that the gastropod Phorcus lineatus (da Costa, 1778) forms its shell in conditions of near equilibrium with the oxygen isotope signature of the seawater environment, demonstrating the utility of this species for reconstruction of sea surface temperature and determination of the season of harvest in archaeological studies. In contrast, the shell growth patterns of this species have received virtually no attention despite providing infor…
Fe-periclase reactivity at Earth's lower mantle conditions: Ab-initio geochemical modelling
2017
Intrinsic and extrinsic stability of the (Mg, Fe) O solid mixture in the Fe-Mg-Si-O system at high P, T conditions relevant to the Earth's mantle is investigated by the combination of quantum mechanical calculations (Hartree-26 Fock/DFT hybrid scheme), cluster expansion techniques and statistical thermodynamics. Iron in the (Mg, Fe) O binary mixture is assumed to be either in the low spin (LS) or in the high spin (HS) state. Un-mixing at solid state is observed only for the LS condition in the 23-42 GPa pressure range, whereas HS does not give rise to un-mixing. LS (Mg, Fe) O un-mixings are shown to be able to incorporate iron by subsolidus reactions with a reservoir of a virtual bridgmanit…