Search results for "German"

showing 10 items of 2468 documents

CCDC 1861473: Experimental Crystal Structure Determination

2018

Related Article: Chris Gendy, Akseli Mansikkamäki, Juuso Valjus, Joshua Heidebrecht, Paul Chuk-Yan Hui, Guy M. Bernard, Heikki M. Tuononen, Roderick E. Wasylishen, Vladimir K. Michaelis, Roland Roesler|2019|Angew.Chem.,Int.Ed.|58|154|doi:10.1002/anie.201809889

(11'-[(1133-tetramethyldisiloxane-13-diyl)bis(methylene)]bis{3-[26-bis(propan-2-yl)phenyl]-imidazol-2-ylidene})-dichloro-germanium-nickel(0) toluene unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952092: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-bromo-germaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952094: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

(1-(2-(t-butylamido)ethyl)-3-mesitylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1952093: Experimental Crystal Structure Determination

2020

Related Article: Xueer Zhou, Petra Vasko, Jamie Hicks, M. Ángeles Fuentes, Andreas Heilmann, Eugene L. Kolychev, Simon Aldridge|2020|Dalton Trans.|49|9495|doi:10.1039/D0DT01960G

(1-(2-(t-butylamido)ethyl)-3-t-butylimidazol-2-ylidene)-germanium tetrakis(tris(trifluoromethyl)methoxy)-aluminiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 954558: Experimental Crystal Structure Determination

2013

Related Article: Zachary D. Brown , Petra Vasko , Jeremy D. Erickson , James C. Fettinger , Heikki M. Tuononen , and Philip P. Power|2013|J.Am.Chem.Soc.|135|6257|doi:10.1021/ja4003553

(22''44''66''-Hexamethyl-11':3'1''-terphenyl)-((22''44''66''-hexamethyl-11':3'1''-terphenyl-2'-yl)(methyl)carbonoimidoyl)-germanium n-hexane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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El puerto de Valencia durante las Germanías: (contribución a su estudio)

1962

(contribución a su estudio) Artículo [El puerto de Valencia durante las Germanías]UNESCO::HISTORIA::Historia por épocas::Historia antiguaHumanidadesGrupo CEl puerto de Valencia durante las Germanías: (contribución a su estudio) Artículo:HISTORIA::Historia por épocas::Historia antigua [UNESCO]Historia
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New low-temperature phosphate glasses as a host for Europium Ions

2021

Abstract Artificial lightining, especially that of light emitting diodes, and telecommunications are penetrating every part of human lives daily. Different compositions phosphate glasses were suggested as a suitable host material for Eu3+ ions. Here rare earth metal ions act as luminescent centers also perturbing the bond order of phosphate glass network comprised of (PO4)3−, [−(O)PO3]2−, [−(O)2PO2]−, [−(O)3PO] structural units, which is indicated by Raman spectroscopy, confirming successful integration of aforementioned ions into the glass material. Glasses doped with Eu3+ ions show their typical photoluminescence spectra in low symmetry environment, consisting of the highest intensity 5D0…

010302 applied physicsMaterials scienceBorosilicate glassMetal ions in aqueous solutionInorganic chemistryDopingchemistry.chemical_elementGermanium02 engineering and technology021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesElectronic Optical and Magnetic MaterialsPhosphate glasssymbols.namesakechemistry0103 physical sciencesMaterials ChemistryCeramics and Compositessymbols0210 nano-technologyEuropiumLuminescenceRaman spectroscopyJournal of Non-Crystalline Solids
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High-Resolution Stimulated Raman Spectroscopy and Analysis of the ν1 Stretching Band of GeD4

2007

The high-resolution stimulated Raman spectrum of the ν1 band of GeD4 with natural isotopic abundance germanium has been recorded. It has been analyzed as part of the ν1/ν3 stretching dyad. The ν1 and ν3 band centers have been deduced for all the isotopologues. Copyright © 2006 John Wiley & Sons, Ltd.

010304 chemical physics010504 meteorology & atmospheric sciencesChemistryAnalytical chemistryHigh resolutionchemistry.chemical_elementNatural abundanceGermanium01 natural sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistrysymbols.namesake[CHIM.THEO] Chemical Sciences/Theoretical and/or physical chemistry0103 physical sciences[ CHIM.THEO ] Chemical Sciences/Theoretical and/or physical chemistrysymbolsGeneral Materials ScienceIsotopologueStimulated ramanSpectroscopyRaman spectroscopySpectroscopyComputingMilieux_MISCELLANEOUS0105 earth and related environmental sciences
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Germanium Dicarbide: Evidence for a T-Shaped Ground State Structure

2017

The equilibrium structure of germanium dicarbide GeC2 has been an open question since the late 1950s. Although most high-level quantum calculations predict an L-shaped geometry, a T-shaped or even a linear geometry cannot be ruled out because of the very flat potential energy surface. By recording the rotational spectrum of this dicarbide using sensitive microwave and millimeter techniques, we unambiguously establish that GeC2 adopts a vibrationally averaged T-shaped structure in its ground state. From analysis of 14 isotopologues, a precise r0 structure has been derived, yielding a Ge–C bond length of 1.952(1) A and an apex angle of 38.7(2)°.

010304 chemical physicsChemistrychemistry.chemical_elementLinear molecular geometryGermanium02 engineering and technology021001 nanoscience & nanotechnology01 natural sciencesMolecular physicsBond lengthCrystallography0103 physical sciencesPotential energy surfaceGeneral Materials ScienceMillimeterIsotopologuePhysical and Theoretical Chemistry0210 nano-technologyGround stateMicrowaveThe Journal of Physical Chemistry Letters
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Cooperative N–H bond activation by amido-Ge(ii) cations

2020

N-heterocyclic carbene (NHC) and tertiary phosphine-stabilized germylium-ylidene cations, [R(L)Ge:]+, featuring tethered amido substituents at R have been synthesized via halide abstraction. Characterization in the solid state by X-ray crystallography shows these systems to be monomeric, featuring a two-coordinate C,N- or P,N-ligated germanium atom. The presence of the strongly Lewis acidic cationic germanium centre and proximal amide function allows for facile cleavage of N-H bonds in 1,2-fashion: the products resulting from reactions with carbazole feature a tethered secondary amine donor bound to a three-coordinate carbazolyl-GeII centre. In each case, addition of the components of the N…

010405 organic chemistryCarbazoleHydrogen bondCationic polymerizationchemistry.chemical_elementGermaniumSubstrate (electronics)010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryAmideAmine gas treatingCarbeneDalton Transactions
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