Search results for "Glass"
showing 10 items of 1153 documents
Ferroelectricity and orientational glass behavior in the [Rbx(NH4)1−x]2SO4system
1996
Abstract The ordering in the electric dipole subsystem of the [Rbx(NH4)1−x]22SO4 family is investigated. The microscopic origin of ferroelectricity for x=0 is discussed, and evidences for the existence of orientational glass behavior in highly substituted crystals are presented.
Shear moduli of two dimensional binary glasses
2012
The shear moduli of two-component glasses in two dimensions are studied within mode coupling theory. Varying the concentration, strong mixing effects are observed along the glass transition lines for two interaction potentials. Nonoverlapping disks with size ratios between 0.3 and 0.9, and point particles interacting with (magnetic) dipoles of strength ratio between 0.1 and 0.6 are considered. Equilibrium structure factors (partially obtained from Monte Carlo simulations) and glass form factors, and perturbative calculations show that a softening of the elastic shear constant of glass upon adding another component arises from a dilution effect of the majority component. For very disparate m…
Triphenylmethyl and triphenylsilyl based molecular glasses for photonic applications
2015
Triphenylmethyl and triphenylsilyl structural fragments can be used to obtain glass forming, solution processable materials from polar chromophore molecules. Large number of compounds has been synthesized taking advantage of this approach, making it possible to identify some structure-property relations. Regarding the non-linear optical (NLO) properties of the given materials it is evident that triphenylmethyl groups help shielding unwanted NLO efficiency limiting dipolar interactions between polar chromophores in solid films. Chromophore stacking is still observed for compounds with large dipole momentum values. The glass transition temperatures of the compounds increase with the molecular…
Theory of heterogeneous viscoelasticity
2015
We review a new theory of viscoelasticity of a glass-forming viscous liquid near and below the glass transition. In our model we assume that each point in the material has a specific viscosity, which varies randomly in space according to a fluctuating activation free energy. We include a Maxwellian elastic term and assume that the corresponding shear modulus fluctuates as well with the same distribution as that of the activation barriers. The model is solved in coherent-potential approximation (CPA), for which a derivation is given. The theory predicts an Arrhenius-type temperature dependence of the viscosity in the vanishing-frequency limit, independent of the distribution of the activatio…
A family of weakest link models for fiber strength distribution
2007
It is well known that the most widely used distribution function for fiber tensile strength, the two-parameter Weibull distribution, does not always adequately describe the experimentally observed fiber strength scatter and the strength dependence on fiber length. To remedy this discrepancy, modifications of the Weibull distribution have been proposed that, while providing a good empirical fit to the strength data, sometimes lack the theoretical appeal of the weakest link models. We derive a family of weakest link models based on the assumption of a two-stage failure process incorporating explicitly the probabilities of flaw initiation and the fiber fracture due to the largest flaw (i.e. th…
Forward rapidity isolated photon production in proton-nucleus collisions
2018
We calculate isolated photon production at forward rapidities in proton-nucleus collisions in the Color Glass Condensate framework. Our calculation uses dipole cross sections solved from the running coupling Balitsky-Kovchegov equation with an initial condition fit to deep inelastic scattering data and extended to nuclei with an optical Glauber procedure that introduces no additional parameters beyond the basic nuclear geometry. We present predictions for future forward RHIC and LHC measurements. The predictions are also compared to updated results for the nuclear modification factors for pion production, Drell-Yan dileptons and $J/\psi$ mesons in the same forward kinematics, consistently c…
Harmonic behavior of trehalose-coated carbon-monoxy-myoglobin at high temperature.
1999
Abstract Embedding biostructures in saccharide glasses protects them against extreme dehydration and/or exposure to very high temperature. Among the saccharides, trehalose appears to be the most effective bioprotectant. In this paper we report on the low-frequency dynamics of carbon monoxy myoglobin in an extremely dry trehalose glass measured by neutron spectroscopy. Under these conditions, the mean square displacements and the density of state function are those of a harmonic solid, up to room temperature, in contrast to D 2 O-hydrated myoglobin, in which a dynamical transition to a nonharmonic regime has been observed at ∼180K (Doster et al., 1989. Nature. 337:754–756). The protective ef…
Predictability of drug encapsulation and release from propylene carbonate/PLGA microparticles.
2020
Abstract Key parameters for microparticle-based parenteral depot formulation development are entrapment efficiency and sustained drug release, which both depend on the intermolecular affinity of the components. Here, partial solubility parameters were evaluated as descriptors for 21 drug substances and 3 polymers in propylene carbonate (PC). Out of these 21 drug substances, eight BCS class II substances (celecoxib, clotrimazole, erythromycin, ibuprofen, indomethacin, itraconazole, lopinavir and ritonavir) were encapsulated using PLGA (Poly(DL-lactide-co-glycolide)) as polymer matrix and PC as a polar aprotic solvent in order to assign microparticle properties to potential affinity-related i…
Pre-stressed translucent panels made of innovative 3D glass components DSC-integrated, for safety and active building façades
2018
The widespread use of glazed envelopes, especially in high-rise buildings, is pushing building designers and researchers to the development of novel solutions for the improvement of their performance. At the University of Palermo, SBskin. Smart Building Skin s.r.l. (an innovative start up and academic spin off) is prototyping precast, pre- stressed and dry-assembled panels made of 3D glass subcomponents, able to reduce the energy consumption of buildings, to produce clean energy and to maintain high level of mechanical resistance against horizontal forces due to winds and earthquakes. The integration of glass subcomponents with third-generation PV technologies -Dye- Sensitized Solar Cells (…
Thermal and optical properties of red luminescent glass forming symmetric and non symmetric styryl-4H-pyran-4-ylidene fragment containing derivatives
2012
Abstract Dyes with amorphous structure deposited from organic solvents and having good fluorescence properties show potential for photonic device applications. Organic glass-forming symmetric and non symmetric styryl- derivatives of 2(2,6-substituted-4H-pyran-4-ylidene)-malononitrile (it has backbone of known laser dye 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran), 2(2,6-substituted-4H-pyran-4-ylidene)-1H-indene-1,3(2H)-dione and 2(2,6-substituted-4H-pyran-4-ylidene)-pyrimidine-2,4,6(1H,3H,5H)-trione were synthesized and investigated. Glass transition temperatures higher than 110 °C were achieved. The absorption bands in dichloromethane solution cover the spectral regi…