Search results for "Gradation"

Study of the effects of salt crystallisation on degradation of limestone rocks

2013

Salt crystallization is widely recognized as a cause of deterioration of porous building materials. In particular, the crystallization pressure of salt crystals growing in confined pores is found to be the main cause for damage. The aim of this study is to better understand the degradation of porous rocks induced by salt crystallisation and correlate such processes with the intrinsic characteristics of materials. With this intend, an experimental salt weathering simulation has been carried out on two limestones widely used in the Baroque architecture of eastern Sicily. A systematic approach including petrographic, porosimetric and colorimetric analyses, was used to evaluate the correlation …

Preliminary studies about thermal degradation of edible oils through attenuated total reflectance mid-infrared spectrometry

2009

Abstract Degradation of edible oils during their heating process has been evaluated through the determination of cis -unsaturation and trans -fatty acids together with free fatty acids as a function of time and temperature heating. Two types of cooking oils, sunflower and seed (mixture of different seeds non-detailed), were heated at three different temperatures (147, 171 and 189 °C) during a total time of 1920 min (32 h) shared out in four sessions of 8 h each one, and samples were studied from their spectra obtained by Fourier transform infrared spectrometry using attenuated total reflectance measurements. A critical comparison between different multivariate calibration models built based…

Short communication: Driftwood provides reliable chronological markers in Arctic coastal deposits

2021

Originating from the boreal forest and often transported over large distances, driftwood characterizes many Arctic coastlines. Here we present a combined assessment of radiocarbon (14C) and dendrochronological (ring width) age estimates of driftwood samples to constrain the progradation of two Holocene beach-ridge systems near the Lena Delta in the Siberian Arctic (Laptev Sea). Our data show that the 14C ages obtained on syndepositional driftwood from beach deposits yield surprisingly coherent chronologies for the coastal evolution of the field sites. The dendrochronological analysis of wood from modern drift lines revealed the origin and recent delivery of the wood from the Lena River catc…

2020

Skeletal muscle atrophy is characterized by a decrease in muscle fiber size as a result of a decreased protein synthesis, which leads to degradation of contractile muscle fibers. It can occur after denervation and immobilization, and glucocorticoids (GCs) may also increase protein breakdown contributing to the loss of muscle mass and myofibrillar proteins. GCs are already used in vitro to induce atrophic conditions, but until now no studies with primary human skeletal muscle existed. Therefore, this study deals with the effects of the GC dexamethasone (dex) on primary human myoblasts and myotubes. After incubation with 1, 10, and 100 µM dex for 48 and 72 h, gene and protein expression analy…

Optimization of Nitrification Process by a Bacterial Consortium in the Submerged Biofiltration System with Ceramic Bead Carrier

2014

Laboratory-scale solid phase submerged system was developed to study the process of ammonium biodegradation. Ceramic beads were found to be an appropriate carrier material for the attachment of thePNN bacterial consortium (Pseudomonas sp., Nitrosomonas sp., Nitrobacter sp.) exhibiting nitrification/denitrification activity. This consortium was previously isolated from a biological activated sludge process at a fish factory wastewater treatment plant. Three organic amendments - molasses, humic acid extract, and malt extract - were used for the ceramic bead pretreatment. Molasses significantly enhanced (p<0.05) the process of bacteria attachment onto the ceramic carrier and further ammonium r…

Influence of design mistakes and material degradation on the collapse of a long-span RC roof in South Italy

2020

Abstract In 2004, during ordinary maintenance work, consisting in the waterproofing of a building located in the South of Italy, the long-span (14.50 m) in situ cast reinforced concrete (RC) roof partially collapsed. The building, constructed in 1950, was in service as a cinema up to 1967 and utilized as a school up to 1985. Finally, it was a hotel up to 2000. In 2004, when the building was not in service and underwent maintenance work, it partially collapsed under the dead load. After the collapse, which involved a large portion of the roof, several beams and two columns, the Court nominated a first Official Technical Consultant in order to investigate on the causes of failure and related …

New flow-multicommutation method for the photo-chemiluminometric determination of the carbamate pesticide asulam

2004

This paper deals with a straightforward automated method for the determination of asulam in water based on the use of a flow manifold including three computer-controlled solenoid valves. The method involves irradiating on an aqueous solution of asulam in glycine buffer at pH 8.3 with UV light during 90 s, then follows the oxidation with potassium permanganate in a sulphuric medium and chemiluminescence-based detection of the resulting photoproducts. The limit of detection thus achieved is 40 mug l(-1). The detector response is linear up to a 5 mg l(-1) asulam concentration and the throughput is 30 samples h(-1). In parallel tests, oxidation with alkaline ferricyanide was also assessed and t…

Flow‐Injection Chemiluminescent Determination of Thiamine in Pharmaceutical Samples by On‐line Photodegradation

2004

Abstract A simple, sensitive, and precise method for the determination of thiamine hydrochloride in a flow‐injection system is described. The method is based on the UV irradiation of thiamine in acid medium. Then, the photo‐fragments are oxidized by permanganate in acid medium, and the resultant chemiluminescent intensity is measured. The optimum conditions for the photoreaction and for the chemiluminescence emission were investigated. The method allows the determination of thiamine, over the range 0.05(LOD)–84 mg · l−1, with a throughput of 30 h−1, and a RSD (n, 20) at 20 and 0.5 mg · l−1 of the thiamine level of 2.5 and 1.3%, respectively. The method was applied to pharmaceutical preparat…

Photochemical-chemiliminometric determination of aldicarb in a fully automated multicommutation based flow-assembly

2004

[EN] A sensitive and fully automated method for determination of aldicarb in technical formulations (Temik) and mineral waters is proposed. The automation of the flow-assembly is based on the multicommutation approach, which uses a set of solenoid valves acting as independent switchers. The operating cycle for obtaining a typical analytical transient signal can be easily programmed by means of a home-made software running in the Windows environment. The manifold is provided with a photoreactor consisting of a 150 cm long x 0.8 mm i.d. piece of PTFE tubing coiled around a 20 W low-pressure mercury lamp. The determination of aldicarb is performed on the basis of the iron(III) catalytic minera…

Analytical strategy photodegradation/chemiluminescence/continuous-flow multicommutation methodology for the determination of the herbicide Propanil

2006

The present paper is dealing with an analytical strategy based on coupling photodegradation, chemiluminescence and multicommutation continuous-flow methodology for the determination of the pesticide Propanil, a common herbicide. The pesticide solution is inserted as small segments sequentially alternated with segments of the solution for adjusting the suitable medium for the photodegradation. Both flow-rates (sample and medium) are adjusted to required time for photodegradation, 2.0 min; and then, the resulting solution is also sequentially inserted as segments alternated with segments of the oxidizing solutions system, 1.00 x 10(-4) mol 1(-1) potassium permanganate in 2.00 mol 1(-1) sulphu…