Search results for "Ground State"
showing 10 items of 928 documents
Compression of Polarized 3He
1991
This article gives a status report on the polarized 3He target development work at Mainz. It is based on the optical pumping of the 3S1 state of 3He with subsequent metastability spin exchange to the ground state atoms. This pumping scheme is very efficient at 3He pressures of about 1 Torr; for high density targets, however, a mechanical compression of the polarized gas is needed in a second step. First results with a Toepler compression pump look promising and will be discussed in the following.
Precision spectroscopy at heavy ion ring accelerator SIS300
2007
Unique spectroscopic possibilities open up if a laser beam interacts with relativistic lithium-like ions stored in the heavy ion ring accelerator SIS300 at the future Facility for Antiproton and Ion Research FAIR in Darmstadt, Germany. At a relativistic factor gamma = 36 the 2P 1/2 level can be excited from the 2S 1/2 ground state for any element with frequency doubled dye-lasers in collinear geometry. Precise transition energy measurements can be performed if the fluorescence photons, boosted in forward direction into the X-ray region, are energetically analyzed with a single crystal monochromator. The hyperfine structure can be investigated at the 2P 1/2 - 2S 1/2 transition for all elemen…
Radiative lifetimes of Am I atomic levels.
1988
The lifetimes of several atomic levels of Am I that are connected by electric dipole transitions to the ground state have been measured. The Am atoms were excited by light pulses from a cw single-mode dye laser with the aid of an optoacoustic modulator. The decay curve of the delayed emitted photons was measured by counting single photons in the beam-off periods. The lifetimes of 14 levels in the wavelength region between 6405 and 4265 A were measured using Am-metal vapor. The metallic Am was obtained by reducing AmO/sub 2/ with La at 1500 /sup 0/C in a high-vacuum system and collecting Am on a catcher foil. The Am vapor was then produced by controlled reevaporation from the foil at a tempe…
On the hexagonal ice-like model of structured water: Theoretical analysis of the low-lying excited states
2014
Abstract The basic molecular unit ( BMU ) of the hexameric ice-like model has been identified as the negatively charged radical species [H 19 O 10 ] − . On the basis of high-level ab initio computations, by means of using the CASPT2 methodology, the low-lying excited states of BMU and its π-stacked dimer are analysed. It is concluded that the BMU constitutes certainly a versatile unit having two spectroscopic features in the near infrared region, two in the visible range and two in the near ultraviolet zone. The main absorption feature is found however for the π-stacked dimer formed by two BMUs , the H 38 O 20 system, which has a pronounced stabilization in the ground state with respect to …
Molecular and electronic structure of square-planar nickel(ii), nickel(iii) and nickel(iii)π-cation radical complexes with a tetradentate o-phenylene…
2005
The molecular and electronic structures of the electron transfer series of four-coordinate square-planar nickel complexes with the ligand o-phenylenebis(N'-methyloxamidate), [NiL]z (z = 2-, 1-, 0), have been evaluated by DFT and TDDFT calculations, and most of their experimentally available structural and spectroscopic properties (X. Ottenwaelder et al., Dalton Trans., 2005, DOI: 10.1039/b502478a) have been reasonably reproduced at the B3LYP level of theory. The anionic species [NiL]2- and [NiL]- are genuine low-spin nickel II and nickel III complexes with diamagnetic singlet (S = 0) and paramagnetic doublet (S = 1/2) states, respectively. The nickel III complex presents shorter Ni-N(amidat…
Detailed studies of $^{100}$Mo two-neutrino double beta decay in NEMO-3
2019
The full data set of the NEMO-3 experiment has been used to measure the half-life of the two-neutrino double beta decay of $^{100}$Mo to the ground state of $^{100}$Ru, $T_{1/2} = \left[ 6.81 \pm 0.01\,\left(\mbox{stat}\right) ^{+0.38}_{-0.40}\,\left(\mbox{syst}\right) \right] \times10^{18}$ y. The two-electron energy sum, single electron energy spectra and distribution of the angle between the electrons are presented with an unprecedented statistics of $5\times10^5$ events and a signal-to-background ratio of ~80. Clear evidence for the Single State Dominance model is found for this nuclear transition. Limits on Majoron emitting neutrinoless double beta decay modes with spectral indices of …
Monte Carlo investigation of head-tail ordering of CO monolayers on graphite
1994
Abstract Heat capacity measurements recently showed that CO physisorbed on graphite undergoes a head-tail ordering transition at roughly 5 K. The present paper is a detailed Monte Carlo study of this phase transition and the ordered state. The simulations are based on an ab initio pair potential and rely crucially on a thorough finite-size scaling study of various quantities. In agreement with experiments we find that the transition belongs to the universality class of the Ising model in two dimensions. We go beyond experimental knowledge by revealing the particular ferrielectric structure of the ground state, and show that the transition is due to the molecule's shape asymmetry rather than…
Signatures of topological phase transitions in Josephson current-phase discontinuities
2016
Topological superconductors differ from topologically trivial ones for the presence of topologically protected zero-energy modes. To date, experimental evidence of topological superconductivity in nanostructures has been mainly obtained by measuring the zero-bias conductance peak via tunneling spectroscopy. Here, we propose an alternative and complementary experimental recipe to detect topological phase transitions in these systems. We show in fact that, for a finite-sized system with broken time-reversal symmetry, discontinuities in the Josephson current-phase relation correspond to the presence of zero-energy modes and to a change in the fermion parity of the groundstate. Such discontinui…
Increasing the Templating Effect on a Bulk Insulator Surface: From a Kinetically Trapped to a Thermodynamically More Stable Structure
2016
Molecular self-assembly, governed by the subtle balance between intermolecular and molecule- surface interactions, is generally associated with the thermodynamic ground state, while the competition between kinetics and thermodynamics during its formation is often neglected. Here, we present a simple model system of a benzoic acid derivative on a bulk insulator surface. Combining high-resolution non-contact atomic force microscopy experiments and density functional theory, we characterize the structure and the thermodynamic stability of a set of temperature-dependent molecular phases formed by 2,5-dihydroxybenzoic acid molecules, self- assembled on the insulating calcite (10.4) surface. We d…
The Ferroelectric Photo-Groundstate of SrTiO$_3$: Cavity Materials Engineering
2021
Significance Controlling collective phenomena in quantum materials is a promising route toward engineering material properties on demand. Strong THz lasers have been successful at inducing ferroelectricity in S r T i O 3 . Here we demonstrate, from atomistic calculations, that cavity quantum vacuum fluctuations induce a change in the collective phase of S r T i O 3 in the strong light–matter coupling regime. Under these conditions, the ferroelectric phase is stabilized as the ground state, instead of the quantum paraelectric one. We conceptualize this light–matter hybrid state as a material photo ground state: Fundamental properties such as crystal structure, phonon frequencies, and the col…