Search results for "Guaiacol"
showing 4 items of 34 documents
Comprehensive valorisation of technically relevant organosolv lignins via anodic oxidation
2021
Lignin represents the largest renewable feedstock of aromatic moieties in nature. However, its valorisation towards organic chemicals poses a challenging task. We herein report the selective electrochemical depolymerisation of several technically relevant organosolv lignins to aromatic fine chemicals with a simple two-electrode arrangement using caustic soda as electrolyte. Vanillin, syringaldehyde, the corresponding ketones and guaiacol were obtained with a combined maximum of 7.8 wt% isolated yield. Deeper insight in the process was provided by FT-IR, HSQC NMR and 31P NMR analyses of the lignins.
Chemical Composition of the Essential Oil of Teucrium flavum ssp. flavum from Zakynthos, Greece
2012
Essential oil extracted from dried aerial parts of Teucrium flavum ssp. flavum harvested in Zakynthos, Greece, was analysed by gas phase chomatography (GC) and gas chomatography mass spectrometry (GC-MS). The main constituents were caryophyllene (13.5%), caryophyllene oxide (8.5%), 4-vinyl guaiacol (6.0%) and α- humulene (5.0%).
Seducin, male sex pheromone of the cockroachNauphoeta cinerea: Isolation, identification, and bioassay.
1990
The male sex pheromone of the cockroachNauphoeta cinerea was isolated from adult sternal glands and identified by gas chromatography-mass spectrometry. This pheromone, which attracts females from a distance, is a multicomponent blend. It is composed principally of three compounds: 3-hydroxy-2-butanone (acetoin), 2-methylthiazolidine, and 4-ethyl-2-meth-oxyphenol. A mixture of synthetic compounds in a ratio of 4∶4∶1 (2700 ng) elicits maximal response and short latency of response by receptive females, similar to that induced by male sternal gland extracts. Tested separately, each compound induces a positive response, but the moving times spent by females are generally longer than with the mi…
Chemical composition of the essential oil of Centaurea grinensis Reuter and Centaurea apiculata Ledeb: Growing wild in Croatia and Bulgaria, respecti…
2016
AbstractIn the present study, the chemical composition of the essential oils from aerial parts of Centaurea grinensis Reuter (K) collected at Žuta Lova, near Senj (Croatia), and aerial parts (L1) and flowers (L2) of C. apiculata Ledeb. collected near Rebro village, near Breznik town, Znepole Region (Bulgaria), both belonging to subgenus Lopholoma (Cass.) Dobrocz, was evaluated by GC and GC-MS. The main components of K were 4-vinyl guaiacol (21.5%), hexadecanoic acid (16.2%), acetophenone (12.5%). Caryophyllene oxide (15.8%) together with sphathulenol (14.5%) and humulene epoxide II (9.4%) were recognized as the main constituent of both the aerial part (L1) and flowers (L2) of C. apiculata. …