Search results for "H2O"

[Cu(tn)]3[Cr(CN)6]2·3H2O: A unique two-dimensional Cu-Cr cyano-bridged ferromagnet (tn = 1,3-diaminopropane)

2002

Reaction of the two-coordinate ‘assembling complex-ligand’ [Cu(tn)]2+ with the building block [Cr(CN)6]32 leads to a unique two-dimensional Cu–Cr cyano-bridged ferromagnet with unusual m3- and m4-bridging [Cu(tn)]2+ units. Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es

Electrochemical Quantification of H2O2 Released by Airway Cells Growing in Different Culture Media

2022

Quantification of oxidative stress is a challenging task that can help in monitoring chronic inflammatory respiratory airway diseases. Different studies can be found in the literature regarding the development of electrochemical sensors for H2O2 in cell culture medium to quantify oxidative stress. However, there are very limited data regarding the impact of the cell culture medium on the electrochemical quantification of H2O2. In this work, we studied the effect of different media (RPMI, MEM, DMEM, Ham’s F12 and BEGM/DMEM) on the electrochemical quantification of H2O2. The used electrode is based on reduced graphene oxide (rGO) and gold nanoparticles (AuNPs) and was obtained by co-electrode…

Ionic Transport through Chemically Functionalized Hydrogen Peroxide-Sensitive Asymmetric Nanopores

2015

We describe the fabrication of a chemical-sensitive nanofluidic device based on asymmetric nanopores whose transport characteristics can be modulated upon exposure to hydrogen peroxide (H2O2). We show experimentally and theoretically that the current-voltage curves provide a suitable method to monitor the H2O2-mediated change in pore surface characteristics from the electronic readouts. We demonstrate also that the single pore characteristics can be scaled to the case of a multipore membrane whose electric outputs can be readily controlled. Because H2O2 is an agent significant for medical diagnostics, the results should be useful for sensing nanofluidic devices.

Effects of H2O2 on mesoangioblast stem cells: survival and cell death

2009

TiO2-H2O Interactions by Fast Field Cycling (FFC) NMR Relaxometry

2010

Selective Photocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxaldehyde by Polymeric C3N4-H2O2 Adduct

2018

Selective Photocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxaldehyde by Polymeric C3N4-H2O2 Adduct

H2O2 INDUCES NECROPTOSIS IN MESOANGIOBLAST STEM CELLS

2018

Stem cells are used in regenerative medicine, but their therapeutic efficacy is compromised by their huge death during the first days post-transplantation. Indeed, the microenvironment within damaged tissues is hostile for stem cell survival mainly due to oxidative stress. H2O2 may play a relevant role in inducing death of the injected cells. The aim of our study was to determine the mechanism of mesoangioblast (A6) cell death after an H2O2 treatment. FACS analysis with annV/PI showed that H2O2 induced a dose and time-dependent decrement in A6 viability. We have also found an increase in caspases 8, 9 and 3 activity after the treatment. To assess their involvement in cell death, the pan cas…

Nanowire Ordered Arrays for Electrochemical Sensing of H2O2

2016

Today, electrochemical sensors are considered very interesting in comparison to conventional techniques because they are very adaptable, cheap, have very low limit of detection and low detection time. The most used electrochemical technique is the amperometry . In amperometric sensors, a fixed potential is applied to the electrochemical cell, and a corresponding current, due to a reduction or oxidation reaction, is then obtained. This current it can be correlated with the bulk concentration of the detecting species (the solute) such as H2O2. Hydrogen peroxide is an essential mediator in food, pharmaceutical, clinical, industrial, and environmental analyses therefore, it is of great importan…

Pd-NWs ordered arrays for electrochemical sensing of H2O2

2016

In this work, we present the performance of nanostructured array of Pd (Pd-NWs) for electrochemical sensors of hydrogen peroxide. Hydrogen peroxide is widely used in several fields, because to its oxidizing and reducing properties, like for treatment of waste water, paper and contaminated soils, as reagent in many chemical industries or like rocket propellant [1]. Furthermore, its presence or absence may be connected with many neurological deseases or/and with cancer [2].Today the most used methods for detection of that chemical are IR spectroscopy, spectrophotometry, fluorimetry, chemioluminescence and redox titration. However these methods are often uneconomical, have very high detection …

H2O, H2, HF, F2 and F2O nuclear magnetic shielding constants and indirect nuclear spin–spin coupling constants (SSCCs) in the BHandH/pcJ‐n and BHandH…

2009

Good performance of segmented contracted basis sets XZP, where X = D, T, Q and 5, for obtaining H2O, H2, HF, F2 and F2O nuclear isotropic shielding constants in the BHandH Kohn–Sham basis set limit was shown. The results of two‐ and three‐parameter complete basis set limit extrapolation schemes were compared with experimental results, earlier literature data and benchmark ab initio results. Similar convergence patterns of shieldings obtained from calculations using general purpose XZP basis sets and from polarization‐consistent basis sets pcS‐n and pcJ‐n, where n = 0, 1, 2, 3 and 4, designed to accurately predict magnetic properties were observed. On the contrary, the SSCCs were more sensit…