Search results for "H3PW12O40"
showing 2 items of 2 documents
Phosphomolybdic acid and mixed phosphotungstic/phosphomolybdic acid chitosan membranes as polymer electrolyte for H2/O2 fuel cells
2017
Abstract Flat, free-standing phosphomolybdic acid and mixed phosphotungstic/phosphomolybdic acid chitosan membranes were prepared by in-situ ionotropic gelation process at room temperature on porous alumina support firstly impregnated by heteropolyacid. Scanning electron microscopy revealed the formation of compact and homogenous polymeric membranes, whose thickness resulted to be dependent on reticulation time, and almost independent on the employed heteropolyacid nature and concentration. X-ray diffraction and Fourier transform infrared spectroscopy evidenced the formation of crystalline membranes without appreciable concentration of unprotonated NH 2 groups and heteropolyacid ions with p…