Search results for "HDI"

Kotouttavat kontaktit : puheenvuoroja maahanmuuttajien kotoutumisesta ja hyvinvoinnista

2018

Käsillä oleva julkaisu on syntynyt SEMPRE-hankkeessa (Social Empowerment in Rural Areas). SEMPRE:n tavoitteena on ollut tarkastella ja vahvistaa maahanmuuttajataustaisten ihmisten sosiaalista osallisuutta. Kehittämistyössä ovat olleet mukana maahanmuuttajien lisäksi Kokkolan ja Pietarsaaren kaupungit sekä näiden kaupunkien alueella kotouttamistyötä tekevät hankkeet, yhdistykset ja yhteisöt. SEMPRE on ulottunut myös Keski-Pohjanmaan ja Pohjanmaan maakuntien pienempiin kuntiin. Erityisesti Veteli on ollut mukana hankkeessa. Tässä hankkeessa käsitetään, että maaseutu tai pienet kaupungit ovat ympäristönä erityisiä maahanmuuttajien osallisuuden näkökulmasta. SEMPRE on osa EU-rahoitteista (Inter…

Removal of ammonium ions from aqueous solutions using alkali-activated analcime as sorbent

2023

Five alkali-activated analcime (ANA) sorbents (ANA-MK 1, ANA 2, ANA 3, ANA-MK 4, and ANA-MK 5) were developed for ammonium (NH4+) ion removal. Acid treatment and calcination were used as pre-treatments for analcime, and metakaolin (MK) was used as a blending agent in three sorbents. Sorption experiments were performed to evaluate the effects of sorbent dosage (1–20 g L−1), initial NH4+ ion concentration (5–1000 g L−1), and contact time (1 min–24 h). ANA-MK 1, ANA 2, and ANA-MK 4 were the most efficient sorbents for NH4+ ion removal, with a maximum experimental sorption uptake of 29.79, 26.00, and 22.24 mg g−1, respectively. ANA 3 and ANA-MK 5 demonstrated…

Transition path selection between ammonium nitrate solid phases IV, III and II

1994

Article dissertation. Contains an introduction and five articles. This study was made of factors affecting the transition paths between ammonium nitrate solid state phases IV, III and II. The effect of the sample preparation method was investigated by differential scanning calorimetry (DSC), transition mechanisms were explored with simultaneous DSC and Raman spectrometry developed for in situ investigation of the transitions, and the relationship between phase IV structure and the transition paths was studies by X-ray powder diffraction (XRD) and DSC. The results were analysed by partial least-squares regression (PLS) and principal component analysis (PCA). [Continues; please see the book]

Testing the effectiveness of pyrazine defences against spiders

2020

Insects live in a dangerous world and may fall prey to a wide variety of predators, encompassing multiple taxa. As a result, selection may favour defences that are effective against multiple predator types, or target-specific defences that can reduce predation risk from particular groups of predators. Given the variation in sensory systems and hunting tactics, in particular between vertebrate and invertebrate predators, it is not always clear whether defences, such as chemical defences, that are effective against one group will be so against another. Despite this, the majority of research to date has focused on the role of a single predator species when considering the evolution of defended…

Molecular and supramolecular structures of self-assembled Cu(II) and Co(II) complexes with 4,4’-[6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4-…

2020

The molecular and supramolecular structures of [Cu(PTM)Cl2]*0.75MeOH (1), [Co(PTM)Cl2]; (2A) and [Co(PTM)Cl2(EtOH)]; (2B) complexes, where PTM is 4,4’-[6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4-diyl]dimorpholine, were presented. In complexes 1 and 2A, the Cu(II) and Co(II) are tetra-coordinated with a distorted tetrahedral coordination environment. In case of complex 2B, an additional ethanol molecule is found coordinated with Co(II) leading to a highly distorted penta-coordinated Co(II) complex. In all cases, the PTM ligand is acting as a bidentate NN-chelate. Hirshfeld surface analysis indicated the importance of H⋯H (49.0–55.1%), Cl⋯H (18.8–20.5%) and O⋯H (8.3–9.9%) contacts in…

Distress, Eustress, or No Stress? Explaining Smartphone Users' Different Technostress Responses

2018

Technostress is common and has harmful consequences. Therefore, researchers have shown increasing interest in explaining technostress in the field of information systems (IS). While extant research merits in identifying the causes and consequences of technostress, it has not explained empirically why information technology (IT) users have different responses to similar potentially stressful IT events. Indeed, events such as smartphone failures can derive negative distress responses for some users and positive eustress responses for others. To address this gap in research, we conducted a qualitative study by interviewing users who had experienced smartphone failures. As a contribution, our f…

Kylätoiminta ja aktiivisen kylän tuottaminen

2012

The 'jytky' of the Finns party : or, how to take advantage of masculinity in populist politics

2018

In this article the authors look at the way leading politicians of the Finns Party have appealed to masculine values. The exceptional rise of the populist party between 2003 and 2015 is seen as a major indicator of the overall rise of ‘masculinist’ values in Finnish politics. However, the question is not only of more masculinist politics, but also of a change in styles of masculinity – a shift towards a plurality of different political styles emphasizing masculine values. This does not preclude the ideological nature of the adherence to those values but sets new challenges to scholarship addressing what has been called backlash of traditional values in recent years in Europe and from 2016 o…

Titanocene Selenide Sulfides Revisited: Formation, Stabilities, and NMR Spectroscopic Properties

2019

[TiCp2S5] (phase A), [TiCp2Se5] (phase F), and five solid solutions of mixed titanocene selenide sulfides [TiCp2SexS5−x] (Cp = C5H5−) with the initial Se:S ranging from 1:4 to 4:1 (phases B–E) were prepared by reduction of elemental sulfur or selenium or their mixtures by lithium triethylhydridoborate in thf followed by the treatment with titanocene dichloride [TiCp2Cl2]. Their 77Se and 13C NMR spectra were recorded from the CS2 solution. The definite assignment of the 77Se NMR spectra was based on the PBE0/def2-TZVPP calculations of the 77Se chemical shifts and is supported by 13C NMR spectra of the samples. The following complexes in varying ratios were identified in the CS2 solutions of …

1,2,6-Thiadiazine 1-Oxides: Unsaturated Three-Dimensional S,N-Heterocycles from Sulfonimidamides.

2020

Unprecedented three-dimensional 1,2,6-thiadiazine 1-oxides have been prepared by an aza-Michael-addition/cyclization/condensation reaction sequence starting from sulfonimidamides and propargyl ketones. The products have been further functionalized by standard cross-coupling reactions, selective bromination of the heterocyclic ring, and conversion into a β-hydroxy substituted derivative. A representative product was characterized by single-crystal X-ray structure analysis. peerReviewed