Search results for "HIF"
showing 10 items of 1515 documents
Solution chemistry of N,N'-ethylenebis(salicylideneimine) and its copper(II), nickel(II) and iron(III) complexes
1991
Abstract Potentiometric determination of protonation-deprotonation equilibria of the N,N'-ethylenebis(salicylideneimine) (H2sal2en), the related N-(2-aminoethyl)salicylideneimine, (Hsalen), and their organic fragments, salicylaldehyde (Hsal) and ethylenediamine (en), has been used to study the equilibria involved in the formation of Schiff bases from Hsal, sal− and en and in their complex formation with copper(II), nickel(II) and iron(III) ions in dimethyl sulfoxide (dmso)-water (80:20 wt./wt.) mixture (25 °C and 0.1 mol dm−3 KClO4 ionic strength): en+Hsal⇔Hsalen; en+2Hsal⇔H2sal2en; en+ sal−⇔salen−; en+2sal−⇔sal2en2−; sal−+en+MN+⇔[M(salen)](n−1)+; 2sal−+en+Mn+⇔ [M(sal2en)](n−2)+. In these t…
Self-assembly of extended Schiff base amino acetate skeletons, 2-{[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)]amino}phenylpropionate and 2-{[(E)-1-(2-h…
2007
The organotin(IV) compounds, [Ph 3 SnL 1 H] n · nCCl 4 ( 1 ), [Me 2 SnL 2 (OH 2 )] ( 2 ), [ n Bu 2 SnL 2 ] ( 3 ), [Ph 2 SnL 2 ] n ( 4 ), [Ph 3 SnL 2 H] n ( 5 ) and [Ph 3 SnL 3 H] n ( 7 ) (L 1 = 2-{[(2 Z )-(3-hydroxy-1-methyl-2-butenylidene)]amino}phenylpropionate and L 2−3 = 2-{[( E )-1-(2-hydroxyaryl)alkylidene]amino}phenylpropionate), were synthesized by treating the appropriate organotin(IV) chloride(s) with the potassium salt of the ligand in a suitable solvent, while [ n Bu 2 SnL 3 (OH 2 )] ( 6 ) was obtained by reacting the acid form of L 3 (generated in situ) with n Bu 2 SnO. These complexes have been characterized by 1 H, 13 C, 119 Sn NMR, ESI-MS, IR and 119m Sn Mossbauer spectro…
Structural Variation and Magneto-Structural Correlation in Two New Dinuclear Bis(µ2-Phenoxo)-Bridged CuII Schiff-Base Complexes: Catalytic Potential …
2010
Two new dinuclear bis(μ2-phenoxo)-bridged copper(ii) complexes [Cu(NCS)L1]2 (1) and [Cu(NCS)L2]2 (2) have been synthesized using two tridentate NNO-donor Schiff-base ligands, L1H (Me2N(CH2)3N=CHC6H3(OMe)(OH)) and L2H (Me2N(CH2)3N=C(CH3)C6H4(OH)), respectively. They have been characterized by elemental analyses, IR, UV-visible, and electron paramagnetic resonance (EPR) spectroscopy, cyclic voltammetry, and magnetic susceptibility measurements. X-Ray single-crystal structures reveal a central Cu2O2 core in each complex with an isothiocyanate ligand coordinated terminally to each metal centre. The coordination environments around the CuII ions in 1 and 2 are a distorted trigonal bipyramid and…
An unprecedented CuII–Schiff base complex existing as two different trinuclear units with strong antiferromagnetic couplings
2009
Abstract A new tetradentate N 2 O 2 donor Schiff base ligand [OHC 6 H 4 CH NCH 2 CH 2 CH(CH 2 CH 3 )N CHC 6 H 4 OH = H 2 L ] was obtained by 1:2 condensation of 1,3-diaminopentane with salicylaldehyde and has been used to synthesise an unusual copper(II) complex whose asymmetric unit presents two structurally different almost linear trinuclear units [Cu 3 (μ- L ) 2 (ClO 4 ) 2 ] [Cu 3 (μ- L ) 2 (H 2 O)(ClO 4 ) 2 ] ( 1 ). The ligand and the complex were characterised by elemental analysis, FT-IR, 1 H NMR and UV–Vis spectroscopy in addition electrochemical and single crystal X-ray diffraction studies were performed for the complex. The magnetic properties of 1 reveal the presence of strong in…
Sterically-controlled nuclearity in new copper(II) complexes with di-compartmental ligands: Formation of antiferromagnetically coupled angular trimer…
2010
Abstract Two new copper(II) complexes, [Cu3(L1)2(H2O)2](ClO4)2 (1) and [CuL2 ⊂ (H2O)] (2) have been derived from two di-compartmental Schiff base ligands H2L1 and H2L2, respectively. Depending on slight modification of the substituent group of the potentially N2O4 donor ligands, tri- and mononuclear structures are obtained, which have been confirmed by single-crystal X-ray diffraction studies. Both complexes have been characterized by elemental analysis, IR, UV–vis and EPR spectroscopy. Complex 1 consists of an angular trinuclear array of copper ions, while complex 2 consists of a mononuclear copper center. Variable temperature magnetic susceptibility measurements have been performed to inv…
Hexanuclear NiII4LnIII2 Complexes with SMM Behavior at Zero Field for Ln = Tb, Dy, Ho
2020
A mononuclear Ni(II) complex, [NiL2]·2H2O, was prepared by the reaction of a N2O2 donor monocondensed Schiff base ligand, 2-((3-aminopropylimino)methyl)-6-methoxyphenol (HL), with NiCl2·6H2O. The reaction of this complex with NiCl2·6H2O and LnCl3·6H2O (Ln = Gd, Tb, Dy, Ho) in a 1:1:1 molar ratio leads to four hexanuclear Ni4Ln2 complexes formulated as [{(NiL)2Gd}2(μ2-Cl)2(μ3-OH)4(OH2)4]Cl4·CH3CN·H2O (1), [{(NiL)2Tb}2(μ2-Cl)2Cl2(μ3-OH)4(OH2)2]Cl2·12H2O (2), [{(NiL)2Dy}2(μ2-Cl)2Cl2(μ3-OH)4(OH2)2]Cl2·16H2O (3), and [{(NiL)2Ho}2(μ2-Cl)2(μ3-OH)4(OH2)4]Cl4·CH3CN·1.8H2O (4). The Ln(III) centers are octacoordinated with a triangular-dodecahedral geometry, and the geometries around the Ni(II) center…
Ring opening polymerization of ε-caprolactone initiated by titanium and vanadium complexes of ONO-type schiff base ligand
2021
AbstractA phenoxy-imine proligand with the additional OH donor group, 4,6-tBu2-2-(2-CH2(OH)-C6H4N = CH)C6H3OH (LH2), was synthesized and used to prepare group 4 and 5 complexes by reacting with Ti(OiPr)4 (LTi) and VO(OiPr)3 (LV). All new compounds were characterized by the FTIR, 1H and 13C NMR spectroscopy and LTi by the single-crystal X-ray diffraction analysis. The complexes were used as catalysts in the ring opening polymerization of ε-caprolactone. The influence of monomer/transition metal molar ratio, reaction time, polymerization temperature as well as complex type was investigated in detail. The complexes showed high (LTi) and moderate (LV) activity in ε-caprolactone polymerization a…
Dichlorovanadium (IV) complexes with salen-type ligands for ethylene polymerization
2008
Vanadium complexes with tetradentate salen-type ligands were first time explored in ethylene polymerizations. The effects of the vanadium complex structure, the alkyl aluminum cocatalysts type (EtAlCl2, Et2AlCl, Et3Al, and MAO), and the polymerization conditions (Al/V molar ratio, temperature) on polyethylene yield were explored. It was found that EtAlCl2 in conjunction with investigated vanadium complexes produced the most efficient catalytic systems. It was shown, moreover, that the structural changes of the tetradentate salen ligand (type of bridge which bond donor nitrogen atoms and type of substituent on aryl rings) affected activity of the catalytic system. The complexes containing li…
Ethylenebis(5-chlorosalicylideneiminato)vanadium dichloride immobilized on MgCl2 -based supports as a highly effective precursor for ethylene polymer…
2009
Ethylenebis(5-chlorosalicylideneiminato)vanadium dichloride supported on MgCl2(THF)2 or on the same carrier modified by EtnAlCl3−n, where n = 1–3, was used in ethylene polymerization in the presence of MAO or a common alkylaluminium compounds as a cocatalyst. The support type alter vanadium loading and also change the characteristic of the catalytic active sites. Et2AlCl is the best activator for a catalyst which has been immobilized on a nonmodified support, whereas the systems which contain a carrier which has been modified by an organoaluminium compound reveal the highest activity in conjunction with MAO. That difference, together with different temperature effects on polymerization effi…
C3-symmetric trinuclear copper(ii) species as tectons in crystal engineering
2013
Three new complexes have been obtained using C3-symmetric trinuclear complexes as tectons; [Cu3(felden)(NCS)3(dmf)3] (1), [Cu3(felden)(mand)3]·(C2H5)2O (2), and [Cu3(felden)(dca)3(C2H5OH)]·2H2O (3) (H3felden is the Schiff base resulting from the condensation of 2,4,6-triformylphloroglucinol with N,N-dimethylethylenediamine, mand− is the anion of the R-mandelic acid and dca− is the dicyanamide anion). Compounds 1 and 2 are discrete trinuclear species, while compound 3 is a 2D coordination polymer, constructed from trinuclear nodes and dicyanamido spacers. The variable-temperature magnetic properties of 1–3 have been investigated and they reveal the occurrence of weak antiferromagnetic intera…