Search results for "HOS"

A reinvestigation of compound CpMo(PMe3)2(CH3)2: Alkylation by single electron transfer and radical addition?

2001

International audience; The synthesis of the half-sandwich molybdenum(III) diphosphine dimethyl complex CpMo(PMe3)2(CH3)2 has been reinvestigated. The compound was obtained from the corresponding dichloro complex CpMo(PMe3)2Cl2 and methyllithium at low temperatures and isolated as a crystalline product by conducting all operations at temperatures lower than −10 °C. The complex is thermally unstable at room temperature but has been fully characterised by EPR spectroscopy, cyclic voltammetry and X-ray diffraction. The formation reaction is retarded by excess phosphine. On the basis of this and other related observations, a mechanism involving phosphine pre-dissociation followed by single elec…

Modeling the Effects of Climate Change on the Supply of Phosphate-Phosphorus

2009

The transfer of phosphorus from terrestrial to aquatic ecosystems is a key route through which climate can influence aquatic ecosystems. A number of climatic factors interact in complex ways to regulate the transfer of phosphorus and modulate its ecological effects on downstream lakes and reservoirs. Processes influencing both the amount and timing of phosphorus export from terrestrial watersheds must be quantified before we can assess the direct and indirect effects of the weather on the supply and recycling of phosphorus. Simulation of the export of phosphorus from the terrestrial environment is complicated by the fact that it is difficult to describe seasonal and inter-annual variations …

The effect of rheological approximations in 3-D numerical simulations of subduction and collision

2018

Abstract Subduction and collision zones evolve differently from one another due to different rheological properties, different amounts of regional isostatic compensation, and the different mechanisms by which forces are applied to the convergent plates. The rheology of mantle and lithosphere is known to have the largest influence on the dynamics of subduction and continental collision. However, previous 3-D geodynamic models of subduction/collision processes have used various rheological approximations, making their results difficult to compare, since there is no clear understanding on the extent of these approximations on the dynamics. Here, we test the effect of rheological approximations…

Causas y consecuencias del crecimiento urbanístico en el litoral valenciano a través de la evolución de los usos del suelo. El caso de Oliva.

2019

Mediante la fotointerpretación de imágenes aéreas con la utilización de técnicas SIG y a través de un intenso trabajo bibliográfico y de campo, se realiza un análisis diacrónico (1956, 1991 y 2015) de la evolución de los usos del suelo en Oliva (València, España). A partir de este análisis multimetodológico se estudia la evolución de la situación urbanística y de las dinámicas territoriales en un municipio paradigmático para explicar la evolución urbanística del litoral valenciano en las últimas décadas. In this paper we have carried out a diachronic analysis about land uses evolution in Olive through a mixed method of research, based on photo-interpretation of aerial images (years 1956, 19…

2021

Intracratonic basins tend to subside much longer than the timescale predicted by thermal relaxation of the lithosphere. Many hypotheses have been suggested to explain their longevity, yet few have been tested using quantitative thermo-mechanical numerical models, which capture the dynamic of the lithosphere. Lithospheric-scale geodynamic modelling preserving the tectono-stratigraphic architecture of these basins is challenging because they display only few kilometres of subsidence over 1000 of km during time periods exceeding 250 Myr. Here we present simulations that are designed to examine the relative role of thermal anomaly, tectonics and heterogeneity of the lithosphere on the dynamics …

Global modeling of the lower three polyads of PH_{3} Preliminary results

2009

International audience; In order to model the high-resolution infrared spectrum of the phosphine molecule in the 3 mu m region, a global approach involving the lower three polyads of the molecule (Dyad, Pentad and Octad) as been applied using an effective hamiltonian in the form of irreducible tensors. This model allowed to describe all the 15 vibrational states involved and to consider explicitly all relevant ro-vibrational interactions that cannot be accounted for by conventional perturbation approaches. 2245 levels (up to J=14) observed through transitions arising from 34 cold and hot bands including all available existing data as well as new experimental data have been fitted simultaneo…

Melange: A viscoelastic lattice-particle model applicable to the lithosphere

2012

[1] This article introduces the software Melange, a 3D lattice-particle hybrid model. The software was specifically designed in order to simulate ductile visco-elasto-plastic deformation and can be used to study tectonic processes in the lithosphere from the micro to the macro scale. Melange is under an open source license. The code takes both relevant yield mechanisms for the deformation of lithospheric material into account: dynamic brittle failure and ductile creep, where ductile creep is modeled as viscoelasticity. The software considers effects of the local geology, of the inherent disorder of geomaterials, of rheological layering of the lithosphere and applies repulsion when the mater…

Is there a global carbonate layer in the oceanic mantle?

2021

co-auteur étranger; International audience; Previous modeling of carbonate subduction by high‐pressure experimentation has allowed to propose scenarios for bulk carbon return to the mantle, but the detailed transfer mechanisms have seldom been studied. We monitored carbonate – silicate reactions by combining high‐pressure experiments and synchrotron‐based x‐ray diffraction. Carbonates break down at moderate pressure and high temperature and CO2 is trapped at grain boundaries. Further isothermal compression yields melting, which may control continuous carbon introduction, first in the mantle wedge, and next, away from the wedge. Carbon presence has been discussed in a variety of magmatic con…

Complex geometry and kinematics of subsidiary faults within a carbonate-hosted relay ramp

2019

Abstract Minor fault geometry and kinematics within relay ramps is strongly related to the stress field perturbations that can be produced when two major fault segments overlap and interact. Here we integrate classical fieldwork and interpretation of a virtual outcrop to investigate the geometry and kinematics of subsidiary faults within a relay ramp along the Tre Monti normal fault in the Central Apennines. Although the Tre Monti fault strikes parallel to the regional extension (NE-SW) it shows predominant dip-slip kinematics, suggesting a NW-SE oriented extension acting at sub-regional scale (1–10 km). Conversely, the slickenlines collected on the front segment of the relay ramp highlight…

P and S wave travel time tomography of the SE Asia-Australia collision zone

2019

© 2019 Elsevier B.V. The southeast (SE)Asia - Australia collision zone is one of the most tectonically active and seismogenic regions in the world. Here, we present new 3-D P- and S-wave velocity models of the crust and upper mantle by applying regional earthquake travel-time tomography to global catalogue data. We first re-locate earthquakes provided by the standard ISC-Reviewed and ISC-EHB catalogues using a non-linear oct-tree scheme. A machine learning algorithm that clusters earthquakes depending on their spatiotemporal density was then applied to significantly improve the consistency of travel-time picks. We used the Fast Marching Tomography software package to retrieve 3-D velocity a…