Search results for "HYDROCARBONS"

showing 10 items of 368 documents

Persistent Organic Pollutants and Fatty Acid Profile in a Typical Cheese from Extensive Farms: First Assessment of Human Exposure by Dietary Intake

2022

Dairy products represent an important source of beneficial substances for humans. At the same time, they can expose the consumers to environmental contaminants ingested by animals through their diet, influencing their health negatively. This experiment aims to evaluate the risk and benefits related to the consumption of typical stretched cheeses, considering their fatty acid (FA) profile and persistent organic pollutants (POPs) content. Six representative farms, two of them organic, raising Cinisara cattle were selected, considering the typical extensive management systems, based on feeding of natural pasture integrated with concentrate and hay depending on the availability of forage on pas…

Settore AGR/19 - Zootecnica SpecialeGeneral VeterinarySettore CHIM/10 - Chimica Degli Alimentiautochthonous cow breedpolychlorinated biphenyls; polycyclic aromatic hydrocarbons; polybrominated diphenyl ethers; autochthonous cow breed; pasture; production season; Caciocavallo Palermitano cheese; chemical composition; fatty acidspastureCaciocavallo Palermitano cheesepolybrominated diphenyl etherSettore CHIM/09 - Farmaceutico Tecnologico Applicativopolycyclic aromatic hydrocarbonchemical compositionAnimal Science and Zoologyfatty acidpolychlorinated biphenylproduction season
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Comparison of stable isotope composition and inorganic and organic contaminant levels in wild and farmed bluefin tuna, Thunnus thynnus, in the Medite…

2009

Abstract Stable isotope composition (δ13C and δ15N) and persistent pollutants, including heavy metals (Hg, Cd, Pb, As, Cu, Zn) and organochlorine compounds (PCBs, HCB and p,p′-DDE), were measured in muscle and liver tissues of wild and farmed bluefin tunas to investigate the changes occurring during the farming period and to assess the quality, in terms of contaminants, of the final product. At the end of farming, the food supplied was clearly integrated into the tuna tissues as derived from stable isotope signatures, and, contrarily to the literature findings obtained for other species, farmed tunas showed slight variations in persistent elements and chemical compounds in comparison with w…

Settore BIO/07 - EcologiaEnvironmental EngineeringDichlorodiphenyl DichloroethyleneHealth Toxicology and MutagenesisFish farmingAquaculturechemistry.chemical_compoundAquacultureMetals HeavyPCBs HCB pp’-DDE heavy metals stable isotopes tuna farmingHexachlorobenzeneHydrocarbons ChlorinatedMediterranean SeaAnimalsEnvironmental ChemistryPollutantCarbon IsotopesNitrogen IsotopesbiologyTunabusiness.industryChemistryStable isotope ratioPublic Health Environmental and Occupational Healthfood and beveragesGeneral MedicineGeneral ChemistryHexachlorobenzeneContaminationbiology.organism_classificationPolychlorinated BiphenylsPollutionLiverEnvironmental chemistryMultivariate AnalysisbusinessTunahuman activitiesWater Pollutants ChemicalThunnusEnvironmental MonitoringChemosphere
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Intrinsic bioremediation potential of a chronically polluted marine coastal area.

2015

A microbiological survey of the Priolo Bay (eastern coast of Sicily, Ionian Sea), a chronically polluted marine coastal area, was carried out in order to discern its intrinsic bioremediation potential. Microbiological analysis, 16S rDNA-based DGGE fingerprinting and PLFAs analysis were performed on seawater and sediment samples from six stations on two transects. Higher diversity and variability among stations was detected by DGGE in sediment than in water samples although seawater revealed higher diversity of culturable hydrocarbon-degrading bacteria. The most polluted sediment hosted higher total bacterial diversity and higher abundance and diversity of culturable HC degraders. Alkane- an…

Settore BIO/07 - EcologiaGeologic SedimentsHydrocarbonMicrobial ConsortiaSettore BIO/05 - ZoologiaBiodiversityAquatic ScienceSettore BIO/19 - Microbiologia GeneraleOceanographyDNA RibosomalOleibacterSediment bacteriaGeologic SedimentBioremediationSeawaterDGGETransectSicilyDenaturing Gradient Gel ElectrophoresibiologyBacteriaEcologyDenaturing Gradient Gel ElectrophoresisMedicine (all)Water PollutionSedimentBiodiversitybiology.organism_classificationHydrocarbonoclastic bacteriaPollutionHydrocarbonsBiodegradation EnvironmentalPLFAEnvironmental scienceSeawaterAlcanivoraxhuman activitiesBayTemperature gradient gel electrophoresisMarine pollution bulletin
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Essential oil composition of the fruits of Periploca laevigata Aiton subsp. angustifolia (Labill.) Markgraf (Apocynaceae – Periplocoideae)

2011

The essential oil of the fruits of Periploca laevigata Aiton subsp. angustifolia (Labill.) Markgraf (Apocynaceae) from Lampedusa Island was obtained by hydrodistillation and its composition was analysed. The analyses allowed the identification and quantification of 64 volatile compounds belonging to different classes. The most abundant compounds were nonacosane, heptacosane, hentriacontane and δ-cadinene. Among the volatile compounds identified in the fruits of P. laevigata subsp. angustifolia, 31 are present in other taxa of Apocynaceae, 19 have antimicrobial activity and four are pheromones for the butterfly Danaus chrysippus. The possible ecological role of the volatile compounds found i…

Settore BIO/07 - EcologiaNonacosanePlant ScienceBiochemistryPheromonesessential oilAnalytical Chemistrylaw.inventionchemistry.chemical_compoundpheromoneAnti-Infective AgentslawBotanyAlkanesOils VolatileDanaus chrysippusEssential oilHentriacontanePeriplocabiologyApocynaceaeOrganic ChemistrySettore CHIM/06 - Chimica Organicabiology.organism_classificationHydrocarbonsApocynaceaeTaxonSettore AGR/11 - Entomologia Generale E ApplicatachemistrySex pheromoneFruitvolatile componentsSettore BIO/03 - Botanica Ambientale E ApplicataantimicrobialPeriplocoideae
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Highly contaminated areas as sources of pollution for adjoining ecosystems: The case of Augusta Bay (Central Mediterranean).

2014

An assessment of trace element and polycyclic aromatic hydrocarbon (PAH) contamination based on surface sediments collected in summer 2012 was carried out in Priolo Bay adjoining one of the most polluted areas of the Mediterranean Sea, the industrial Augusta harbour (Italy, Central Mediterranean). Inorganic and organic contaminants were generally not remarkable. Occasional elevated concentrations of Hg, Cd, Ni and PAHs exceeding sediment quality guidelines were detected in the northern sector of Priolo Bay, close to Augusta harbour, possibly as a result of water drainage of industrialised and urbanised areas and/or potential direct export of contaminated material from Augusta harbour, whose…

Settore BIO/07 - EcologiaPollutionMediterranean climateAquatic OrganismsGeologic Sedimentsmedia_common.quotation_subjectAquatic ScienceOceanographyMediterranean seaPolycyclic Aromatic HydrocarbonsEcosystemmedia_commoncomputer.programming_languageTrace elementSedimentBiotaPollutionSettore GEO/08 - Geochimica E VulcanologiaTrace ElementsOceanographyBaysItalyMediterranean Sea Pollution Sediments PAHs Trace elementsHarbourEnvironmental scienceBaycomputerWater Pollutants ChemicalEnvironmental MonitoringMarine pollution bulletin
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CHEMICAL COMPOSITION OF THE ESSENTIAL OIL OF CLADANTHUS SCARIOSUS(ASTERACEAE) WILD GROWN IN MOROCCO

2014

Cladanthus Cass. [Syn. Ormenis (Cass.) Cass.] is a genus of the family Asteraceae, endemic to the Mediterranean region and related to the tribe Anthemideae (1). It comprises 15 species including C. scariosus (Ball) Oberpr. & Vogt [Bas. Santolina scariosa; Syn. Ormenis scariosa Litard. & Maire] from Morocco where is concentrates 1/3 of the species of the genus (2). Some of these are perennial, suffruticose and strongly aromatic plants. C. mixta (L.) Chev. is used in Morocco as chamomile and this is commonly called Moroccan chamomile. In the same country, C scariosus is fairly common in open places, on sandstone substrates (3) and is characterized by a strong aromatic character, this has moti…

Settore BIO/15 - Biologia Farmaceuticaaromatic plantsesquiterpene hydrocarbons
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Molecular Selectivity of CH 4 –C 2 H 6 Mixed Hydrates: A GCMC Study

2021

International audience; In this paper, we report the first grand canonical Monte Carlo simulation study aiming at characterizing the competitive trapping of CH4 and C2H6 molecules into clathrate hydrates under temperature conditions typical of those encountered at the surface of Titan. Various compositions of the fluid in contact with the clathrate phase have been considered in the simulations, including pure methane, pure ethane, and mixed fluids made of various methane/ethane ratios. The trapping isotherms obtained from the simulations clearly show that ethane molecules can be enclathrated at lower pressures than methane molecules. In addition, they provide evidence that the methane molec…

SimulationsAtmospheric ScienceMaterials scienceClathrate hydrate02 engineering and technologyTrapping010402 general chemistry01 natural sciences7. Clean energyMethaneSolvatesIsothermschemistry.chemical_compound[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/PlanetologyGeochemistry and PetrologyPhase (matter)MoleculeClathrateGrand canonical monte carloGrand Canonical Monte Carlo[PHYS]Physics [physics]FluidsEthane[PHYS.PHYS]Physics [physics]/Physics [physics]Molecules021001 nanoscience & nanotechnologyHydrocarbons0104 chemical scienceschemistry13. Climate actionSpace and Planetary ScienceChemical physics[SDU]Sciences of the Universe [physics]High pressure0210 nano-technologySelectivityMethanePlanetary Science
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Effect of rhamnolipids on microbial biomass content and biochemical parameters in soil contaminated with coal tar creosote

2019

AbstractThe objective of the present study was to compare the effect of rhamnolipids on the microbial biomass content and the activity of dehydrogenases (DHA), acid phosphatase (ACP), alkaline phosphatase (ALP), and urease (URE) in soil contaminated with two types of coal tar creosote: type C and type GX-Plus. The experiment was carried out on samples of sandy clay loam under laboratory conditions. Coal tar creosote was added to soil samples at a dose of 0 and 10 g·kg−1 DM, along with rhamnolipids at a dose of 0, 10, 100, and 1000 mg·kg−1 DM. The humidity of the samples was brought to 60% maximum water holding capacity, and the samples were incubated at 20°C. Microbial and biochemical param…

Soil testUreaseQH301-705.5polycyclic aromatic hydrocarbonsBiomass010501 environmental sciencescomplex mixtures01 natural sciencesGeneral Biochemistry Genetics and Molecular Biologylaw.inventionBioremediationbioremediationlawmedicineBiology (General)Coal tarsandy clay loampolycycli aromatic hydrocarbons0105 earth and related environmental sciencesGeneral Immunology and MicrobiologybiologyGeneral NeuroscienceAcid phosphatase04 agricultural and veterinary sciencessoil enzymatic activityCreosoteEnvironmental chemistryLoam040103 agronomy & agriculturebiology.protein0401 agriculture forestry and fisheriesGeneral Agricultural and Biological SciencesResearch Articlemedicine.drugOpen Life Sciences
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Reduced graphene oxide-based magnetic composite for trace determination of polycyclic aromatic hydrocarbons in cosmetics by stir bar sorptive dispers…

2020

This work describes a sensitive and rapid analytical method for trace determination of polycyclic aromatic hydrocarbons (PAHs) in cosmetic samples. The proposed method is based on stir bar sorptive-dispersive microextraction (SBSDME). A magnetic composite made of CoFe2O4 magnetic nanoparticles embedded into reduced graphene oxide sheets is used as sorbent phase. After the extraction, the target analytes are desorbed in toluene and then analyzed by gas chromatography-mass spectrometry (GC-MS). The main parameters involved in the extraction procedure (i.e., composite amount, extraction time and desorption time) were evaluated and optimized to provide the best extraction efficiency. The method…

SorbentCosmetics010402 general chemistryMass spectrometryFerric Compounds01 natural sciencesBiochemistryGas Chromatography-Mass SpectrometryAnalytical ChemistryMatrix (chemical analysis)Magneticschemistry.chemical_compoundLimit of DetectionPolycyclic Aromatic HydrocarbonsSolid Phase MicroextractionDetection limitChromatography010401 analytical chemistryOrganic ChemistryExtraction (chemistry)CobaltGeneral MedicineToluene0104 chemical sciencesLinear rangechemistryStandard additionGraphiteJournal of Chromatography A
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Hydration/elimination reactions of trapped protonated fluoroalkyl triazines

2007

Spectrometry Mass Electrospray IonizationHydrocarbons FluorinatedTriazinesChemistryIONIZATION MASS-SPECTROMETRYWaterProtonationFLUORINATED HETEROAROMATIC-COMPOUNDS5-MEMBERED RINGSElimination reactionComputational chemistry2 HETEROATOMSProtonsHETEROCYCLESSpectroscopyJournal of Mass Spectrometry
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