Search results for "Hell"

Development of core-shell colloids to study self-diffusion in highly concentrated dispersions

2007

To study single particle motion in highly concentrated colloidal dispersions, a host-tracer colloid system was developed, consisting of crosslinked polymer micronetwork spheres placed in a good solvent. The host colloid is made invisible to the experimental probe by matching its refractive index to that of the solvent. For the tracer particles a core-shell structure was chosen to ensure the interaction potential to be identical to that of the host particles. Therefore the shell was made of the same polymer as the host. The core differs in refractive index from the solvent and is therefore visible due to scattered light.

Dicyclopentaannelated Hexa-peri-hexabenzocoronenes with a Singlet Biradical Ground State

2021

Abstract Synthesis of two dicyclopentaannelated hexa‐peri‐hexabenzocoronene (PHBC) regioisomers was carried out, using nonplanar oligoaryl precursors with fluorenyl groups: mPHBC 8 with two pentagons in the “meta”‐configuration was obtained as a stable molecule, while its structural isomer with the “para”‐configuration, pPHBC 16, could be generated and characterized only in situ due to its high chemical reactivity. Both PHBCs exhibit low energy gaps, as reflected by UV‐vis‐NIR absorption and electrochemical measurements. They also show open‐shell singlet ground states according to electron paramagnetic resonance (EPR) measurements and density functional theory (DFT) calculations. The use of…

Dynamic tuning of the director field in liquid crystal shells using block copolymers

2020

When an orientationally ordered system, like a nematic liquid crystal (LC), is confined on a self-closing spherical shell, topological constraints arise with intriguing consequences that depend critically on how the LC is aligned in the shell. We demonstrate reversible dynamic tuning of the alignment, and thereby the topology, of nematic LC shells stabilized by the nonionic amphiphilic block copolymer Pluronic F127. Deep in the nematic phase, the director (the average molecule orientation) is tangential to the interface, but upon approaching the temperature TNI of the nematic– isotropic transition, the director realigns to normal. We link this to a delicate interplay between an interfacial …

Conformations and orientational ordering of semiflexible polymers in spherical confinement.

2017

Semiflexible polymers in lyotropic solution confined inside spherical nanoscopic “containers” with repulsive walls are studied by molecular dynamics simulations and density functional theory, as a first step to model confinement effects on stiff polymers inside of miniemulsions, vesicles, and cells. It is shown that the depletion effects caused by the monomer-wall repulsion depend distinctly on the radius R of the sphere. Further, nontrivial orientational effects occur when R, the persistence length ℓp, and the contour length L of the polymers are of similar magnitude. At intermediate densities, a “shell” of wall-attached chains is forming, such that the monomers belonging to those chains a…

Three beta-decaying states in 128In and 130In resolved for the first time using Penning-trap techniques

2020

Isomeric states in 128In and 130In have been studied with the JYFLTRAP Penning trap at the IGISOL facility. By employing state-of-the-art ion manipulation techniques, three different beta-decaying states in 128In and 130In have been separated and their masses measured. JYFLTRAP was also used to select the ions of interest for identification at a post-trap decay spectroscopy station. A new beta-decaying high-spin isomer feeding the isomer in 128Sn has been discovered in 128In at 1797.6(20) keV. Shell-model calculations employing a CD-Bonn potential re-normalized with the perturbative G-matrix approach suggest this new isomer to be a 16⁺ spin-trap isomer. In 130In, the lowest-lying (10⁻) isom…

A discontinuous Galerkin formulation for nonlinear analysis of multilayered shells refined theories

2023

A novel pure penalty discontinuous Galerkin method is proposed for the geometrically nonlinear analysis of multilayered composite plates and shells, modelled via high-order refined theories. The approach allows to build different two-dimensional equivalent single layer structural models, which are obtained by expressing the covariant components of the displacement field through-the-thickness via Taylor’s polynomial expansion of different order. The problem governing equations are deduced starting from the geometrically nonlinear principle of virtual displacements in a total Lagrangian formulation. They are addressed with a pure penalty discontinuous Galerkin method using Legendre polynomial…

Reconstruction of the internal structure of the pore system of a complex dinosaur eggshell (Megaloolithus siruguei)

2013

Despite the many reconstructions of fossil material that have recently appeared in the literature, dinosaur eggshells have never been reconstructed using computing techniques. Using the EMAC 3-D modelling methodology, we reconstruct a section of the Late Cretaceous Megaloolithus siruguei eggshell, which has a particularly complex pore system, exhibiting an intricate network of vertical, oblique, and horizontal pores.

Shell-model study of the 4th- and 6th-forbidden β -decay branches of 48-Ca

2014

The highly forbidden β− decay of 48Ca is reexamined by performing shell-model calculations with the GXPF1A effective interaction. We examine the three available decay branches to the lowest 6+, 5+, and 4+ states of 48Sc, and extract a theoretical half-life of T β 1/2 = 5.2+1.7 −1.3 × 1020 g−2 A yr for the β− decay, where gA is the value of the axial-vector coupling constant. The current half-life estimate suggests stronger competition between the single-β-decay and double-β-decay branches of 48Ca than previously expected on theoretical grounds. peerReviewed

Synthesis, Characterization, and Spectroscopy of Type-II Core/Shell Semiconductor Nanocrystals with ZnTe Cores

2005

In Vitro Bioactivity of Astaxanthin and Peptides from Hydrolisates of Shrimp (Parapenaeus longirostris) By-Products: From the Extraction Process to B…

2021

Non-edible parts of crustaceans could be a rich source of valuable bioactive compounds such as the carotenoid astaxanthin and peptides, which have well-recognized beneficial effects. These compounds are widely used in nutraceuticals and pharmaceuticals, and their market is rapidly growing, suggesting the need to find alternative sources. The aim of this work was to set up a pilot-scale protocol for the reutilization of by-products of processed shrimp, in order to address the utilization of this valuable biomass for nutraceutical and pharmaceuticals application, through the extraction of astaxanthin-enriched oil and antioxidant-rich protein hydrolysates. Astaxanthin (AST) was obtained using …