Search results for "Het"
showing 10 items of 8390 documents
Supramolecular assemblies and photophysical properties of ionic homo- and heteronuclear metallophilic complexes
2019
Abstract The synthesis of two dinuclear ionic complexes with chemical formula [Au(PR 3 ) 2 ][Au(C ≡ CC 5 H 4 N-4) 2 ] that contain the water soluble phosphines, PR 3 , PTA (1, 3,5-triaza-7-phosphaadamantane, 1 ) and DAPTA (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, 2 ) is herein described. The differences on their intermolecular reorganization have been analyzed and compared with the previously reported for the neutral complexes [Au(PR 3 )(C ≡ CC 5 H 4 N-4)]. It has been evidenced that the reorganization of the ligands giving rise to the dinuclear ionic complexes produces a complete change in the properties giving rise to Au⋯Au intermolecular assemblies. These aurophilic conta…
Down-Scaling Modis Vegetation Products with Landsat GAP Filled Surface Reflectance in Google Earth Engine
2020
High spatial resolution vegetation products are fundamental in different fields, such as improving the understanding of crop seasonality at regional scales. Here, two new vegetation products such as the Leaf Area Index (LAI) and the Fraction of Absorbed Photosynthetically Active Radiation (FAPAR) are downscaled at continental scales. A novel HIghly Scalable Temporal Adaptive Reflectance Fusion Model (HIS-TARFM) is used to generate the gap-free time series of Landsat surface reflectance data by fusing MODIS and Landsat reflectance for the contiguous United States. An artificial neural network is trained to capture the relationship between the gap free Landsat surface reflectance and the MODI…
Volcanic structures investigation through SAR and seismic interferometric methods: The 2011-2013 Campi Flegrei unrest episode
2019
Observations from satellites provide high-resolution images of ground deformation allowing to infer deformation sources by developing advanced modeling of magma ascent and intrusion processes. Nevertheless, such models can be strongly biased without a precise model of the internal structure of the volcano. In this study, we jointly exploited two interferometric techniques to interpret the 2011–2013 unrest at Campi Flegrei caldera (CFc). The first is the Interferometric Synthetic Aperture Radar (InSAR) technique, which provides highly-resolved spatial and temporal images of ground deformation. The second is the Ambient Noise Tomography (ANT), which images subsurface structures, providing the…
The global forest above-ground biomass pool for 2010 estimated from high-resolution satellite observations
2021
Funding Information: We are thankful to the GlobBiomass project team and Frank Martin Seifert (ESA) for valuable suggestions and stimulating scientific discussions. We are thankful to Takeo Tadono (JAXA EORC), Masato Hayashi, (JAXA EORC), Kazufumi Kobayashi (RESTEC), Åke Rosenqvist (soloEO), and Josef Kellndorfer (EBD) for support with the use and interpretation of the ALOS PALSAR mosaics. Support by the CCI Land Cover project team, in particular Sophie Bontemps (UCL), is greatly acknowledged. The help from Martin Jung (MPI-BGC) in feature selection and Ulrich Weber (MPI-BGC) for data processing for the GSV-to-AGB conversions is greatly acknowledged. Forest inventory data for the validation…
Effects of natural radiation damage on back-scattered electron images of single crystals of minerals
2006
Generally, it has been assumed that signal intensity variations in back-scattered electron (BSE) images of minerals are mainly controlled by chemical heterogeneity. This is especially true for images of single crystals, where effects of different crystal orientations with respect to the incident beam on the observed BSE are excluded. In contrast, we show that local variations of the structural state within single-crystals (i.e., degree of lattice order or lattice imperfectness) may also have dramatic effects on the back-scattering of electrons. As an example, we present BSE images of single-crystals of natural zircon, ZrSiO 4 , whose intensity patterns are predominantly controlled by struct…
Toward a Comprehensive Dam Monitoring: On-Site and Remote-Retrieved Forcing Factors and Resulting Displacements (GNSS and PS–InSAR)
2021
Many factors can influence the displacements of a dam, including water level variability and environmental temperatures, in addition to the dam composition. In this work, optical-based classification, thermal diachronic analysis, and a quasi-PS (Persistent Scatter) Interferometric SAR technique have been applied to determine both forcing factors and resulting displacements of the crest of the Castello dam (South Italy) over a one-year time period. The dataset includes Sentinel-1A images acquired in Interferometric Wide swath mode using the Terrain Observation with Progressive Scans SAR (TOPSAR); Landsat 8 Thermal Infrared Sensor (TIRS) thermal images, and Global Navigation Satellite System …
Element variations in rhyolitic magma resulting from gas transport
2013
Tuffisite veins are glass-filled fractures formed when magma fragments during degassing within the conduit. These veins form transient channels through which exsolved gases can escape from magma. The purpose of this study is to determine the extent to which chemical heterogeneity within the melt results from gas transport, and assess how this can be used to study magma degassing. Two tuffisite veins from contrasting rhyolitic eruptions at Torfajökull (Iceland) and Chaitén (Chile) were studied in detail. The tuffisite vein from Torfajökull is from a shallow dissected conduit (~70. ka) that fed a degassed lava flow, while the sample from Chaitén was a bomb ejected during the waning phases of …
Quantifying vegetation biophysical variables from the Sentinel-3/FLEX tandem mission: Evaluation of the synergy of OLCI and FLORIS data sources
2020
The ESA’s forthcoming FLuorescence EXplorer (FLEX) mission is dedicated to the global monitoring of the vegetation’s chlorophyll fluorescence by means of an imaging spectrometer, FLORIS. In order to properly interpret the fluorescence signal in relation to photosynthetic activity, essential vegetation variables need to be retrieved concomitantly. FLEX will fly in tandem with Sentinel-3 (S3), which conveys the Ocean and Land Colour Instrument (OLCI) that is designed to characterize the atmosphere and the terrestrial vegetation at a spatial resolution of 300 m. In this work we present the retrieval models of four essential biophysical variables: (1) Leaf Area Index (LAI), (2) leaf chlorophyll…
Potential of Automated Digital Hemispherical Photography and Wireless Quantum Sensors for Routine Canopy Monitoring and Satellite Product Validation
2021
To better characterize the temporal dynamics of vegetation biophysical variables, a variety of automated in situ measurement techniques have been developed in recent years. In this study, we investigated automated digital hemispherical photography (DHP) and wireless quantum sensors, which were installed at two sites under the Copernicus Ground Based Observations for Validation (GBOV) project. Daily estimates of plant area index (PAI) and the fraction of absorbed photosynthetically active radiation (FAPAR) were obtained, which realistically described expected vegetation dynamics. Good correspondence with manual DHP and LAI-2000 data (RMSE = 0.39 to 0.90 for PAI, RMSE = 0.07 for FAPAR) provid…
Top-of-Atmosphere Retrieval of Multiple Crop Traits Using Variational Heteroscedastic Gaussian Processes within a Hybrid Workflow.
2021
In support of cropland monitoring, operational Copernicus Sentinel-2 (S2) data became available globally and can be explored for the retrieval of important crop traits. Based on a hybrid workflow, retrieval models for six essential biochemical and biophysical crop traits were developed for both S2 bottom-of-atmosphere (BOA) L2A and S2 top-of-atmosphere (TOA) L1C data. A variational heteroscedastic Gaussian process regression (VHGPR) algorithm was trained with simulations generated by the combined leaf-canopy reflectance model PROSAILat the BOA scale and further combined with the Second Simulation of a Satellite Signal in the Solar Spectrum (6SV) atmosphere model at the TOA scale. Establishe…