Search results for "Heterogeneou"
showing 10 items of 461 documents
Modified Nanocarbons for Catalysis
2018
Nanocarbons represent useful scaffolds in the preparation of last generation nanostructured catalysts, and their chemical functionalization through covalent or non-covalent modification is becoming an important tool for introducing well-distributed anchoring points and, in the meantime, could be the first step toward the assembling of hybrid nanostructured materials with a hierarchical order. In this Review are reported synthesis and catalytic applications of chemically modified nanocarbons such as fullerene, carbon nanotubes, graphene, nanohorns and nanodiamonds in organocatalytic and metal-based (metal nanoparticles, organometallic complexes) reactions, covering major chemical reactions e…
A CAPWAP Architecture for Automatic Frequency Planning in WLAN
2007
Recently, the impressive success of the IEEE 802.11 WLAN technology has dramatically changed the role of the wireless connectivity provisioning. Born as a wireless extension of small office or home networks, todays the WLANs are getting more and more popular as a large, even metropolitan, area networks. The deployment of large-scale WLANs has some critical issues, because of the lack of coordinated management functionalities among the network nodes. In this paper we briefly describe the CAPWAP architectural solution, for centralizing some control and maintenance functionalities in large scale WLAN, by guaranteeing the interoperability between network nodes provided by different vendors. We …
A Logical Framework for Augmented Simulations of Wireless Sensor Networks
2006
This paper describes a framework for practical and efficient monitoring of a wireless sensor network. The architecture proposed exploits the dynamic reasoning capabilities of the situation calculus in order to assess the sensor network behavior before actually deploying all the nodes. Designing a wireless sensor network for a specific application typically involves a preliminary phase of simulations that rely on specialized software, whose behavior does not necessarily reproduce what will be experienced by an actual network. On the other hand, delaying the test phase until deployment may not be advisable due to unreasonable costs. This paper suggests the adoption of a hybrid approach that i…
Functional nicotinic acetylcholine receptors on subplate neurons in neonatal rat somatosensory cortex.
2004
The establishment of cortical synaptic circuits during early development requires the presence of subplate neurons (SPn's), a heterogeneous population of neurons capable to integrate and process synaptic information from the thalamus, cortical plate, and neighboring SPn's. An accumulation of cholinergic afferents and nicotinic acetylcholine receptors (nAChRs) has been documentated in the subplate around birth. To assess the developmental role of the cholinergic innervation onto SPn's, we used whole cell patch-clamp recordings of visually identified and biocytin-labeled SPn's in neonatal rat somatosensory cortex. Functional nAChRs were present in 92% of the investigated SPn's. Activation of…
Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions
2021
Metal–organic frameworks (MOFs) have become one of the versatile solid materials used for a wide range of applications, such as gas storage, gas separation, proton conductivity, sensors and catalysis. Among these fields, one of the more well-studied areas is the use of MOFs as heterogeneous catalysts for a broad range of organic reactions. In the present review, the employment of MOFs as solid catalysts for the Henry reaction is discussed, and the available literature data from the last decade are grouped. The review is organized with a brief introduction of the importance of Henry reactions and structural properties of MOFs that are suitable for catalysis. The second part of the review dis…
Dynamics of supercooled liquids and glassy solids
2001
Monotonic solution of heterogeneous anisotropic diffusion problems
2013
Anisotropic problems arise in various areas of science and engineering, for example groundwater transport and petroleum reservoir simulations. The pure diffusive anisotropic time-dependent transport problem is solved on a finite number of nodes, that are selected inside and on the boundary of the given domain, along with possible internal boundaries connecting some of the nodes. An unstructured triangular mesh, that attains the Generalized Anisotropic Delaunay condition for all the triangle sides, is automatically generated by properly connecting all the nodes, starting from an arbitrary initial one. The control volume of each node is the closed polygon given by the union of the midpoint of…
Upstream Product Market Regulations, ICT, R&D and Productivity
2017
Our study aims to assess the actual importance of the two main channels via which upstream anti-competitive sector regulations are usually considered to impact productivity growth, i.e. by acting as a disincentive to business investments in R&D and in ICT. We estimate the specific impacts of these two channels and their shares in the total impact as opposed to alternative channels of investments in other forms of intangible capital that we cannot explicitly consider for lack of appropriate data such as improvements in skills, management and organization. To achieve this, we specify an extended production function explicitly relating productivity to R&D and ICT capital as well as to upstream…
DFT Study of Ethylene and Propylene Copolymerization over a Heterogeneous Catalyst with a Coordinating Lewis Base
2005
The copolymerization of ethylene and propylene over a heterogeneous Ti(III) catalyst containing tetrahydrofuran (THF) as a Lewis base and MgCl2 as a support has been studied by means of DFT. Two feasible models of active sites have been examined thoroughly, and one of them turned out to be favorable in terms of both catalytic activity and the microstructure of the resulting polymer. The external barriers of olefin insertion for this model range from 3.1 to 16.0 kcal/mol and are influenced by a variety of factors, such as the structure of the growing polymer chain and the nature of the incoming olefin as well as the orientation of the ligands around the titanium atom. Stochastic simulations …
Fourth Workshop on using Emerging Parallel Architectures
2012
AbstractThe Fourth Workshop on Using Emerging Parallel Architectures (WEPA), held in conjunction with ICCS 2012, provides a forum for exploring the capabilities of emerging parallel architectures such as GPUs, FPGAs, Cell B.E., Intel M.I.C. and multicores to accelerate computational science applications.