Search results for "Hexagonal crystal system"

Controlled Synthesis of CdSe Tetrapods with High Morphological Uniformity by the Persistent Kinetic Growth and the Halide-Mediated Phase Transformati…

2012

We report scalable controlled synthesis of CdSe tetrapods with high morphological uniformity based on the continuous precursor injection (CPI) approach with halide ligands. The CPI approach involves the successive injection of precursors into the seed solution at a controlled rate so that the reaction condition remains in the kinetic growth regime. To initiate the successful development of tetrapod structure, the controlled amount of halide ligands are added during the reaction, which triggered the formation of wurtzite arms on {111}-facets of the zincblende seeds. The formation of the wurtzite phase is responsible for the halide-mediated displacement of oleate ligands, destabilizing the em…

Structure analysis on the nanoscale: closed WS2 nanoboxes through a cascade of topo- and epitactic processes

2014

Closed WS2 nanoboxes were formed by topotactic sulfidization of a WO3/WO3·⅓H2O intergrowth precursor. Automated diffraction tomography was used to elucidate the growth mechanism of these unconventional hollow structures. By partial conversion and structural analysis of the products, each of them representing a snapshot of the reaction at a given point in time, the overall reaction can be broken down into a cascade of individual steps and each of them identified with a basic mechanism. During the initial step of sulfidization WO3·⅓H2O transforms into hexagonal WO3 whose surface allows for the epitaxial induction of WS2. The initially formed platelets of WS2 exhibit a preferred orientation wi…

Pressure-Induced Hexagonal to Monoclinic Phase Transition of Partially Hydrated CePO4

2019

We present a study of the pressure dependence of the structure of partially hydrated hexagonal CePO 4 up to 21 GPa using synchrotron powder X-ray diffraction. At a pressure of 10 GPa, a second-order structural phase transition is observed, associated with a novel polymorph. The previously unknown high-pressure phase has a monoclinic structure with a similar atomic arrangement as the low-pressure phase, but with reduced symmetry, belonging to space group C2. Group-subgroup relations hold for the space symmetry groups of both structures. There is no detectable volume discontinuity at the phase transition. Here we provide structural information on the new phase and determine the axial compress…

Transient photoconductivity in a discotic hexagonal plastic crystal

1996

Subdivision into i-packings and S-packing chromatic number of some lattices

2015

An ?$i$?-packing in a graph ?$G$? is a set of vertices at pairwise distance greater than ?$i$?. For a nondecreasing sequence of integers ?$S=(s_1,s_2,\ldots)$?, the?$S$?-packing chromatic number of a graph ?$G$? is the least integer ?$k$? such that there exists a coloring of ?$G$? into ?$k$? colors where each set of vertices colored ?$i$?, ?$i=1,\ldots,k$?, is an ?$s_i$?-packing. This paper describes various subdivisions of an ?$i$?-packing into ?$j$?-packings ?$(j>i)$? for the hexagonal, square and triangular lattices. These results allow us to bound the ?$S$?-packing chromatic number for these graphs, with more precise bounds and exact values for sequences ?$S=(s_i,i \in \mathbb{N}^*)$?, …

Ultrastructural myopathology in the molecular era.

2013

Electron microscopy is an essential component of myopathology, both in diagnostics and research of neuromuscular diseases. Although recently reduced in the diagnostic armamentarium, it has greatly been expanded to mouse models in research. Mostly it is descriptive, but a few additional techniques in combination with transmission electron microscopy have been employed. Foremost among them is immunoelectron microscopy, which assists in guiding molecular analysis in hereditary conditions, but may be vital in diagnostics of certain acquired entities, e.g., undulating tubules in dermatomyositis and in those congenital myopathies where genes and mutations remain to be identified, as in cylindrica…

Exploring the Interplay Between Ligand Derivatisation and Cation Type in the Assembly of Hybrid Polyoxometalate Mn-Andersons

2012

Herein a library of hybrid Mn-Anderson polyoxometalates anions are presented: 1, [(MnMo6 O18 )((OCH2 )3 -C-(CH2 )7 CHCH2 )2 ](3-) ; compound 2, [(MnMo6 O18 )((OCH2 )3 C-NHCH2 C16 H9 )2 ](3-) ; compound 3, [(MnMo6 O18 )((OCH2 )3 C-(CH2 )7 CHCH2 )1 ((OCH2 )3 C-NHCH2 C16 H9 )1 ](3-) ; compound 4, [(MnMo6 O18 )((OCH2 )3 C-NHC(O)CH2 CHCH2 )2 ](3-) and compounds 5-9, [(MnMo6 O18 )((OCH2 )3 C-NHC(O)(CH2 )x CH3 )2 ]), where x = 4, 10, 12, 14, and 18 respectively. The compounds resulting from the cation exchange of the anions 1-9 to give TBA (a) and DMDOA (b) salts, and additionally for compounds 1, 2 and 3, tetraphenylphosphonium (PPh4 ) (c) salts, are explored at the air/water interface using scan…

Advances in the enumeration of foldable self-avoiding walks

2020

<font color="#336633"&gtSelf-avoiding walks (SAWs) have been studied for a long time due to their intrinsic importance and the many application fields in which they operate. A new subset of SAWs, called foldable SAWs, has recently been discovered when investigating two different SAW manipulations embedded within existing protein structure prediction (PSP) software. Since then, several attempts have been made to find out more about these walks, including counting them. However, calculating the number of foldable SAWs appeared as a tough work, and current supercomputers fail to count foldable SAWs of length exceeding ≈ 30 steps. In this article, we present new progress in this enumeration, bo…

Mo(CO)6 dissociation on Cu(111) stimulated by a Scanning Tunneling Microscope

2013

Abstract The surface of Cu(111) was exposed to molybdenum hexacarbonyl Mo(CO)6 with monolayer coverage at temperature 160 K and studied by a Scanning Tunneling Microscope. The monolayer structure has a hexagonal arrangement and forms a (√7 × √7) R19 superlattice on the copper (111) plane. Upon repeated scanning the monolayer is transformed into a (1 × 2) superstructure with 3-fold oriented domains. The domains of (1 × 2) superstructure can change orientation under scanning according to 3-fold surface symmetry. From analysis of the domain mobility, it follows that CO groups of carbonyl fragments are organized in the (1 × 2) superstructure conditioning the domain reorientation. The observed s…

Effect of bone loss on the fracture resistance of narrow dental implants after implantoplasty. An in vitro study

2021

Background Implantoplasty (IP) involves polishing of the exposed surface of implants affected by peri-implantitis (PI). A study was made to determine whether the degree of bone loss influences the fracture resistance of implants with or without IP. Material and Methods An in vitro study was carried out on 32 narrow (3.5 mm) dental implants with a rough surface and external hexagonal connection. Implantoplasty was performed in half of the implants of the sample. Both the IP and control implants were divided into two subgroups according to the amount of bone loss (3 mm or 7.5 mm). Standardized radiographic assessment of implant width was performed using specific software. The main outcome var…