Search results for "Hexuronic Acids"

showing 3 items of 23 documents

Structural behaviour differences in low methoxy pectin solutions in the presence of divalent cations (Ca 2+ and Zn 2+ ): a process driven by the bind…

2014

International audience; In this paper, we compare the interactions between low methoxy pectin (LMP) and either Ca2+ or Zn2+ in semi-dilute solutions. Intrinsic viscosity and turbidity measurements reveal that pectin-calcium solutions are more viscous, but yet less turbid, than pectin-zinc ones. To get a molecular understanding on the origin of this rather unexpected behavior, we further performed isothermal titration calorimetry, small angle neutron scattering experiments, as well as molecular dynamics simulations. Our results suggest that calcium cations induce the formation of a more homogeneous network of pectin than zinc cations do. The molecular dynamics simulations indicate that this …

food.ingredientGelationPectinInorganic chemistryEgg-box modelchemistry.chemical_elementZincMolecular Dynamics SimulationCalciumAqueous-solutionsInsightsDivalentAssociationScatteringMolecular dynamicschemistry.chemical_compoundfoodPolysaccharides[SDV.IDA]Life Sciences [q-bio]/Food engineeringMoleculeCarboxylateAlginate gelschemistry.chemical_classificationViscosityHexuronic AcidsIsothermal titration calorimetryGeneral ChemistryCondensed Matter PhysicsDrug-deliverySolutionsZincCrystallographychemistryPectinsCalcium
researchProduct

Engineering a morphogenetically active hydrogel for bioprinting of bioartificial tissue derived from human osteoblast-like SaOS-2 cells.

2014

Abstract Sodium alginate hydrogel, stabilized with gelatin, is a suitable, biologically inert matrix that can be used for encapsulating and 3D bioprinting of bone-related SaOS-2 cells. However, the cells, embedded in this matrix, remain in a non-proliferating state. Here we show that addition of an overlay onto the bioprinted alginate/gelatine/SaOS-2 cell scaffold, consisting of agarose and the calcium salt of polyphosphate [polyP·Ca 2+ -complex], resulted in a marked increase in cell proliferation . In the presence of 100 μ m polyP·Ca2+ -complex, the cells proliferate with a generation time of approximately 47–55 h. In addition, the hardness of the alginate/gelatin hydrogel substantially i…

food.ingredientMaterials scienceAlginatesBiophysicschemistry.chemical_elementBioengineeringBiocompatible MaterialsCalciumGelatinHydrogel Polyethylene Glycol Dimethacrylatelaw.inventionCell LineBiomaterialschemistry.chemical_compoundfoodTissue engineeringGlucuronic AcidlawHardnessPolyphosphatesElastic ModulusmedicineHumansSaos-2 cellsCell Proliferation3D bioprintingOsteoblastsTissue EngineeringTissue ScaffoldsPolyphosphateHexuronic AcidsBioprintingOsteoblastmedicine.anatomical_structurechemistryMechanics of MaterialsCeramics and CompositesBiophysicsAgaroseGelatinBiomedical engineeringBiomaterials
researchProduct

Sequestration of biogenic amines by alginic and fulvic acids.

2006

The interaction of natural (alginic and fulvic acids) and synthetic (polyacrylic acid 2.0 kDa) polyelectrolytes with some protonated polyamines [diamines: ethylendiamine, 1,4-diaminobutane (or putrescine), 1,5-diaminopentane (or cadaverine); triamines: N-(3-aminopropyl)-1,4diaminobutane (or spermidine), diethylenetriamine; tetramine: N.N'-bis(3-aminopropyl)-1,4-diaminobutane (or spermine); pentamine: tetraethylene-pentamine; hexamine: pentaethylenehexamine] was studied at T=25 degrees C by potentiometry and calorimetry. Measurements were performed without supporting electrolyte, in order to avoid interference, and results were reported at I=0 mol L(-1). For all the systems, the formation of…

polyammonium-polycarboxylate interactionsAlginatesPolymersBiogenic aminesInorganic chemistryFulvic acidCarboxylic AcidsBiophysicsProtonationCalorimetryBiochemistryMedicinal chemistryElectrolyteschemistry.chemical_compoundbiogenic amineGlucuronic AcidPolyaminesBenzopyransAlginic acidPolyacrylic acidCadaverineChemistryHexuronic AcidsOrganic ChemistryPolyacrylic acidPentaminesequestrationPolyelectrolytesPolyelectrolyteQuaternary Ammonium CompoundsBiogenic amines; Fulvic acid; Alginic acid; Polyacrylic acid; sequestrationModels ChemicalDiethylenetriamineThermodynamicsAmine gas treatingProtonsMathematics
researchProduct