Search results for "High-resolution"
showing 10 items of 208 documents
The effect of the surface disordered layer on the photoreactivity of titania nanoparticles
2017
It is well known that the surface of metal oxide catalysts presents, usually, non-crystalline species containing impurities and low coordinated cations, which are observed in HRTEM images as a disordered layer of amorphous phase. Despite of being these species more accessible and less stable than the crystalline catalysts components, they have been rarely considered when analysing the catalyst activity. In this work, we have studied the effect of a treatment with HCl solution at pH = 0 on the characteristics of the disordered layer in two commercial anatase TiO2 samples, using techniques such as TGA, 1H MAS-NMR and HRTEM, and by determining these sample photocatalytic activity for the 4-nit…
Mesocrystalline anatase nanoparticles synthesized using a simple hydrothermal approach with enhanced light harvesting for gas-phase reaction
2018
Mesocrystalline TiO2 nanoparticles were synthesized using a hydrothermal approach. A simple two-step procedure at low temperature (<140 °C) allowed the nucleation of primary particles sized 2–4 nm and their subsequent assembly as almost spherical aggregates sized ≈20 nm. X-ray powder diffraction (XRD), Raman and X-ray photoelectron spectroscopy (XPS) studies, and HRTEM studies confirmed anatase as the unique TiO2 crystalline phase. The mesocrystalline structure of the anatase aggregates was clearly evidenced by HRTEM and SAED results. The mesocrystalline nanopowders exhibit a mesoporous structure with a surface area and pore volume of 63.5 m2 g−1 and 0.22 cm3 g−1, respectively. Ultraviolet …
Hydrothermal-mediated synthesis of orange Cr, Sb-containing TiO 2 nano-pigments with improved microstructure
2017
Abstract A hydrothermal-mediated via was developed to prepare discrete, non-aggregated Cr,Sb-doped rutile nano-pigments. After annealing the Cr- and Sb-containing TiO2 anatase nanocrystals obtained by hydrothermal aging the nano-pigments Cr,Sb-TiO2 were characterized with the aid of X-ray diffraction (XRD) including lattice parameter and crystallite size determination, Raman spectroscopy, field emission scanning and transmission electron microscopies (FESEM and TEM, respectively) including energy-dispersive X-ray (FESEM/EDX) spectroscopy, high resolution transmission electron microscopy (HRTEM) including selected area electron diffraction (SAED), ultraviolet–visible diffuse reflectance (UV–…
Exploring the validity of the long term data record V4 database for land surface monitoring
2015
The last (and final) version of the Long Term Data Record (LTDR) — Version 4 — has been released recently by NASA. This database includes daily information for all AVHRR (Advanced Very High Resolution Radiometer) channels, as well as ancillary data, since July 1981 up to present. This database is the longest available record of remotely sensed data useful for land surface monitoring, since it allows the estimation of vegetation indices at daily resolution, as well as the daily estimation of land surface temperature (LST). Here, we analyze the fitness of this database for land surface monitoring. To that end, we first estimated NDVI (Normalized Difference Vegetation Index), LST, as well as e…
Facile synthesis and characterization of functionalized, monocrystalline rutile TiO2 nanorods.
2006
Functionalized, monocrystalline rutile TiO2 nanorods were prepared from TiCl4 in aqueous solution under acidic conditions in the presence of dopamine, followed by aging and hydrothermal treatment at 150 degrees C. The surface-bound organic ligand controls the morphology as well as the crystallinity and the phase selection of TiO2. The presence of monocrystalline rutile TiO2 was confirmed by X-ray powder diffraction and HRTEM investigations. The as-prepared nanorods are soluble in water at pH3. The surface functionalization was analyzed by IR and 1H NMR, confirming the presence of dopamine on the surface. The surface amine groups can be tailored further with functional molecules such as dyes…
A 45-year sub-annual reconstruction of seawater temperature in the Bay of Brest, France, using the shell oxygen isotope composition of the bivalve Gl…
2020
A reconstruction of sea surface temperature (SST) spanning 45 years (1966–2011) was developed from δ18O obtained from the aragonitic shells of Glycymeris glycymeris, collected from the Bay of Brest, France. Bivalve sampling was undertaken monthly between 2014 and 2015 using a dredge. In total, 401 live specimens and 243 articulated paired valves from dead specimens were collected, of which 24 individuals were used to reconstruct SST. Temperatures determined using the palaeotemperature equation of Royer et al. compared well with observed SST during the growing season between 1998 and 2010 (Pearson’s correlation: p = 0.002, r = 0.760). Furthermore, a significant negative correlation was foun…
The Mediterranean Sea and the Gulf of Cadiz as a natural laboratory for paleotsunami research: Recent advancements
2021
International audience; After the 2004 Indian Ocean (IOT) and the 2011 Tohoku-oki tsunamis, new research in tsunami-related fields was strongly stimulated worldwide and also in the Mediterranean. This research growth yields substantial advancements in tsunami knowledge.Among these advancements is the “Paleotsunami” research that has marked particular progress on the reconstruction of the tsunami history of a region. As an integration of the historical documentation available in the Mediterranean and the Gulf of Cadiz areas, geological and geoarchaeological records provide the insights to define the occurrence, characteristics, and impact of tsunamis of the past. Here, we present the recent …
Thermal remote sensing of land surface temperature from satellites: Current status and future prospects
1995
Abstract In this paper we review the current status for deriving land surface temperatures (LSTs) by remote sensing from satellites in the thermal infrared. Because of its widespread use and global applicability, we concentrate on the Advanced Very High Resolution Radiometer (AVHRR). The theoretical framework and methodologies used to derive LSTs are reviewed and amplified. Practical algorithms are described and their accuracy and application critically evaluated through sensitivity studies and by inter‐comparison. The important effects of the atmosphere, surface emissivity and instrument noise are considered and the current practice for removing these effects is specified. The accuracy cur…
Night-time cloud cover estimation
2004
In this paper a method for cloud cover assessment at night-time (when only thermal infrared data are available) is presented. It is based on the analysis of long wave radiation transfer processes in partially cloudy areas, which led to the formulation of a simplified model of the surface–cloud–atmosphere system. The model was implemented in an operational and iterative algorithm to solve the radiative equations. The algorithm was validated using ground data collected at four meteorological stations in Argentina during November 1997 and May–June 1998, which were compared to cloudiness derived from National Oceanic and Atmospheric Administration Advanced Very High Resolution Radiometer therma…
Exploring the Validity of the Long-Term Data Record V4 Database for Land Surface Monitoring
2016
A new version of the long-term data record (LTDR)—Version 4—has been released recently by NASA. This database includes daily information for all advanced very high resolution radiometer channels, as well as ancillary data, from July 1981 up to present. This dataset is the longest available record of remotely sensed data useful for land surface monitoring, since it allows the daily estimation of vegetation indices, as well as the estimation of land surface temperature (LST). Here, we analyze the fitness of this database for land surface monitoring, especially as regards long-term trends and their validity. To that end, we estimated normalized difference vegetation index (NDVI), LST, as well …