Search results for "High-temperature"
showing 9 items of 79 documents
Mechanical Stresses: Inhibitor of Catalyst of High Temperature Oxidation?
2001
Oxidation of metals is a complex reaction in which mechanical and chemical phenomena occur. A dynamic and macroscopic model is developed in order to simulate oxidation kinetics of a metal. It includes the stress/diffusion coupling in the bulk and the interfacial phenomena at metal/oxide interface. Its application to the Zr/ZrO 2 system shows the important role of stress field distribution in oxide on kinetic behavior. According to the sign of stress gradient in the oxide scale, the oxidation rate can speed up or slow down. The calculated kinetic curves could he fitted using a k p .t 1/n law where n and kp vary all over the process, like for the experimental kinetic curves.
Investigation of the SHS mechanisms of titanium nitride by in situ time-resolved diffraction and infrared thermography
2007
Abstract The self-propagating high-temperature synthesis (SHS) or combustion synthesis is a promising process to produce advanced ceramics due to the high purity of the elaborated materials and the very short synthesis time. Titanium nitride has been synthesised from pressed titanium powder and a nitrogen gas flow under a 0.1 MPa pressure. The influence of the addition of a TiN diluent was investigated. For the first time, SHS reaction mechanisms were determined from in situ time-resolved X-ray diffraction (TRXRD) experiments using the synchrotron radiation. These experiments were coupled with infrared thermography to study the propagation of the combustion reaction. It appeared that the in…
Combustion wave structure during the MoSi2 synthesis by Mechanically-Activated Self-propagating High-temperature Synthesis (MASHS): In situ time-reso…
2006
Abstract In situ synchrotron time-resolved X-ray diffraction experiments coupled with an infrared imaging camera have been used to reveal the combustion wave structure during the production of MoSi2 by Mechanically Activated Self-propagating High-temperature Synthesis (MASHS). The fast combustion front exhibits a form described as an ‘equilibrium structure’ where the chemical reaction is the sole major driving force. In the MASHS process, oxide-free interfaces between Mo and Si nanocrystallites enhance the reaction Mo+2Si→MoSi2. Exhaustive time-resolved investigations show a possible solid-state process in the first second of the reaction within the combustion front. If preheating is added,…
Macroscopic persistent currents in YBa2Cu3O7
1988
Persistent currents in polycrystalline YBa2Cu3O7 rings have been investigated by measuring the spatial distribution of the magnetic flux trapped in field-cooled samples. The results unambiguously show that macroscopic persistent ring currents exist. The critical current density depends very sensitively on the sample quality, reachingj c ≈250 A/cm2 at 77 K for our best samples.
Anomalous intensity of the 335 cm−1 phonon in YBa2Cu3O7−δ
1991
Abstract We report results on Raman scattering for the intensity of the 335 cm −1 phonon of A g (pseudo B 1g ) symmetry in thin YBa 2 Cu 3 O 7−δ films on MgO and LaAlO 3 substrates. The intensity of this phonon shows a pronounced increase below 100 K and saturates at low temperatures. We also observe an additional intensity peaking at temperatures close to the superconducting transition T C . This may indicate a structural phase transition in the vicinity of T C .
An investigation on using pre-treated tyre rubber as a replacement of synthetic polymers for bitumen modification
2015
Rubberized bitumen obtained through a swelling process, has widely proven to be a successful technology for asphalt pavement applications and a solution to reduce the dismantling of tyre rubber on landfills. However, this technology presents two main operative issues which needs the adoption of costly special equipment. Firstly, significant high value of High Temperature Viscosity (HTV) which imposes mixing and compaction difficulties and leads to increased energy consumption and emissions. Furthermore, during the hot storage period, phase separation between rubber particles and the base bitumen could occur. Developing Recycled Tyre Rubber Modified Bitumen (RTR-MBs) with improved storage st…
The NG2 Proteoglycan Protects Oligodendrocyte Precursor Cells against Oxidative Stress via Interaction with OMI/HtrA2.
2015
The NG2 proteoglycan is characteristically expressed by oligodendrocyte progenitor cells (OPC) and also by aggressive brain tumours highly resistant to chemo- and radiation therapy. Oligodendrocyte-lineage cells are particularly sensitive to stress resulting in cell death in white matter after hypoxic or ischemic insults of premature infants and destruction of OPC in some types of Multiple Sclerosis lesions. Here we show that the NG2 proteoglycan binds OMI/HtrA2, a mitochondrial serine protease which is released from damaged mitochondria into the cytosol in response to stress. In the cytosol, OMI/HtrA2 initiates apoptosis by proteolytic degradation of anti-apoptotic factors. OPC in which NG…
Effects of Briquetting and High Pyrolysis Temperature on Hydrolysis Lignin Char Properties and Reactivity in CO-CO2-N2 Conditions
2021
Carbonaceous reductants for pyrometallurgical applications are usually obtained from fossil-based sources. The most important properties of the reductants greatly depend on the application and the feeding of the reductant into the process. However, the mechanical strength, calorific value, fixed carbon content, and reactivity of the reductant are the properties that usually define the applicability of the reductant for different processes. The reactivity of the biochars is usually high in comparison to metallurgical coke, which may restrict the applicability of the biochar in reduction processes. One cause of the higher reactivity is the higher surface area of the biochars, which can be sup…
Ultra-high temperature metamorphism recorded in Fe-rich olivine-bearing migmatite from the Khondalite Belt, North China Craton
2018
International audience; We document the first occurrence of Fe‐rich olivine‐bearing migmatitic metapelite in the Khondalite Belt, North China Craton. Petrological analyses revealed two exotic assemblages of orthopyroxene+spinel+olivine and orthopyroxene+spinel+cordierite. Phase relation modelling suggests that these assemblages are diagnostic of ultra‐high temperature (UHT) metamorphism in the Fe‐rich system, with temperatures from 1,000 to 1,050°C at 0.6 GPa. U–Th–Pb SIMS analyses on zircon reveal a similar age of c. 1.92 Ga for the olivine‐bearing migmatite and an adjacent gabbronoritic intrusion that is therefore identified as the heat source for the UHT metamorphism. These results, coup…