Search results for "Homogeneous"

Magnetic Properties of Ni II Cr III Layered Double Hydroxide Materials

2008

This paper describes the isolation of four layered double hydroxide (LDH) compounds having the general formula[NiII3–xCrIIIx(OH)6](CO3)x/2·yH2O [x = 0.57 (1), 0.69 (2), 0.81 (3) and 0.93 (4)] by using homogeneous precipitation methods and varying the metal ratio in the synthetic solutions. All the reported compounds have carbonate anions in the interlamellar space. This fact forces the interlayer distances to remain unchanged in all the cases, thus providing an ideal system in which the changes observed in magnetic properties can be correlated with metal composition along the hydroxide layers.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

Accelerated dinuclear palladium catalyst identification through unsupervised machine learning.

2021

Although machine learning bears enormous potential to accelerate developments in homogeneous catalysis, the frequent need for extensive experimental data can be a bottleneck for implementation. Here, we report an unsupervised machine learning workflow that uses only five experimental data points. It makes use of generalized parameter databases that are complemented with problem-specific in silico data acquisition and clustering. We showcase the power of this strategy for the challenging problem of speciation of palladium (Pd) catalysts, for which a mechanistic rationale is currently lacking. From a total space of 348 ligands, the algorithm predicted, and we experimentally verified, a number…

Validation of Collection 6 MODIS land surface temperature product using in situ measurements

2019

Land surface temperature (LST) is an important physical quantity at the land-atmosphere interface. Since 2016 the Collection 6 (C6) MODIS LST product is publicly available, which includes three refinements over bare soil surfaces compared to the Collection 5 (C5) MODIS LST product. To encourage the use of the C6 MODIS LST product in a wide range of applications, it is necessary to evaluate the accuracy of the C6 MODIS LST product. In this study, we validated the C6 MODIS LST product using temperature-based method over various land cover types, including grasslands, croplands, cropland/natural vegetation mosaic, open shrublands, woody savannas, and barren/sparsely vegetated. In situ measurem…

Nanomechanical cleavage of molybdenum disulphide atomic layers.

2014

The discovery of two-dimensional materials became possible due to the mechanical cleavage technique. Despite its simplicity, the as-cleaved materials demonstrated surprising macrocontinuity, high crystalline quality and extraordinary mechanical and electrical properties that triggered global research interest. Here such cleavage processes and associated mechanical behaviours are investigated by a direct in situ transmission electron microscopy probing technique, using atomically thin molybdenum disulphide layers as a model material. Our technique demonstrates layer number selective cleavage, from a monolayer to double layer and up to 23 atomic layers. In situ observations combined with mole…

A Three-Component Palladium-Catalyzed Oxidative CC Coupling Reaction: A Domino Process in Two Dimensions

2013

Accounting Symmetries on Indonesian Entities by Applying the Edgeworth's Box

2020

Decisions making of entities in an economy are materialized into transactions to transform economic goods into monetary goods, maintaining a continued management of the corporate activity. The transformation of economic goods into monetary ones is a <<mutatis mutandis>> effect in which entities of the economic and financial market interfere with different impact in their respective financial statements. In accordance to the economic situation of the market, we can make a bigger/smaller association between such entities. This association is susceptible of being represented by accounting symmetries. Accounting symmetries are obtained to measure the positions taken by entities in a…

Not all group members are created equal: heterogeneous abilities in inter-group contests

2020

AbstractCompetition between groups is ubiquitous in social and economic life, and typically occurs between groups that are not created equal. Here we experimentally investigate the implications of this general observation on the unfolding of symmetric and asymmetric competition between groups that are either homogeneous or heterogeneous in the ability of their members to contribute to the success of the group. Our main finding is that relative to the benchmark case in which two homogeneous compete against each other, heterogeneity within groups per se has no discernable effect on competition, while introducing heterogeneity between groups leads to a significant intensification of conflict a…

Utilization of dense carbon dioxide as an inert solvent for chemical syntheses

2010

Inflating an inhomogeneous universe

2014

While cosmological inflation can erase primordial inhomogeneities, it is possible that inflation may not begin in a significantly inhomogeneous universe. This issue is particularly pressing in multifield scenarios, where even the homogeneous dynamics may depend sensitively on the initial configuration. This paper presents an initial survey of the onset of inflation in multifield models, via qualitative lattice-based simulations that do not include local gravitational backreaction. Using hybrid inflation as a test model, our results suggest that small subhorizon inhomogeneities do play a key role in determining whether inflation begins in multifield scenarios. Interestingly, some configurati…

Information Flows Among the Major Stock Market Areas

2001

The relationship between the index returns of the major stock markets has been analysed in many papers. These studies usually examine lead–lag relationships between markets, without distinguishing the influencing ability and the sensitivity of each of the markets. Additionally, these studies use indices that are not directly comparable — either because of the way the indices are calculated or because of the number of companies and sectors used to construct them. This paper addresses both points. First, all the analyses have been made using homogeneous indices designed by Morgan Stanley Capital International. Secondly, the information flow has been studied by applying the model proposed by P…