Search results for "Homogeneous"
showing 10 items of 718 documents
Atoms embedded in an electron gas: Phase shifts and cross sections
1983
The Fermi-level scattering phase shifts and the transport cross sections are reported for atoms embedded in a homogeneous electron gas. The applications of the results are discussed, using the electronic stopping power for slow ions and impurity resistivity as examples. Peer reviewed
Estimates for Divergence Velocities of Axially Moving Orthotropic Thin Plates
2014
Some models for axially moving orthotropic thin plates are investigated analytically via methods of complex analysis to derive estimates for critical plate velocities. Linearised Kirchhoff plate theory is used, and the energy forms of steady-state models are considered with homogeneous and inhomogeneous tension profiles in the cross direction of the plate. With the help of the energy forms, some limits for the divergence velocity of the plate are found analytically. In numerical examples, the derived lower limits for the divergence velocity are analysed for plates with small flexural rigidity. peerReviewed
Microstructures in shells of the freshwater gastropod Viviparus viviparus: a potential sensor for temperature change?
2013
Abstract Mollusk shells contain a plethora of information on past climate variability. However, only a limited toolkit is currently available to reconstruct such data from the shells. The environmental data of some proxies (e.g. Sr/Ca ratios) is obscured by physiological effects, whereas other proxies, such as δ 18 O, simultaneously provide information on two or more different environmental variables. The present study investigates whether microstructures of the freshwater gastropod Viviparus viviparus provide an alternative means to reconstruct past water temperature. Cold and highly variable temperature regimes resulted in the precipitation of highly unordered first-order lamellae of simp…
Habitat Differences and Variability in the Lek Mating System of Black Grouse
1996
Spatially fixed territoriality has been regarded to be a general feature in lek mating systems. In the absence of territories, however, the nature of leks may change remarkably. We compared leks of black grouse in areas, where territoriality was governed by habitat characteristics. On ice-covered lakes, where the lekking ground was homogeneous and offered no landmarks by which the displaying males would be able to recognize territory boundaries, the male aggregations were mobile. 'Classical' leks on bogs, however, were stable. It also appeared that on mobile leks, as compared to stable leks, the opportunities for females to choose their mates were reduced. The distribution of mating success…
Spectro-temporal reflectance surfaces: a new conceptual framework for the integration of remote-sensing data from multiple different sensors
2012
The conflict between spatial and temporal resolution of satellite systems, as well as the frequent presence of clouds in the images, has been a traditional limitation of remote sensing in the optical domain. Nevertheless, most of the conceptual tools and algorithms developed classically in remote sensing are based on the input of a series of cloud-free images from identical sensors. In this study, we propose a conceptual framework that is able to ingest data from several different sensors, make them homogeneous, eliminate clouds virtually, and make them usable in a flexible, efficient, and transparent way. The methodology is based on previous developments such as spatial ‘downscaling’, temp…
Symmetry operators in computer vision
1996
Abstract Symmetry plays a remarkable role in perception problems. For example, peaks of brain activity are measured in correspondence with visual patterns showing symmetry . Relevance of symmetry in vision was already noted by Koler in 1929. Here, properties of a symmetry operator are reported and a new algorithm to measure local symmetries is proposed. Its performance is tested on segmentation of complex visual patterns and the classification of sparse images.
Calibration of a knock prediction model for the combustion of gasoline-LPG mixtures in spark ignition engines
2015
Gaseous fuels, such as liquefied petroleum gas (LPG) and natural gas (NG), thanks to their good mixing capabilities, allow complete and cleaner combustion than gasoline in spark ignition (SI) engines, resulting in lower pollutant emissions and particulate matter. In a previous work the authors showed that the simultaneous combustion of gasoline and LPG improves an SI engine efficiency with respect to pure gasoline operation with any significant power loss. The addition of LPG to the gasoline-air mixture produces an increase in knock resistance that allows running the engine at full load with overall stoichiometric mixture and better spark advance. In order to predict both performance and ef…
Electrocarboxylation of Benzyl Halides through Redox Catalysis on the Preparative Scale
2006
The electrocarboxylation of benzyl halides to the corresponding carboxylic acids through homogeneous charge-transfer catalysis was investigated both theoretically and experimentally to determine the influence of the operative parameters on the yield of the process and on the catalyst consumption. Theoretical considerations, based on fast kinetics of redox catalysis, were confirmed by the electrocarboxylation of 1-phenyl-1-chloroethane catalyzed by 1,3-benzenedicarboxylic acid di methyl ester performed at a carbon cathode under different operative conditions. We obtained high yields of the target carboxylic acid and experienced a low catalyst consumption by operating with optimized [RX]bulk/…
Insights into the Synthesis and the Solution Behavior ofmeso-Aryloxy- and Alkoxy-Substituted Porphyrins
2015
meso-RO-appended (R = alkyl, aryl) porphyrins bearing one or two OR substituents at the tetrapyrrolic macrocycle were synthesized in good yields from 5,15-dibromo-10,20-diphenylporphyrins 2H(Br2DPP), Ni(Br2DPP) and Zn(Br2DPP) using an SNAr reaction. By varying the solvent, the base, the temperature, and the time of the reaction, the optimum conditions were established, and the selective introduction of one or two meso-RO substituents at the periphery of the macrocycle was achieved. Moreover, monofunctionalization of Ni(Br2DPP) according to an SNAr reaction was used as a key step for the synthesis of rarely explored unsymmetrical porphyrinyl alkyl ethers. 1H NMR studies of these ethers in CD…
Anaerobic Palladium-Catalyzed Chemoselective Oxidation of Allylic and Benzylic Alcohols with α-Bromo Sulfoxide as a Co-Oxidant.
2007
A chemoselective palladium-catalyzed anaerobic oxidation of allylic and benzylic alcohols using an α-bromo sulfoxide as a co-oxidant is described for the first time. The catalyst system is simple and has a long life because of the allowance of phosphane ligands under the non-aerobic conditions. The advantages of the described method include no overoxidation of primary alcohols to carboxylic acids because of the mild conditions applied, the tolerance of oxygen-sensitive functionalities such as a carbon-carbon double bond, an organothio group, or a diorganoamino group and the effective preparation of α,β-unsaturated aldehydes and ketones, resulting from the oxidation of primary and secondary …