Search results for "Homogeneous"

Multilevel Latent Profile Analysis With Covariates : Identifying Job Characteristics Profiles in Hierarchical Data as an Example

2018

Latent profile analysis (LPA) is a person-centered method commonly used in organizational research to identify homogeneous subpopulations of employees within a heterogeneous population. However, in the case of nested data structures, such as employees nested in work departments, multilevel techniques are needed. Multilevel LPA (MLPA) enables adequate modeling of subpopulations in hierarchical data sets. MLPA enables investigation of variability in the proportions of Level 1 profiles across Level 2 units, and of Level 2 latent classes based on the proportions of Level 1 latent profiles and Level 1 ratings, and the extent to which covariates drawn from the different hierarchical levels of th…

PRELIMINARY ANALYSES FROM A HOSPITAL BASED STUDY ON 3154 WESTERN SICILIAN PATIENTS WITH ORAL MUCOSAL LESIONS

2010

Objectives: Diagnosis of the wide variety of lesions that occur in the oral cavity is an essential part of dental practice. The objective of this study was to explore the demographic and behavioural profiles of patients affected by oral cavity diseases on a wide spectrum. Methods: Demographic and behavioural data of 3154 patients with at least one oral cavity disease among those consecutively visited between 2004 and 2009 at the Unit of Oral Medicine, were recorded: gender, age, smoking status, alcohol consumption, drugs use. Analysis was restricted to the eleven more frequent oral cavity diseases. Firstly, Multiple Correspondence Analysis (MCA) was applied as a descriptive tool to geometri…

1,1prime-Binaphthyl-2-methylpyridinium-based peroxophosphotungstate salts: synthesis, characterization, and their use as oxidation catalysts

2009

A series of 1,1′-binaphthyl-2-methylammonium and pyridinium salts 6, 7, and 8 was synthesized through the coupling reaction of 2-(bromomethyl)-1,1′-binaphthalene (5) with the dendritic tetraallyl pyridinedicarbinol dendron 2 as well as triethylamine and 4-tert-butylpyridine. Tetraallyl pyridinedicarbinol dendron 2 was prepared by allylation of commercially available diethyl pyridine-3,5-dicarboxylate (1). The allylation of 2 with allyltrimethylsilane in the presence of boron trifluoride was unsuccessful, as tetraallyl pyridinedicarbinol trifluoroboron adduct 3 was obtained instead of expected hexaallylpyridine compound 4. The catalytic hydrogenation of allyl groups of the ammonium salt of 2…

On the Porosity of Free Boundaries in Degenerate Variational Inequalities

2000

Abstract In this note we consider a certain degenerate variational problem with constraint identically zero. The exact growth of the solution near the free boundary is established. A consequence of this is that the free boundary is porous and therefore its Hausdorff dimension is less than N and hence it is of Lebesgue measure zero.

Topics in calculus and geometry on metric spaces

2022

In this thesis we present an overview of some important known facts related to topology, geometry and calculus on metric spaces. We discuss the well known problem of the existence of a lipschitz equivalent metric to a given quasiultrametric, revisiting known results and counterexamples and providing some new theorems, in an unified approach. Also, in the general setting of a quasi-metric doubling space, suitable partition of unity lemmas allows us to obtain, in step two Carnot groups, the well known Whitney’s extension theorem for a given real function of class C^m defined on a closed subset of the whole space: this result relies on relevant properties of the symmetrized Taylor’s polynomial…

Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines

2016

International audience; Direct unequal C-H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phosphines. The prepared primary diamantyl phosphines are quite air stable compared to their adamantyl and especially alkyl or aryl analogues. This finding is corroborated by comparing the singly occupied molecular orbital energy levels of the corresponding phosphine radical cations obtained by density functional theory computations.

Spherical Top Theory and Molecular Spectra

2011

In this article, we present an overview of the present state of the art of the theory of high-resolution spherical-top spectra in the framework of the effective Hamiltonian approach. We describe the specific features of this class of molecules to explain the basic concepts of the theoretical methods used for the analysis (line positions and intensities) and the simulation of absorption (including pure rotation) and Raman spectra of such species. The non conventional formalism that we use is essentially based on irreducible tensor methods and is especially adapted to computational treatments and global analyses of complex interacting band systems. We give examples concerning mainly methane (…

Preliminary Evaluation of Plasmix Compound from Plastics Packaging Waste for Reuse in Bituminous Pavements

2021

Finding an appropriate technical solution for reusing waste plastics is crucial for creating a circular plastic economy. Although mechanical recycling is the best option for recycling post-consumer plastics, some heterogeneous mixed plastics cannot be recycled to produce secondary material due to their very low properties. In this case, alternative routes should be considered in order to limit their disposal as much as possible. Therefore, in order to solve the environmental problems in the landfills of plastic waste recycling, and to improve the mechanical performance of bitumen for road pavement, the reuse of these post-consumer plastic wastes are preliminarily evaluated for the modificat…

The Homogeneous Poisson Point Process

2008

A Leibniz variety with almost polynomial growth

2005

Abstract Let F be a field of characteristic zero. In this paper we study the variety of Leibniz algebras V ˜ 1 defined by the identity y 1 ( y 2 y 3 ) ( y 4 y 5 ) ≡ 0 . We give a complete description of the space of multilinear identities in the language of Young diagrams through the representation theory of the symmetric group. As an outcome we show that the variety V ˜ 1 has almost polynomial growth, i.e., the sequence of codimensions of V ˜ 1 cannot be bounded by any polynomial function but any proper subvariety of V ˜ 1 as polynomial growth.