Search results for "Honeycomb"

A Wavy Two-Dimensional Covalent Organic Framework from Core- Twisted Polycyclic Aromatic Hydrocarbons

2019

A high degree of crystallinity is an essential aspect in two-dimensional covalent organic frameworks, as many properties depend strongly on the structural arrangement of the different layers and their constituents. We introduce herein a new design strategy based on core-twisted polycyclic aromatic hydrocarbon as rigid nodes that give rise to a two-dimensional covalent organic framework with a wavy honeycomb (chairlike) lattice. The concave–convex self-complementarity of the wavy two-dimensional lattice guides the stacking of framework layers into a highly stable and ordered covalent organic framework that allows a full 3D analysis by transmission electron microscopy revealing its chairlike …

2015

AbstractAtomic manipulation in the scanning tunnelling microscopy, conventionally a tool to build nanostructures one atom at a time, is here employed to enable the atomic-scale imaging of a model low-dimensional system. Specifically, we use low-temperature STM to investigate an ultra thin film (4 atomic layers) of potassium created by epitaxial growth on a graphite substrate. The STM images display an unexpected honeycomb feature, which corresponds to a real-space visualization of the Wigner-Seitz cells of the close-packed surface K atoms. Density functional simulations indicate that this behaviour arises from the elastic, tip-induced vertical manipulation of potassium atoms during imaging,…

Topological edge states of nonequilibrium polaritons in hollow honeycomb arrays

2020

We address topological currents in polariton condensates excited by uniform resonant pumps in finite honeycomb arrays of microcavity pillars with a hole in the center. Such currents arise under combined action of the spin–orbit coupling and Zeeman splitting, which breaks the time-reversal symmetry and opens a topological gap in the spectrum of the structure. The most representative feature of this structure is the presence of two interfaces, inner and outer ones, where the directions of topological currents are opposite. Due to the finite size of the structure, polariton–polariton interactions lead to coupling of the edge states at the inner and outer interfaces, which depends on the size o…

Slow Relaxation of the Magnetization in Anilato-Based Dy(III) 2D Lattices.

2021

The search for two- and three-dimensional materials with slow relaxation of the magnetization (single-ion magnets, SIM and single-molecule magnets, SMM) has become a very active area in recent years. Here we show how it is possible to prepare two-dimensional SIMs by combining Dy(III) with two different anilato-type ligands (dianions of the 3,6-disubstituted-2,5-dihydroxy-1,4-benzoquinone: C6O4X22−, with X = H and Cl) in dimethyl sulfoxide (dmso). The two compounds prepared, formulated as: [Dy2(C6O4H2)3(dmso)2(H2O)2]·2dmso·18H2O (1) and [Dy2(C6O4Cl2)3(dmso)4]·2dmso·2H2O (2) show distorted hexagonal honeycomb layers with the solvent molecules (dmso and H2O) located in the interlayer space and…

Dielectrophoretic trapping of multilayer DNA origami nanostructures and DNA origami-induced local destruction of silicon dioxide

2015

DNA origami is a widely used method for fabrication of custom-shaped nanostructures. However, to utilize such structures, one needs to controllably position them on nanoscale. Here we demonstrate how different types of 3D scaffolded multilayer origamis can be accurately anchored to lithographically fabricated nanoelectrodes on a silicon dioxide substrate by DEP. Straight brick-like origami structures, constructed both in square (SQL) and honeycomb lattices, as well as curved "C"-shaped and angular "L"-shaped origamis were trapped with nanoscale precision and single-structure accuracy. We show that the positioning and immobilization of all these structures can be realized with or without thi…

The General Routing Problem polyhedron: Facets from the RPP and GTSP polyhedra

1998

[EN] In this paper we study the polyhedron associated with the General Routing Problem (GRP). This problem, first introduced by Orloff in 1974, is a generalization of both the Rural Postman Problem (RPP) and the Graphical Traveling Salesman Problem (GTSP) and, thus, is NP -hard. We describe a formulation of the problem such that from every non-trivial facet-inducing inequality for the RPP and GTSP polyhedra, we obtain facet-inducing inequalities for the GRP polyhedron, We describe a new family of facet-inducing inequalities for the GRP, the honeycomb constraints, which seem to be very useful for solving GRP and RPP instances. Finally, new classes of facets obtained by composition of facet-i…

Two-Dimensional Assembling of (2,2‘-Bipyrimidine)bis(oxalato)chromate(III) Units through Alkaline Cations

1999

Self-assembling of the tris-chelated [Cr(bpm)(ox)2]- complex with Na+ in aqueous solution leads to the remarkable bimetallic honeycomb layered compound of formula [NaICrIII(bpm)(ox)2]·5H2O (2) (bpm...

The pore structure of compacted and partly saturated MX-80 bentonite at different dry densities

2014

Compacted MX-80 bentonite is a potential backfill material in radioactive-waste repositories. Pore space in MX-80 has been the subject of considerable debate. 3D reconstructions of the pore space based on tomographic methods could provide new insights into the nature of the pore space of compacted bentonites. To date, few such reconstructions have been done because of problems with the preparation of bentonite samples for electron microscopy. The nanoscale intergranular pore space was investigated here by cryo-Focused Ion Beam nanotomography (FIB-nt) applied to previously high-pressure frozen MX-80 bentonite samples. This approach allowed a tomographic investigation of the in situ microstru…

Honeycomb supported Co3O4/CeO2 catalysts for CO/CH4 emissions abatement: effect of low Pd-Pt content on the catalytic activity

2007

Abstract A structured Co3O4–CeO2 composite oxide, containing 30% by weight of Co3O4, has been prepared over a cordieritic honeycomb support. The bimetallic, Pd–Pt catalyst has been obtained by impregnation of the supported Co3O4–CeO2 with Pd and Pt precursors in order to obtain a total metal loading of 50 g/ft3. CO, CH4 combined oxidation tests were performed over the catalyzed monoliths in realistic conditions, namely GHSV = 100,000 h−1 and reaction feed close to emission from bi-fuel vehicles. The Pd–Pt un-promoted Co3O4–CeO2 is promising for cold-start application, showing massive CO conversion below 100 °C, in lean condition. A strong enhancement of the CH4 oxidation activity, between 4…

Evidence for Graphene Edges Beyond Zigzag and Armchair

2009

The edges of nanoscopic objects determine most of their properties. For this reason the edges of honeycomb carbon--always considered either zigzag- or armchair-like--need special attention. In this report we provide experimental evidence confirming a previous unexpected prediction: zigzag is a metastable edge, as its planar reconstruction lowers energy and forms the most stable graphene edge. Our evidence is based on re-analyzing a recent experiment. Since the reconstructed edge, along with other unconventional edges we discuss, has distinct chemical properties, this discovery urges for care in experiments and theory--we must enter the realm beyond zigzag and armchair.