Search results for "Hyperfine structure"
showing 10 items of 423 documents
Fourth-order relativistic corrections to electrical first-order properties using direct perturbation theory.
2011
In this work, we present relativistic corrections to first-order electrical properties obtained using fourth-order direct perturbation theory (DPT4) at the Hartree-Fock level. The considered properties, i.e., dipole moments and electrical-field gradients, have been calculated using numerical differentiation techniques based on a recently reported DPT4 code for energies [S. Stopkowicz and J. Gauss, J. Chem. Phys. 134, 064114 (2011)]. For the hydrogen halides HX, X=F, Cl, Br, I, and At, we study the convergence of the scalar-relativistic contributions by comparing the computed DPT corrections to results from spin-free Dirac-Hartree-Fock calculations. Furthermore, since in the DPT series spin-…
Atomic transitions of Rb, D2 line in strong magnetic fields: Hyperfine Paschen–Back regime
2014
An efficient $\lambda/2$-method ($\lambda$ is the resonant wavelength of laser radiation) based on nanometric-thickness cell filled with rubidium is implemented to study the splitting of hyperfine transitions of $^{85}$Rb and $^{87}$Rb $D_2$ lines in an external magnetic field in the range of $B =3$~kG -- 7~kG. It is experimentally demonstrated that at $B > 3$~kG from 38 (22) Zeeman transitions allowed at low $B$-field in $^{85}$Rb ($^{87}$Rb) spectra in the case of $\sigma^+$ polarized laser radiation there remain only 12 (8) which is caused by decoupling of the total electronic momentum $\textbf{J}$ and the nuclear spin momentum $\textbf{I}$ (hyperfine Paschen-Back regime). Note that at $…
Hyperfine Paschen-Back regime in alkali metal atoms: consistency of two theoretical considerations and experiment
2013
Simple and efficient "\lambda-method" and "\lambda/2-method" (\lambda is the resonant wavelength of laser radiation) based on nanometric-thickness cell filled with rubidium are implemented to study the splitting of hyperfine transitions of 85Rb and 87Rb D_1 line in an external magnetic field in the range of B = 0.5 - 0.7 T. It is experimentally demonstrated from 20 (12) Zeeman transitions allowed at low B-field in 85Rb (87Rb) spectra in the case of \sigma+ polarized laser radiation, only 6 (4) remain at B > 0.5 T, caused by decoupling of the total electronic momentum J and the nuclear spin momentum I (hyperfine Paschen-Back regime). The expressions derived in the frame of completely uncoupl…
High-precision hyperfine spectroscopy inM1-M1 double-resonance transitions on trappedPb+207
1992
Optical pumping of the ground state of $^{207}\mathrm{Pb}^{+}$ ions, confined in a Paul ion trap on the weak 6${\mathit{P}}_{1/2\mathrm{\ensuremath{-}}}$6${\mathit{P}}_{3/2}$ M1 transition at \ensuremath{\lambda}=710 nm, and consequent magnetic-dipole transitions between the ground-state hyperfine Zeeman levels have resulted in an A factor of 12 968 180 601.61(0.22) Hz and linewidth of 0.5 Hz. The value includes corrections of Zeeman shifts from residual magnetic fields and second-order Doppler shifts in the several-eV-deep trap potential, while the ions were cooled by He buffer gas. Two M1 quanta have been applied simultaneously in a double-resonance experiment.
Electric field induced hyperfine level-crossings in (nD)Cs at two-step laser excitation: experiment and theory
2005
The pure electric field level-crossing of m_F Zeeman sublevels of hyperfine F levels at two-step laser excitation was described theoretically and studied experimentally for the nD_3/2 states in Cs with n = 7,9, and 10, by applying a diode laser in the first 6S_1/2 to 6P_3/2 step and a diode or dye laser for the second 6P_3/2 to nD_3/2 step. Level-crossing resonance signals were observed in the nD_3/2 to 6P_1/2 fluorescence. A theoretical model was developed to describe quantitatively the resonance signals by correlation analysis of the optical Bloch equations in the case when an atom simultaneously interacts with two laser fields in the presence of an external dc electric field. The simulat…
Hyperfine structure measurements in the
1997
Clouds of stable and unstable Eu+ isotopes have been confined in a Paul trap, each containing about 105 particles. In a microwave-optical double resonance experiment several hyperfine separations in the 4f7 6s 7S3 exited level have been measured with the experimental uncertainties ranging between 10-8 and 3×10-6. These experiments have confirmed that also in the case of an excited level with a large number of hyperfine or Zeeman sublevels the microwave-optical double resonance technique in a Paul trap can be useful for precise hyperfine structure investigation. The hyperfine coupling constants A and B have been determined for the isotopes 153Eu+, 151Eu+, 150Eu+ and 148Eu+. The results compl…
Evaluation of the magnetic moment ofRa213
1991
The hyperfine field at the nucleus of singly ionized radium has been investigated using the relativistic linked-cluster many-body-perturbation-theory procedure, including the effects of distributed charge and magnetization over the nucleus. The total hyperfine field of 1239 T, when combined with the experimentally observed hyperfine constant for $^{213}\mathrm{Ra}^{+}$, yields a nuclear moment of 0.607(12)${\mathrm{\ensuremath{\mu}}}_{\mathit{N}}$, in excellent agreement with the experimentally observed moment of 0.6133(18)${\mathrm{\ensuremath{\mu}}}_{\mathit{N}}$ from Zeeman measurements. Our investigation leads to exchange core-polarization and correlation contributions of 14% and 13%, r…
Broadening and intensity redistribution in theNa(3p)hyperfine excitation spectra due to optical pumping in the weak excitation limit
2008
Detailed analysis of spectral line broadening and variations in relative intensities of hyperfine spectral components due to optical pumping is presented. Hyperfine levels of sodium 3p1/2 and 3p3/2 levels are selectively excited in a supersonic beam at various laser intensities under the conditions when optical pumping time is shorter than transit time of atoms through the laser beam. The excitation spectra exhibit significant line broadening at laser intensities well below the saturation intensity, and redistribution of intensities of hyperfine spectral components is observed, which in some cases is contradicting with intuitive expectations. Theoretical analysis of the dynamics of optical …
Precise determination of the ground state hyperfine structure splitting of43Ca II
1994
We have performed a laser microwave double resonance experiment on43Ca+ ions stored in a Paul ion trap. The ground state hfs splitting has been determined to Δν=3 225 608 286. 4(3) Hz. The value is corrected for small Zeeman, Stark and second order Doppler shifts as well as for light shift effects caused by the laserfields. The uncertainty is mainly determined by the errors of these corrections.
Ion trap nuclear resonance on $\mathsf{^{151}Eu^ + }$
2003
Laser-microwave double resonance techniques applied to a cloud of a natural mixture of Eu + isotopes confined in a Penning trap has been used to induce and detect nuclear Zeeman transitions. In spite of the complex level structure of Eu + and overlapping spectra from the two isotopes five different $\Delta m_I = 1$ transitions could be observed from which the nuclear magnetic moment can be derived. We obtain for 151 Eu + g I = 1.377 34(6) demonstrating the potential for high accuracy of the technique. The experiment can be considered as a feasibility test that precise spectroscopy data using the ion storage technique can be obtained of very complex ions and under unfavourable conditions.