Search results for "Hyperfine"
showing 10 items of 428 documents
The first unpaired electron placed inside a C3-symmetry P-chirogenic cluster
2010
The Pd(3)(dppm*)(3)(CO)(n+) enantiomers (n = 2 (2), 1 (3)) were prepared either from (R,R)- or (S,S)-P-chirogenic bis(phenyl-m-xylylphosphino)methane (dppm*; 1) and Pd(OAc)(2) in the presence of CF(3)CO(2)H, CO and water (n = 2), and then by reductive electrolysis (n = 1). The stable enantiomeric [Pd(3)((S,S)-dppm*)(3)(CO)](+)˙ (3), is the first C(3)-symmetry radical-cation M-M bonded cluster, therefore the odd electron is delocalized onto the Pd(3) frame within this symmetry. The novel chiral species have been characterized by circular dichroism (CD) of both enantiomers of the Pd(3)(dppm*)(3)(CO)(2+) clusters (2) and by EPR spectroscopy for the Pd(3)((S,S)-dppm*)(3)(CO)(+)˙ paramagnetic co…
High-precision measurements of the hyperfine structure of cobalt ions in the deep ultraviolet range
2023
Scientific reports 13(1), 4783 (2023). doi:10.1038/s41598-023-31378-1
NQR/NMR and Mössbauer spectroscopy of sulfides: potential and versatility
2013
Nuclear quadrupole resonance (NQR), nuclear magnetic resonance (NMR) and nuclear gamma-resonance (NGR or Mossbauer Effect) methods are generally described as highly sensitive tools in studies of local electronic structure and symmetry in solid-state materials. This is due to high informativity in electronic structure investigations, high resolution in phase-structural diagnostics (down to nano-scale), possibility to study polycrystalline and complex compounds, and to the non-destructive character of these methods. As applied to Earth sciences, both NQR/NMR and Mossbauer spectroscopy methods contribute to mineralogical material science and mineral physics. Another important aspect is the fac…
Determination of accurate rest frequencies and hyperfine structure parameters of cyanobutadiyne, HC5N
2020
Very accurate transition frequencies of HC$_5$N were determined between 5.3 and 21.4 GHz with a Fourier transform microwave spectrometer. The molecules were generated by passing a mixture of HC$_3$N and C$_2$H$_2$ highly diluted in neon through a discharge valve followed by supersonic expansion into the Fabry-Perot cavity of the spectrometer. The accuracies of the data permitted us to improve the experimental $^{14}$N nuclear quadrupole coupling parameter considerably and the first experimental determination of the $^{14}$N nuclear spin-rotation parameter. The transition frequencies are also well suited to determine in astronomical observations the local speed of rest velocities in molecula…
Physics at CERN's Antiproton Decelerator
2013
The Antiproton Decelerator of CERN began operation in 1999 to serve experiments for studies of CPT invariance by precision laser and microwave spectroscopy of antihydrogen ($\bar{\rm H}$) and antiprotonic helium ($\bar{p}{\rm He}^+$). The first 12 years of operation saw cold $\bar{\rm H}$ synthesized by overlapping clouds of positrons ($e^+$) and antiprotons ($\bar{p}$) confined in magnetic Penning traps. Cold $\bar{\rm H}$ was also produced in collisions between Rydberg positronium atoms and $\bar{p}$. Ground-state $\bar{\rm H}$ was later trapped for up to $\sim 1000$ s in a magnetic bottle trap, and microwave transitions excited between its hyperfine levels. In the $\bar{p}{\rm He}^+$ ato…
Nuclear moments and laser spectroscopy
1990
Laser spectroscopy measurements have yielded a wealth of new information about the moments and charge radii of unstable isotopes. The procedures of evaluating these moments from the magnetic dipole and electric quadrupole terms of the hyperfine structure arew discussed. Examples are presented, with emphasis on the isotopic chains of odd-proton nuclei, and their essential features are put into the context of current theoretical model descriptions for spherical and deformed nuclei. Finally, new developments of extremely sensitive experimental techniques are discussed with regard to an application to nuclei very far from stability.
How to measure nuclear ground-state properties in simple systems such as 11Li or U91+?
2008
Abstract Atomic spectroscopy yields key information on properties of ground and isomeric states via a determination of the hyperfine structure and isotope shift. In order to deduce precise nuclear moments and charge radii, the electromagnetic fields produced by the electrons at the site of the nucleus must be known with high accuracy. This is presently possible only for simple systems with very few electrons. This contribution describes two scenarios for such experiments: the determination of the charge radius of the neutron-rich isotopes 8,9Li and of the halo nucleus 11Li at the on-line isotope separators at GSI and TRIUMF and the Highly charged Ion TRAP (HITRAP) facility which is under co…
LASER SPECTROSCOPY WITH A COOLER RING AT THE ESR (GSI) AND THE TSR (MPI HEIDELBERG)
1992
At the TSR cooler ring at Heidelberg, laser studies were carried out using singly charged lithium and beryllium ions. Laser spectroscopy of relativistic lithium ions (v=0.04c) yielded signals with a narrow linewidth, suitable for an experimental test of special relativity. A dramatic reduction of the beam temperature, as defined by the longitudinal velocity spread, was achieved via laser cooling in both cases. At the ion energies available at ESR it will become possible to prepare and store bare ions up to U92+. Electron cooling was succesfully demonstrated for hydrogen-like Bi82+ ions, where a laser experiment is scheduled to study the ground-state hyperfine splitting.
The state of iron in andalusite
1990
Iron in andalusite (Al2SiO5) with concentrations of 1.5 … 4.3 wt-% has been reported in the literature to occupy mainly Al1 sites as Fe3+, and only small portions occupy Al2 sites as Fe3+ and Fe2+. In no case a magnetic hyperfine splitting has been found at temperatures above 77 K.
First observation of a resonance ionization signal on242mAm fission isomers
1992
The feasibility of a hyperfine spectroscopy on242mAm fission isomers has been demonstrated at the low target production rate of 10/s. The experimental method employed is based on resonance ionization spectroscopy in a buffer gas cell with detection of the ionization process by means of the fission decay of the isomers. The resonance ionization has been performed in two steps, utilizing an excimer dye laser combination with a repetition rate of 300 Hz. The first resonant step proceeds through theJ=7/2 term at 21440.35 cm−1, which has been excited with the tuncable dye laser beam of a wavelength of 466.28 nm, the second non-resonant step is achieved with the 351 nm radiation of the excimer la…