Search results for "IC framework"

Toward Engineering Chiral Rodlike Metal-Organic Frameworks with Rare Topologies.

2018

The establishment of novel design strategies to target chiral rodlike MOFs, elusively faced until now, is one of the most straightforward manners to widen the scope of MOFs. Here we describe our last advances on the application of the metalloligand design strategy toward the development of efficient routes to obtain chiral rodlike MOFs. To this end, we have used as precursor an enantiopure homochiral hexanuclear wheel (1), derived from the amino acid d-valine, which, after a supramolecular reorganization into a one-dimensional homochiral chain-with the same configuration as 1-led to the formation of a homochiral rodlike MOF (2) exhibiting rare etd topology.

Homochiral Metal-Organic Frameworks for Enantioselective Separations in Liquid Chromatography

2020

Selective separation of enantiomers is a substantial challenge for the pharmaceutical industry. Chromatography on chiral stationary phases is the standard method, but at a very high cost for industrial-scale purification due to the high cost of the chiral stationary phases. Typically, these materials are poorly robust, expensive to manufacture, and often too specific for a single desired substrate, lacking desirable versatility across different chiral analytes. Here, we disclose a porous, robust homochiral metal–organic framework (MOF), TAMOF-1, built from copper(II) and an affordable linker prepared from natural l-histidine. TAMOF-1 has shown to be able to separate a variety of model…

A STUDY OF THE πN SCATTERING DATA WITH JP = 3/2- AND A PROOF OF THE EXISTENCE OF THE N*(1700)

2014

Using an interaction extracted from the local hidden gauge Lagrangians and the coupled channels ρN (s-wave), πN (d-wave), πΔ (s-wave) and πΔ (d-wave), we look in the region of [Formula: see text] and we find two resonances dynamically generated which are naturally associated to the N*(1520)(3/2-) and N*(1700)(3/2-). The N*(1700)(3/2-) appears neatly as a pole in the complex plane. The free parameters of the theory are chosen to fit the πN (d-wave) data. The unitary coupled channel approach followed here, in connection with the experimental data, leads automatically to a pole in the 1700 MeV region and makes this second 3/2- resonance unavoidable.

Asymptotics for thenth-degree Laguerre polynomial evaluated atn

1992

We investigate the asymptotic behaviour of ? n (n),n?? where ? n (x) denotes the Laguerre polynomial of degreen. Our results give a partial answer to the conjecture ?? n (n)>1 forn>6, made in 1984 by van Iseghem. We also show the connection between this conjecture and the continued fraction approximants of $$6\sqrt {{3 \mathord{\left/ {\vphantom {3 \pi }} \right. \kern-\nulldelimiterspace} \pi }} $$ .

Integer Complexity: Experimental and Analytical Results II

2015

We consider representing natural numbers by expressions using only 1’s, addition, multiplication and parentheses. Let \( \left\| n \right\| \) denote the minimum number of 1’s in the expressions representing \(n\). The logarithmic complexity \( \left\| n \right\| _{\log } \) is defined to be \({ \left\| n \right\| }/{\log _3 n}\). The values of \( \left\| n \right\| _{\log } \) are located in the segment \([3, 4.755]\), but almost nothing is known with certainty about the structure of this “spectrum” (are the values dense somewhere in the segment?, etc.). We establish a connection between this problem and another difficult problem: the seemingly “almost random” behaviour of digits in the ba…

LE AREE INTERNE PER LO SVILUPPO DEL TERRITORIO E LA COMPLEMENTARITÀ DI PROGRAMMI E STRUMENTI FRA LE POLITICHE EUROPEE DI SVILUPPO RURALE E DI COESIONE

Le Aree Interne rappresentano un tema particolarmente importante per la programmazione e la spesa dei fondi comunitari nel periodo 2014-2020 perché costituiscono il più grande esempio di complementarità fra le Politiche europee di sviluppo rurale e di coesione. Per lo sviluppo di queste Aree è stata creata una Strategia Nazionale per le Aree Interne (SNAI) che mira alla valorizzazione ed al recupero di tutti quei territori (rurali, montuosi, svantaggiati) dal carattere marginale rispetto alla disponibilità e all’offerta di servizi essenziali. La peculiarità di tale Strategia è quella di promuovere lo sviluppo di aree che sono uniformemente distribuite in tutto il comprensorio nazionale a di…

Synthesis of a chiral rod-like metal–organic framework from a preformed amino acid-based hexanuclear wheel

2019

We report the two-step synthesis of a chiral rod-like metal-organic framework (MOF). The chemical approach consists on the use of a previously prepared oxamato-based homochiral hexanuclear wheel, the ligand being a derivative of the natural amino acid l-alanine, with formula (Me4N)6{CuII6[(S)-alama])6}·10H2O (1) [where (S)-alama=(S)-N-(ethyl oxoacetate)alanine]. The anionic hexacopper(II) wheels, stabilized by the presence of templating tetramethylammonium counter-cations, disassemble in the presence of cationic square-planar [Ni(cyclam)]2+ complexes to yield, after a supramolecular reorganization process that involves axial coordination of the [Ni(cyclam)]2+ cations through the free carbon…

A Comprehensive Thermogravimetric Analysis Multifaceted Method for the Exact Determination of the Composition of Multifunctional Metal‐Organic Framew…

2020

Thermogravimetric analysis (TGA) has been widely used as a tool to characterise the composition of materials such as Metal-Organic Frameworks (MOFs). However, given their multifunctionality and structural complexity, examples of detailed methodologies for the exact calculation of the composition of complex MOF structures and MOF composites are lacking in the literature. Herein, we introduce a new straightforward methodology – based on the experimental ratio between the mass of a structure and its residue – for the exact calculation of the composition of almost any MOF material. We provide a detailed guide for the application of our methodology to different MOF materials, including MOFs in w…

Local regularity for time-dependent tug-of-war games with varying probabilities

2016

We study local regularity properties of value functions of time-dependent tug-of-war games. For games with constant probabilities we get local Lipschitz continuity. For more general games with probabilities depending on space and time we obtain H\"older and Harnack estimates. The games have a connection to the normalized $p(x,t)$-parabolic equation $(n+p(x,t))u_t=\Delta u+(p(x,t)-2) \Delta_{\infty}^N u$.

Spurious finite-size instabilities in nuclear energy density functionals

2013

It is known that some well-established parametrizations of the EDF do not always provide converged results for nuclei and a qualitative link between this finding and the appearance of finite-size instabilities of SNM near saturation density when computed within the RPA has been pointed out. We seek for a quantitative and systematic connection between the impossibility to converge self-consistent calculations of nuclei and the occurrence of finite-size instabilities in SNM for the example of scalar-isovector (S=0, T=1) instabilities of the standard Skyrme EDF. We aim to establish a stability criterion based on computationally-friendly RPA calculations of SNM that is independent on the functi…