Search results for "IPA"
showing 10 items of 5795 documents
Hydrogen-bonded networks of [Fe(bpp)2]2+spin crossover complexes and dicarboxylate anions: structural and photomagnetic properties
2016
The paper reports the syntheses, crystal structures, thermal and (photo)magnetic properties of spin crossover salts of formula [Fe(bpp)2](C6H8O4)·4H2O (1·4H2O), [Fe(bpp)2](C8H4O4)·2CH3OH·H2O (2·2MeOH·H2O) and [Fe(bpp)2](C8H4O4)·5H2O (2·5H2O) (bpp = 2,6-bis(pyrazol-3yl)pyridine; C6H8O4 = adipate dianion; C8H4O4 = terephthalate dianion). The salts exhibit an intricate network of hydrogen bonds between low-spin iron(II) complexes and carboxylate dianions, with solvent molecules sitting in the voids. Desolvation is accompanied by a low-spin (LS) to high-spin (HS) transformation in the materials. The dehydrated phase 2 undergoes a two-step transition with a second step showing thermal hysteresis…
Quantifying and easing conflicting goals between interest groups in natural resource planning
2019
Management of natural resources at the regional level is a compromise between a variety of objectives and interests. At the local level, management of the forests depends upon the ownership structure, with forest owners using their forests as they see fit. A potential conflict occurs if the forest owners’ management decisions are counter to the interests of society in general or the industry that relies on the forest resource as their raw material. We explore the intensity of this conflict at the regional level in several large boreal forest production landscapes. To explore the conflict, we investigate three main interest groups: (i) economically oriented forest owners; (ii) industry grou…
Climate indices for the Baltic states from principal component analysis
2017
Abstract. We used principal component analysis (PCA) to derive climate indices that describe the main spatial features of the climate in the Baltic states (Estonia, Latvia, and Lithuania). Monthly mean temperature and total precipitation values derived from the ensemble of bias-corrected regional climate models (RCMs) were used. Principal components were derived for the years 1961–1990. The first three components describe 92 % of the variance in the initial data and were chosen as climate indices in further analysis. Spatial patterns of these indices and their correlation with the initial variables were analyzed, and it was detected (based on correlation coefficient between principal compon…
Comparison of gap-filling techniques applied to the CCI soil moisture database in Southern Europe
2021
Abstract Soil moisture (SM) is a key variable that plays an important role in land-atmosphere interactions. Monitoring SM is crucial for many applications and can help to determine the impact of climate change. Therefore, it is essential to have continuous and long-term databases for this variable. Satellite missions have contributed to this; however, the continuity of the series is compromised due to the data gaps derived by different factors, including revisit time, presence of seasonal ice or Radio Frequency Interference (RFI) contamination. In this work, the applicability of different gap-filling techniques is evaluated on the ESA Climate Change Initiative (CCI) SM combined product, whi…
An autonomous petrological database for geodynamic simulations of magmatic systems
2022
SUMMARY Self-consistent modelling of magmatic systems is challenging as the melt continuously changes its chemical composition upon crystallization, which may affect the mechanical behaviour of the system. Melt extraction and subsequent crystallization create new rocks while depleting the source region. As the chemistry of the source rocks changes locally due to melt extraction, new calculations of the stable phase assemblages are required to track the rock evolution and the accompanied change in density. As a consequence, a large number of isochemical sections of stable phase assemblages are required to study the evolution of magmatic systems in detail. As the state-of-the-art melting diag…
Dissipative analogies of step-pool features: From rills to mountain streams
2019
Abstract In this paper the dissipative similarity of step-pool units at different spatial scales ranging from rills to streams is analyzed. This investigation benefits from the latest theoretical advances in open channel flow resistance, high-resolution topography from close-range photogrammetry applied to rill erosion and the availability of published data from literature on step-pool streams. At first, the integration of a power velocity distribution allowed to obtain a theoretically-based expression of Darcy-Weisbach friction factor, in which Γ function and δ exponent of the velocity profile are included. Then this theoretically-deduced flow resistance relationship is calibrated and test…
Pre- and syn-eruptive geochemistry of volcanic gases from Soufriere Hills of Montserrat, West Indies
1998
International audience; Soufriere Hills fumaroles contained magmaderived volatiles before and during the eruption initiated in 1995 but also preserved a typical and quite steady hydrothermal coinposition. Chemical changes due to increased boiling and a greater input of oxidizing magmatic gas occurred only at Galway's Soufriere, the most active fumarolic field. Hydrothermal buffering of the fumaroles has been favoured by their remote location (!-2 km) froin the eruptive vents and by a preferential degassing of the uprising magma through intrusive conduits under the crater. High temperature (720øC) gas collected froin the extruding lava dome in Feb. 1996 was chemically and isotopically repres…
Growth of stylolite teeth patterns depending on normal stress and finite compaction
2007
Abstract Stylolites are spectacular rough dissolution surfaces that are found in many rock types. They are formed during a slow irreversible deformation in sedimentary rocks and therefore participate to the dissipation of tectonic stresses in the Earth's upper crust. Despite many studies, their genesis is still debated, particularly the time scales of their formation and the relationship between this time and their morphology. We developed a new discrete simulation technique to explore the dynamic growth of the stylolite roughness, starting from an initially flat dissolution surface. We demonstrate that the typical steep stylolite teeth geometry can accurately be modelled and reproduce natu…
Indigenous people’s responses to drought in northwest Bangladesh
2019
Abstract Bangladesh is highly disaster-prone, with drought being a major hazard which significantly impacts water, food, health, livelihoods, and migration. In seeking to reduce drought vulnerabilities and impacts while improving responses, existing literature pays limited attention to community-level views and actions. This paper aims to contribute to filling in this gap by examining how an indigenous group, the Santal in Bangladesh’s northwest, responds to drought through local strategies related to water, food, and migration which in turn impact health and livelihoods. A combination of quantitative data through a household survey and qualitative data through participatory rural appraisal…
The chronic effects of fullereneC 60 -associated sediments in the midge Chironomus riparius – Responses in the first and the second generation
2017
Abstract The life cycle parameters of the benthic invertebrate Chironomus riparius make it a relevant organism for use in multi-generation chronic ecotoxicology tests. Since studies on chronic exposures with fullerene carbon nanoparticles have revealed adverse effects at lower concentration ranges, it is crucial to gain understanding of the consequences in following generations. The aims of this study were to investigate whether sediment-associated fullereneC 60 impacts on C. riparius emergence and breeding, thus affecting the growth of the second generation. Larvae were exposed to fullerene-spiked sediment at concentrations of 0.5, 10 and 40 mg/kg sediment dw. Total emergence and breeding …